NOVEL Fe-Cr OXIDE AND SKELETAL (RANEY) CATALYSTS FOR WATER GAS SHIFT REACTION. The water gas shift reaction has an importance implication in the control of carbon monoxide/hydrogen ratios of gas mixtures used during the synthesis of methanol, diesel and hydrogen. The research study aims to develop and characterise Fe-Cr oxide and chromia-promoted Raney Cu catalysts for water gas shift reaction using a tube wall reactor. The catalyst fabrication is based on leaching and electrochemical deposition ....NOVEL Fe-Cr OXIDE AND SKELETAL (RANEY) CATALYSTS FOR WATER GAS SHIFT REACTION. The water gas shift reaction has an importance implication in the control of carbon monoxide/hydrogen ratios of gas mixtures used during the synthesis of methanol, diesel and hydrogen. The research study aims to develop and characterise Fe-Cr oxide and chromia-promoted Raney Cu catalysts for water gas shift reaction using a tube wall reactor. The catalyst fabrication is based on leaching and electrochemical deposition to promote the catalytic activity. The produced catalysts will be characterised and tested for catalytic activity, temperature stability and other physical properties to determine fundamental understanding for future commercial applications.Read moreRead less
Investigation and Prediction of the Novel Properties of Dendrimers. Dendrimers are a new class of highly branched polymers, which have, until now, been difficult to characterise by conventional means. This project will develop and apply molecular simulation techniques to reveal the chemical and physical properties of dendrimers and their interactions with other molecules. These novel molecules potentially have beneficial applications to areas such as drug delivery and electronic materials. Th ....Investigation and Prediction of the Novel Properties of Dendrimers. Dendrimers are a new class of highly branched polymers, which have, until now, been difficult to characterise by conventional means. This project will develop and apply molecular simulation techniques to reveal the chemical and physical properties of dendrimers and their interactions with other molecules. These novel molecules potentially have beneficial applications to areas such as drug delivery and electronic materials. The outcome of this work will assist in the exploitation of this beneficial application and will provide the basis for efficient processing.Read moreRead less
Catalytic Conversion of Waste Plastics to Hydrocarbon Fuels. This project aims to investigate the catalytic conversion of waste plastics to liquid fuels. Plastics comprise about 20% of municipal waste by volume, and are a major environmental concern as the present practice of disposal by landfilling has long-term hazard potential and is unsustainable. We propose to study the kinetics of the catalytic degradation of pure component plastics as well as their mixtures in a laboratory screw extrusi ....Catalytic Conversion of Waste Plastics to Hydrocarbon Fuels. This project aims to investigate the catalytic conversion of waste plastics to liquid fuels. Plastics comprise about 20% of municipal waste by volume, and are a major environmental concern as the present practice of disposal by landfilling has long-term hazard potential and is unsustainable. We propose to study the kinetics of the catalytic degradation of pure component plastics as well as their mixtures in a laboratory screw extrusion reactor, compare alternative catalysts, and develop process models to be used for scale up. The process and know-how developed will contribute to sustainable development, and provide an internationally competitive advantage to Australia.Read moreRead less
Dry Processing of Fine Coal Using the Reflux Classifier. New and efficient separation technologies are crucial for developing the concept of Dry Coal Processing. The benefits to the industry of Dry Processing are compelling, with savings in water consumption, and much larger savings in dewatering and transportation of the product. The Reflux Classifier is a new fluidized bed technology developed in Australia using the more conventional water fluidization approach. Already the technology is contr ....Dry Processing of Fine Coal Using the Reflux Classifier. New and efficient separation technologies are crucial for developing the concept of Dry Coal Processing. The benefits to the industry of Dry Processing are compelling, with savings in water consumption, and much larger savings in dewatering and transportation of the product. The Reflux Classifier is a new fluidized bed technology developed in Australia using the more conventional water fluidization approach. Already the technology is contributing to Australian exports in the rapidly growing area of mining services. The purpose of this project is to establish its potential for use in the Dry Processing of fine coal. Other benefits of the study include the education and training of researchers in this field.Read moreRead less
Modelling of Adsorption Dynamics in Microporous Adsorbents Using Fractional Order Diffusion Equations. This project investigates the use of fractional order diffusion equations in modelling adsorption dynamics in microporous carbons. The long tail behaviour of adsorption processes cannot be readily explained by the classical second order Fickian model, and makes adsorption a candidate for the use of fractional order diffusion equations that have the potential to model such features. In the pre ....Modelling of Adsorption Dynamics in Microporous Adsorbents Using Fractional Order Diffusion Equations. This project investigates the use of fractional order diffusion equations in modelling adsorption dynamics in microporous carbons. The long tail behaviour of adsorption processes cannot be readily explained by the classical second order Fickian model, and makes adsorption a candidate for the use of fractional order diffusion equations that have the potential to model such features. In the present project we shall develop suitable numerical techniques for solving the fractional order diffusion model, and apply these to the interpretation of experimental kinetic data. The outcome will be an improved model of adsorption dynamics considering the fractal nature of the solid.Read moreRead less
The Study of Pretreatment Options for Composite Fouling of Reverse Osmosis Membranes Used in Water Treatment and Production. It is recognised worldwide that fouling is a major impediment in operation of Reverse Osmosis units used for production, purification and treatment of water. This project is aimed at studying pre-treatment options for composite fouling which is the main type of fouling present in RO units by using both model feed systems and actual field water. The project outcomes are to ....The Study of Pretreatment Options for Composite Fouling of Reverse Osmosis Membranes Used in Water Treatment and Production. It is recognised worldwide that fouling is a major impediment in operation of Reverse Osmosis units used for production, purification and treatment of water. This project is aimed at studying pre-treatment options for composite fouling which is the main type of fouling present in RO units by using both model feed systems and actual field water. The project outcomes are to understand and develop pre-treatment strategies and to use those to develop a hybrid pre-treatment technology. This project will significantly impact water production in general and its outcomes will have far-reaching implications in treatment of water both within Australia and globally.Read moreRead less
The Boron Rejection by RO Membranes in presence of Calcium Carbonate and Magnesium Hydroxide. Water scarcity in various parts of the world demands the use of available saline waters for production of potable water. Reverse Osmosis membranes have been used as a means of achieving this objective. Fouling is a major impediment in operation of reverse osmosis units. The project aims to study boron removal by RO under high pH which increases the boron rejection but at the same time exacerbates compos ....The Boron Rejection by RO Membranes in presence of Calcium Carbonate and Magnesium Hydroxide. Water scarcity in various parts of the world demands the use of available saline waters for production of potable water. Reverse Osmosis membranes have been used as a means of achieving this objective. Fouling is a major impediment in operation of reverse osmosis units. The project aims to study boron removal by RO under high pH which increases the boron rejection but at the same time exacerbates composite fouling by calcium carbonate and magnesium hydroxide. Optimum pH for boron rejection will be determined and propensity of calcium carbonate and magnesium hydroxide at that pH range will be evaluated.Read moreRead less
Development of constitutive models for concentrated suspensions via particle-level simulations. The outcome of this work will be a comprehensive theoretical framework by which accurate microstructural information is distilled into a macro-scale constitutive model of particulate suspensions, readily useable for modelling of practical industrial applications. This work will have a direct impact on the design capability and performance of a wide range of mechanisms and industrial processes involvin ....Development of constitutive models for concentrated suspensions via particle-level simulations. The outcome of this work will be a comprehensive theoretical framework by which accurate microstructural information is distilled into a macro-scale constitutive model of particulate suspensions, readily useable for modelling of practical industrial applications. This work will have a direct impact on the design capability and performance of a wide range of mechanisms and industrial processes involving suspensions. The development of better models for industrially useful suspensions offers a competitive advantage for a diverse range of Australia industry, from the food preparation sector, to mineral slurry transport, and water filtration and recycling.Read moreRead less
Gassing Mechanism and Stability of Foamed Explosive Emulsions. Mining of minerals such as coal involves crushing the surrounding rock strata, or the mineral ore itself, with emulsion explosives. One of the most important properties determining suitability of an emulsion explosive to a particular mining operation is its velocity of detonation, which can be adjusted by varying the number and size of air bubbles distributed in the emulsion matrix. The present project aims to develop new ways of g ....Gassing Mechanism and Stability of Foamed Explosive Emulsions. Mining of minerals such as coal involves crushing the surrounding rock strata, or the mineral ore itself, with emulsion explosives. One of the most important properties determining suitability of an emulsion explosive to a particular mining operation is its velocity of detonation, which can be adjusted by varying the number and size of air bubbles distributed in the emulsion matrix. The present project aims to develop new ways of generating air bubbles, to gain fundamental understanding of the foaming mechanism in currently used gassing techniques, and to invent ways to stabilise large bubbles within the emulsion. The project will provide scientific underpinning for the development of a new range of emulsion explosives manufactured by Orica for Australian and international markets, maintaining the Orica's position as a leader in the field of emulsion explosives.Read moreRead less
Production of a compact disk summarising the evolution and impact of Boger fluids. In 1977 the discovery of a unique class of materials, now called Boger fluids, was reported in the Journal of Non-Newtonian Fluid Mechanics. These materials have had a huge impact in the development of non-Newtonian fluid mechanics, to the extent that the Institute of Non-Newtonian Fluid Mechanics in the UK have offered to make a cd documenting the impact of these materials. Funding is requested to support, in p ....Production of a compact disk summarising the evolution and impact of Boger fluids. In 1977 the discovery of a unique class of materials, now called Boger fluids, was reported in the Journal of Non-Newtonian Fluid Mechanics. These materials have had a huge impact in the development of non-Newtonian fluid mechanics, to the extent that the Institute of Non-Newtonian Fluid Mechanics in the UK have offered to make a cd documenting the impact of these materials. Funding is requested to support, in part, the documentation of this important discovery.Read moreRead less