Electronic-vibrational spectroscopy: A new probe for structure and function. This project aims to solve a major challenge in ultrafast spectroscopy: to identify and quantify competing reaction pathways in complex photochemical systems. Ultrafast Spectroscopy provides information on excited-state processes of photochemical reactions, however, unravelling heterogeneous systems with competing parallel processes remains difficult. Multidimensional electronic-vibrational spectroscopy, sensitive to el ....Electronic-vibrational spectroscopy: A new probe for structure and function. This project aims to solve a major challenge in ultrafast spectroscopy: to identify and quantify competing reaction pathways in complex photochemical systems. Ultrafast Spectroscopy provides information on excited-state processes of photochemical reactions, however, unravelling heterogeneous systems with competing parallel processes remains difficult. Multidimensional electronic-vibrational spectroscopy, sensitive to electronic dynamics and molecular structure, is expected to overcome this barrier. This new level of detail will profoundly enhance our understanding of energy and chemical conversion in complex systems and will reveal design targets for optimising next-generation light-energy harvesting, conducting, and emitting materials.Read moreRead less
Metal-Based Molecular Materials: From Electronic Structure to Functionality. This project aims to develop and explore new metal-based molecular materials, focusing on molecules that can act as magnets or be switched between multiple states by heating/cooling. This project expects to deliver an improved understanding of how the molecular electronic structure engenders desired physical properties in the target species. This insight will allow development of design principles for robust systems for ....Metal-Based Molecular Materials: From Electronic Structure to Functionality. This project aims to develop and explore new metal-based molecular materials, focusing on molecules that can act as magnets or be switched between multiple states by heating/cooling. This project expects to deliver an improved understanding of how the molecular electronic structure engenders desired physical properties in the target species. This insight will allow development of design principles for robust systems for nanodevices or advanced materials. As well as achieving important advances in fundamental chemistry, this project is anticipated to help lay the foundations for development of novel materials for high density data storage, quantum computing, molecular electronics/spintronics, optical displays or temperature/solvent sensors.Read moreRead less
Molecular Spin Switching with Earth Abundant Metals. This project aims to develop molecular materials based on non-precious metals that respond to stimuli, including heat or light, by switching between forms with different properties, such as colour and electrical conductivity. The project expects to deliver enhanced control over the switching characteristics and incorporation of the materials into responsive thin films, ready for integration into devices. These molecular switches are promising ....Molecular Spin Switching with Earth Abundant Metals. This project aims to develop molecular materials based on non-precious metals that respond to stimuli, including heat or light, by switching between forms with different properties, such as colour and electrical conductivity. The project expects to deliver enhanced control over the switching characteristics and incorporation of the materials into responsive thin films, ready for integration into devices. These molecular switches are promising for molecular electronics, spintronics and colour-based sensing and display devices. Their fast response time and small component size imply less heat to dissipate and therefore less electricity required for cooling upon implementation in information communications and other technologies.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE210101627
Funder
Australian Research Council
Funding Amount
$447,625.00
Summary
Developing ultra adsorbent MOF composites as high performance materials. This project aims to improve the adsorption properties of porous materials through enhancing their selectivity and also creating new composites. This research expects to extend application opportunities to encompass real-life scenarios, in particular hydrogen transfer and carbon capture. Expected outcomes is the enhancement of the adsorbent properties of these porous materials, and an improvement of their selectivity and m ....Developing ultra adsorbent MOF composites as high performance materials. This project aims to improve the adsorption properties of porous materials through enhancing their selectivity and also creating new composites. This research expects to extend application opportunities to encompass real-life scenarios, in particular hydrogen transfer and carbon capture. Expected outcomes is the enhancement of the adsorbent properties of these porous materials, and an improvement of their selectivity and mechanical robustness. This is due to the synergistic strengthening effects of new graphene and nanodiamond composites. The benefit of this research is in bridging the gap between porous material synthesis and industrial application, contributing to Australia's becoming a world leader in clean energy research.Read moreRead less
Shape-Shifting Molecules: Photoisomerization Action Spectroscopy. This project aims to examine molecules that change shape in response to light in order to gain insight into the biological processes they control. Many biological systems, including the human visual apparatus and bacterial photosynthesis, depend on molecules that change shape in response to light. The project plans to probe shape-shifting molecules with laser light while they are propelled through gas by an electric field. Light-i ....Shape-Shifting Molecules: Photoisomerization Action Spectroscopy. This project aims to examine molecules that change shape in response to light in order to gain insight into the biological processes they control. Many biological systems, including the human visual apparatus and bacterial photosynthesis, depend on molecules that change shape in response to light. The project plans to probe shape-shifting molecules with laser light while they are propelled through gas by an electric field. Light-induced changes in molecular shape produce detectable variations in drift speed. The ensuing knowledge would help calibrate computational approaches for predicting molecular function. It would also establish foundations for understanding essential biological molecules, including retinals, carotenes and peptides, and for developing new light-activated molecular motors and switches.Read moreRead less
Multi-colour ultrashort soft X-ray pulses. This project aims to create multi-colour, ultrashort, highly coherent, bright pulses of soft X-rays based on high-harmonic generation in a table-top multiple-section gas cell. Studying multi-electronic and non-adiabatic processes and other fundamental aspects such as multi-electronic correlations and non-Born-Oppenheimer vibronic couplings in complex molecules is a major challenge in current ultrafast photochemistry research. This project will use multi ....Multi-colour ultrashort soft X-ray pulses. This project aims to create multi-colour, ultrashort, highly coherent, bright pulses of soft X-rays based on high-harmonic generation in a table-top multiple-section gas cell. Studying multi-electronic and non-adiabatic processes and other fundamental aspects such as multi-electronic correlations and non-Born-Oppenheimer vibronic couplings in complex molecules is a major challenge in current ultrafast photochemistry research. This project will use multiple driving pulses with different carrier frequencies to control the spectral properties and time delay of the pulses. It will use the soft X-ray source to develop an ideal platform for studying multi-electronic and non-adiabatic processes, multi-electronic correlations and non-Born-Oppenheimer vibronic couplings in complex molecules. This is expected to advance materials science, paving the way to soft X-ray technologies.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE200100136
Funder
Australian Research Council
Funding Amount
$1,100,000.00
Summary
High Performance Solid State NMR Spectroscopy for Materials Research. The project will support research in a diverse set of fields such as biomedical engineering catalysis, energy storage and waste recovery, with cutting edge next-generation solid state (400 MHz) nuclear magnetic resonance capabilities and research expertise. The system enabling high sensitivity, high throughput analysis over extended temperature range will enable addressing of fundamental questions regarding the structure-prope ....High Performance Solid State NMR Spectroscopy for Materials Research. The project will support research in a diverse set of fields such as biomedical engineering catalysis, energy storage and waste recovery, with cutting edge next-generation solid state (400 MHz) nuclear magnetic resonance capabilities and research expertise. The system enabling high sensitivity, high throughput analysis over extended temperature range will enable addressing of fundamental questions regarding the structure-property relationships of advanced functional materials. Accessible to a wide user base in fundamental and applied research, in medicine, energy, catalysis and recycling of waste, the project will extend the current facilities to develop Sydney as regional centre for advanced solid state nuclear magnetic resonance analysis.Read moreRead less
Luminophores and photochromes: towards molecular componentry. This project aims to enhance current knowledge of luminogenic and photochromic molecules, including self-assembled structures, and materials composed thereof, by constructing a computationally guided compound library. Translation of primary outcomes towards utility in emerging technologies including passive light harvesting from transparent surfaces, bio-sensors and photo-responsive devices will be pursued in collaboration with both a ....Luminophores and photochromes: towards molecular componentry. This project aims to enhance current knowledge of luminogenic and photochromic molecules, including self-assembled structures, and materials composed thereof, by constructing a computationally guided compound library. Translation of primary outcomes towards utility in emerging technologies including passive light harvesting from transparent surfaces, bio-sensors and photo-responsive devices will be pursued in collaboration with both academia and industry. The expected outcomes from this project include the creation of opportunities to explore the manufacture and commercialisation of high-value products with Australian industry. This will provide significant benefits, such as reduction in the carbon footprint of homes, businesses and other applicable structures due to passive power generation, while creating jobs and up-skilling the workforce.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE210100139
Funder
Australian Research Council
Funding Amount
$1,240,000.00
Summary
Revitalizing facilities for nuclear magnetic resonance in South Australia. Nuclear magnetic resonance (NMR) spectroscopy is the single most powerful spectroscopic tool for determining molecular structure. Our aim is to upgrade NMR infrastructure available to researchers across South Australia with an integrated and complementary array of state-of-the-art spectrometers to diversify usage across a range of disciplines. Replacement of outdated spectrometers will modernise core NMR facilities along ....Revitalizing facilities for nuclear magnetic resonance in South Australia. Nuclear magnetic resonance (NMR) spectroscopy is the single most powerful spectroscopic tool for determining molecular structure. Our aim is to upgrade NMR infrastructure available to researchers across South Australia with an integrated and complementary array of state-of-the-art spectrometers to diversify usage across a range of disciplines. Replacement of outdated spectrometers will modernise core NMR facilities along with installation of new probes to improve sensitivity and the ability to analyze small sample quantities. Our overall strategy is to maximize capability and minimize duplication, while bringing South Australia's NMR capabilities up to a national and international standard. Read moreRead less