Effects of Phase Purity, Porosity and Oxygen Partial Pressure on the Thermal Stability of Nanolayered Ternary Carbides. The successful completion of this collaborative research will lead to (a) enhanced understanding of the roles of phase purity, porosity and atmosphere on the thermal stability of ternary carbides which is crucial for the design of high-performance ternary carbide heating elements; (b) fostering and strengthening of the continuing research collaboration between Curtin University ....Effects of Phase Purity, Porosity and Oxygen Partial Pressure on the Thermal Stability of Nanolayered Ternary Carbides. The successful completion of this collaborative research will lead to (a) enhanced understanding of the roles of phase purity, porosity and atmosphere on the thermal stability of ternary carbides which is crucial for the design of high-performance ternary carbide heating elements; (b) fostering and strengthening of the continuing research collaboration between Curtin University and the Institute of Metals Research; (c) development of high performance prototype ternary carbide heating elements for use in high temperature furnaces and ovens; and (d) potential joint ventures with local suppliers of furnaces in Australia and China, together with Kanthal of Sweden to assist in the manufacture of ternary carbide heating elements. Read moreRead less
Synthesis of Novel Nanostructured Ternary Carbide Composites. This research will lead to (a) new advances and provide contribution of new knowledge to the Priority Research Areas of Advanced Materials; (b) a novel vacuum heat-treatment process for nanostructured materials design. This will offer the ceramics industry in Australia a new technology for producing wear- and heat-resistant components for advanced engineering applications. (c) design of new layer-graded materials with a unique combina ....Synthesis of Novel Nanostructured Ternary Carbide Composites. This research will lead to (a) new advances and provide contribution of new knowledge to the Priority Research Areas of Advanced Materials; (b) a novel vacuum heat-treatment process for nanostructured materials design. This will offer the ceramics industry in Australia a new technology for producing wear- and heat-resistant components for advanced engineering applications. (c) design of new layer-graded materials with a unique combination of hardness for wear resistance and toughness for damage tolerance. This will enable the ceramics industry in Australia to compete internationally in the business of advanced and high performance ceramic products.Read moreRead less
Damage micromechanisms in alumina hybrid bilayers with graded interfaces. This project proposes a new design concept for high performance alumina hybrids with graded interfaces. The key to this process is the incorporation of thin graded interfaces between an outer homogeneous alumina layer for strength, hardness and wear resistance, and an inner heterogeneous alumina hybrid layer for damage tolerance. The project will explore unresolved issues concerning the effect of graded interfaces on the f ....Damage micromechanisms in alumina hybrid bilayers with graded interfaces. This project proposes a new design concept for high performance alumina hybrids with graded interfaces. The key to this process is the incorporation of thin graded interfaces between an outer homogeneous alumina layer for strength, hardness and wear resistance, and an inner heterogeneous alumina hybrid layer for damage tolerance. The project will explore unresolved issues concerning the effect of graded interfaces on the failure micromechanisms. Advances in this area will provide new strategy or insights for designing novel next generation layered materials.Read moreRead less
Surface Polymorphism of Hard Brittle Materials. The knowledge gained from this project will be of great value in creating components of hard brittle materials with enhanced properties and expanded margins of application. The outcome will have impact on the ultra-precision manufacturing giving a competitive edge to the Australian fabrication industry. The fundamental knowledge gained from this project has the potential to facilitate the development of new devices and techniques such as those requ ....Surface Polymorphism of Hard Brittle Materials. The knowledge gained from this project will be of great value in creating components of hard brittle materials with enhanced properties and expanded margins of application. The outcome will have impact on the ultra-precision manufacturing giving a competitive edge to the Australian fabrication industry. The fundamental knowledge gained from this project has the potential to facilitate the development of new devices and techniques such as those required for bio-medical, photonic and electronic technologies.Read moreRead less
Engineering of Crystalline Ternary Ceramic Precursors. Ti3SiC2 belongs to a large group of ternary carbides that exhibit an unique combination of high temperature ceramic properties, with the electrical and thermal conductivity of metals. A great number of potential applications have been identified, but are currently limited by residual intermediate compounds, that degrade the properties. This project will use crystal structure similarities between TiCx and Ti3SiC2 to engineer a crystalline pre ....Engineering of Crystalline Ternary Ceramic Precursors. Ti3SiC2 belongs to a large group of ternary carbides that exhibit an unique combination of high temperature ceramic properties, with the electrical and thermal conductivity of metals. A great number of potential applications have been identified, but are currently limited by residual intermediate compounds, that degrade the properties. This project will use crystal structure similarities between TiCx and Ti3SiC2 to engineer a crystalline precursor, Ti3C2, which circumvents intermediate compound formation. This innovative methodology will also reduce the cost and time of fabrication. Advanced in-situ neutron diffraction techniques will be used to quantify the synthesis kinetics and optimize the method.Read moreRead less
A New Paradigm for the Solid State Synthesis of Layered Materials. Advanced ceramic materials with outstanding properties or combinations of properties are usually made from three (ternary) or more components. Their solid-state synthesis is hampered by the formation and retention of intermediate phases which degrade their performance. We have devised a method for circumventing intermediate phase formation in advanced materials and reducing synthesis temperatures by up to 600 degrees. This projec ....A New Paradigm for the Solid State Synthesis of Layered Materials. Advanced ceramic materials with outstanding properties or combinations of properties are usually made from three (ternary) or more components. Their solid-state synthesis is hampered by the formation and retention of intermediate phases which degrade their performance. We have devised a method for circumventing intermediate phase formation in advanced materials and reducing synthesis temperatures by up to 600 degrees. This project will explore the underlying atomic scale mechanism of the method. This knowledge will allow the low cost, low greenhouse gas emission synthesis of advanced ceramics for use in renewable, conventional and nuclear power generation.Read moreRead less
Engineering quantum-size bioceramics: Photocatalytic / sonocatalytic ceria. This project aims to design and engineer photocatalytic ceria of systematically controlled grain sizes and morphologies, using doping methods to achieve pure and mixed quantum confinement (which enhances performance). The intended outcomes of the computation, fabrication, and validation approach are a fundamental knowledge of the processing-performance matrix and reproducible photocatalysts of optimised performance. Whil ....Engineering quantum-size bioceramics: Photocatalytic / sonocatalytic ceria. This project aims to design and engineer photocatalytic ceria of systematically controlled grain sizes and morphologies, using doping methods to achieve pure and mixed quantum confinement (which enhances performance). The intended outcomes of the computation, fabrication, and validation approach are a fundamental knowledge of the processing-performance matrix and reproducible photocatalysts of optimised performance. While these ceramics will be applied as bioceramics, which can be activated by ultraviolet light, X-rays and ultrasound, the benefits will be applicable in energy (solar cells, photoelectrodes) and the environment (air and water purification).Read moreRead less
Atomistic mechanisms of the mechanical behaviour of nanostructured silicon carbide films. Advanced silicon carbide (SiC) ceramics are leading candidates for applications in high-power, high-speed machining and high-temperature structural components. Superhardness and high ductility (or high fracture toughness), which have been realized in some nanostructured (ns) SiC films and nanowires, respectively, are desirable properties for many applications. This project aims to understand the mechanisms ....Atomistic mechanisms of the mechanical behaviour of nanostructured silicon carbide films. Advanced silicon carbide (SiC) ceramics are leading candidates for applications in high-power, high-speed machining and high-temperature structural components. Superhardness and high ductility (or high fracture toughness), which have been realized in some nanostructured (ns) SiC films and nanowires, respectively, are desirable properties for many applications. This project aims to understand the mechanisms behind the exceptional properties in ns SiC and to explore the possibility of realizing the two properties in the same ns SiC. The results obtained from this research will be very important for guiding the structural design of SiC with exceptional mechanical properties which will have a wide range of structural applications.Read moreRead less
Design of hollow nanoparticles of titania for the sustainable production of hydrogen from water using sunlight. Hydrogen is a clean and non-polluting fuel that is the natural and sustainable replacement for greenhouse gas emitting fossil fuels. Because of its abundant sunlight and vast titanium reserves (the world's largest) Australia is especially well-placed to develop the technology of producing hydrogen directly from water and sunlight using a titanium dioxide photo-anode. This research, whi ....Design of hollow nanoparticles of titania for the sustainable production of hydrogen from water using sunlight. Hydrogen is a clean and non-polluting fuel that is the natural and sustainable replacement for greenhouse gas emitting fossil fuels. Because of its abundant sunlight and vast titanium reserves (the world's largest) Australia is especially well-placed to develop the technology of producing hydrogen directly from water and sunlight using a titanium dioxide photo-anode. This research, which consists of computational and experimental parts, is focused on laying the scientific foundation for that technology to be commercially viable. The national and community benefits are the availability of an inexpensive, limitless and clean fuel, reduction in reliance on energy imports, reduction in greenhouse gas emissions and resultant global warming.Read moreRead less
Unravelling the structural origin of cyclic fatigue in ferroelectrics. Ferroelectric materials have extensive applications in electromechanical devices and memories and in service are often subjected to repeat mechanical and/or electrical loading, leading to cyclic fatigue and failure. This project aims to apply in-situ electron microscopy techniques and computational modelling to explore cyclic ferroelectric fatigue behaviour and to understand the relationships between local atomic scale struct ....Unravelling the structural origin of cyclic fatigue in ferroelectrics. Ferroelectric materials have extensive applications in electromechanical devices and memories and in service are often subjected to repeat mechanical and/or electrical loading, leading to cyclic fatigue and failure. This project aims to apply in-situ electron microscopy techniques and computational modelling to explore cyclic ferroelectric fatigue behaviour and to understand the relationships between local atomic scale structure and fatigue. The structural origin of ferroelectric fatigue has not been clear because of the limitations of previous measurement capabilities. This project will provide guidance in materials design to increase ferroelectric fatigue lifetime for more reliable ferroelectric-based electronic devices.Read moreRead less