Switchable and stereocontrolled photoredox catalysis. This project aims to develop new catalytic synthetic reactions for the rapid and more direct functionalisation of organic compounds under mild conditions with the use of visible light. An integrated experimental and computational approach will be used to design potent visible-light photocatalysts that retain the advantages of standard photoredox catalysis but with the added ability to intercept and, thus control, reactive intermediates in sit ....Switchable and stereocontrolled photoredox catalysis. This project aims to develop new catalytic synthetic reactions for the rapid and more direct functionalisation of organic compounds under mild conditions with the use of visible light. An integrated experimental and computational approach will be used to design potent visible-light photocatalysts that retain the advantages of standard photoredox catalysis but with the added ability to intercept and, thus control, reactive intermediates in situ. This will enable the control of stereochemistry in photoredox reactions – not possible with standard catalysts - and establish other useful synthetic transformations. These strategies will make it easier to prepare valuable classes of organic molecules – efficiently, safely, and cost-effectively.
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How iron is cycled in Southern Ocean waters. This project aims to probe the Southern Ocean phytoplankton’s ability to take up and retain iron, using iron isotope tracer techniques. The Southern Ocean regulates Earth's climate, but the supply of iron to Southern Ocean surface waters is low, restricting the ability of phytoplankton to flourish and draw down carbon dioxide. The results are expected to reveal survival strategies of phytoplankton in this iron-poor environment and their potential abil ....How iron is cycled in Southern Ocean waters. This project aims to probe the Southern Ocean phytoplankton’s ability to take up and retain iron, using iron isotope tracer techniques. The Southern Ocean regulates Earth's climate, but the supply of iron to Southern Ocean surface waters is low, restricting the ability of phytoplankton to flourish and draw down carbon dioxide. The results are expected to reveal survival strategies of phytoplankton in this iron-poor environment and their potential ability to adapt to environmental change. This knowledge could be used to develop models to manage this climate-sensitive region.Read moreRead less
Metal complexes for activation and scission of small, multiply-bonded molecules. The outcome of this work is a series of metal complexes capable of cleaving the strong bonds in a number of small molecules of chemical importance. This will have a significant impact on industry by providing cheaper and safer alternatives to currently expensive and hazardous processes for producing nitrogen and phosphorus containing compounds.
Hot iron: Are submarine volcanoes important for Southern Ocean iron supply? The scarcity of iron limits biological productivity and carbon uptake in the nutrient rich waters of the Southern Ocean. This project will explore for the first time the role of undersea "hot spot" volcanoes in supplying iron to surface waters, thus linking the solid earth and the biosphere. The project will measure iron abundance, reactivity and nutritional value in buoyant plumes emanating from vents near Heard/McDonal ....Hot iron: Are submarine volcanoes important for Southern Ocean iron supply? The scarcity of iron limits biological productivity and carbon uptake in the nutrient rich waters of the Southern Ocean. This project will explore for the first time the role of undersea "hot spot" volcanoes in supplying iron to surface waters, thus linking the solid earth and the biosphere. The project will measure iron abundance, reactivity and nutritional value in buoyant plumes emanating from vents near Heard/McDonald Islands, Australia's only active volcanoes. The project aims to estimate the hydrothermal contribution to regional biological productivity and extrapolate to the whole Southern Ocean. Successful outcomes will benefit Australia by identifying iron sources that govern productivity and carbon uptake of an economically important ecosystem.Read moreRead less
Polymer nanoparticles and their assembled supracolloidal monolithic structures for applications in separation science. This project will generate new polymeric materials that will improve the analysis of complex samples. This will be applied in a wide range of areas of national importance including: pharmaceutical analysis and drug discovery; environmental, clinical and forensic analysis; and energy generation and foods.
Calcification and shell chemistry response of Southern Ocean planktic foraminifers to ocean acidification and changing climates. Plankton that form tiny calcium carbonate shells will be cultured to determine how they will respond to acidification of the Southern Ocean caused by rising CO2 in the atmosphere. The same experiments will be used to gauge from their fossil shells how the Southern Ocean has caused and responded to changing atmosphere CO2 over the last glacial climate cycle
A Midas touch for electrophiles in new reaction development. This project aims to address the lack of knowledge about how high-value organic molecules are formed in gold-catalysed reactions by advancing a novel mode of catalysis. This project expects to generate new knowledge about these gold-catalysed reactions using an innovative, interdisciplinary approach incorporating computational and synthetic techniques. Expected outcomes of this project include the optimisation and development of import ....A Midas touch for electrophiles in new reaction development. This project aims to address the lack of knowledge about how high-value organic molecules are formed in gold-catalysed reactions by advancing a novel mode of catalysis. This project expects to generate new knowledge about these gold-catalysed reactions using an innovative, interdisciplinary approach incorporating computational and synthetic techniques. Expected outcomes of this project include the optimisation and development of important organic reactions and enhancing collaboration nationally and internationally between computational and synthetic chemists. This should provide significant benefits in the form of improved chemical reactions for chemists to prepare new pharmaceuticals, agrochemicals and materials.Read moreRead less
A new route to linear alpha olefins - catalytic isomerisation of internal olefins. Linear alpha olefins are an extremely important class of chemical building blocks used for everyday consumer products, such as plastics, detergents and lubricants. This research aims to develop a new platform technology for the production of these materials from low cost precursors.
Deciphering strategies polar phytoplankton employ to lessen iron limitation. The Southern Ocean is of global importance. It comprises one-third of the global ocean by area and disproportionately absorbs two-thirds of anthropogenic ocean heat and half of anthropogenic carbon dioxide (CO2) emissions even though phytoplankton in this region are chronically iron-limited. This project aims to understand why copper uptake by phytoplankton lessens the effects of iron limitation and how copper substitut ....Deciphering strategies polar phytoplankton employ to lessen iron limitation. The Southern Ocean is of global importance. It comprises one-third of the global ocean by area and disproportionately absorbs two-thirds of anthropogenic ocean heat and half of anthropogenic carbon dioxide (CO2) emissions even though phytoplankton in this region are chronically iron-limited. This project aims to understand why copper uptake by phytoplankton lessens the effects of iron limitation and how copper substitutes for iron. This knowledge is critical for evaluating the impacts and feedbacks between iron and copper in regulating Southern Ocean productivity and ultimately its ability to drawdown atmospheric CO2. The results from this project will facilitate the development of improved ecosystem models and conservation tools.Read moreRead less
Changes in the ocean's biological pump: innovative models and diagnostics. This Project aims to quantify how the ocean’s biological pump, which exports newly formed organic matter into the ocean interior, responds to environmental change. The biological pump is a key control on the global carbon and oxygen cycles, and hence on the viability of marine life. New, efficient numerical models will be developed and analysed with highly innovative mathematical methods. Expected outcomes are optimised .... Changes in the ocean's biological pump: innovative models and diagnostics. This Project aims to quantify how the ocean’s biological pump, which exports newly formed organic matter into the ocean interior, responds to environmental change. The biological pump is a key control on the global carbon and oxygen cycles, and hence on the viability of marine life. New, efficient numerical models will be developed and analysed with highly innovative mathematical methods. Expected outcomes are optimised predictive models and a new understanding of the possible future evolutions of the ocean carbon cycle, acidification, and oxygenation. This should provide significant benefits such as predictions of future ocean health, identification of processes that are sensitive to change, and strategies for marine resource management.Read moreRead less