Surface Polymorphism of Hard Brittle Materials. The knowledge gained from this project will be of great value in creating components of hard brittle materials with enhanced properties and expanded margins of application. The outcome will have impact on the ultra-precision manufacturing giving a competitive edge to the Australian fabrication industry. The fundamental knowledge gained from this project has the potential to facilitate the development of new devices and techniques such as those requ ....Surface Polymorphism of Hard Brittle Materials. The knowledge gained from this project will be of great value in creating components of hard brittle materials with enhanced properties and expanded margins of application. The outcome will have impact on the ultra-precision manufacturing giving a competitive edge to the Australian fabrication industry. The fundamental knowledge gained from this project has the potential to facilitate the development of new devices and techniques such as those required for bio-medical, photonic and electronic technologies.Read moreRead less
Engineering of Crystalline Ternary Ceramic Precursors. Ti3SiC2 belongs to a large group of ternary carbides that exhibit an unique combination of high temperature ceramic properties, with the electrical and thermal conductivity of metals. A great number of potential applications have been identified, but are currently limited by residual intermediate compounds, that degrade the properties. This project will use crystal structure similarities between TiCx and Ti3SiC2 to engineer a crystalline pre ....Engineering of Crystalline Ternary Ceramic Precursors. Ti3SiC2 belongs to a large group of ternary carbides that exhibit an unique combination of high temperature ceramic properties, with the electrical and thermal conductivity of metals. A great number of potential applications have been identified, but are currently limited by residual intermediate compounds, that degrade the properties. This project will use crystal structure similarities between TiCx and Ti3SiC2 to engineer a crystalline precursor, Ti3C2, which circumvents intermediate compound formation. This innovative methodology will also reduce the cost and time of fabrication. Advanced in-situ neutron diffraction techniques will be used to quantify the synthesis kinetics and optimize the method.Read moreRead less
A New Paradigm for the Solid State Synthesis of Layered Materials. Advanced ceramic materials with outstanding properties or combinations of properties are usually made from three (ternary) or more components. Their solid-state synthesis is hampered by the formation and retention of intermediate phases which degrade their performance. We have devised a method for circumventing intermediate phase formation in advanced materials and reducing synthesis temperatures by up to 600 degrees. This projec ....A New Paradigm for the Solid State Synthesis of Layered Materials. Advanced ceramic materials with outstanding properties or combinations of properties are usually made from three (ternary) or more components. Their solid-state synthesis is hampered by the formation and retention of intermediate phases which degrade their performance. We have devised a method for circumventing intermediate phase formation in advanced materials and reducing synthesis temperatures by up to 600 degrees. This project will explore the underlying atomic scale mechanism of the method. This knowledge will allow the low cost, low greenhouse gas emission synthesis of advanced ceramics for use in renewable, conventional and nuclear power generation.Read moreRead less
Engineering quantum-size bioceramics: Photocatalytic / sonocatalytic ceria. This project aims to design and engineer photocatalytic ceria of systematically controlled grain sizes and morphologies, using doping methods to achieve pure and mixed quantum confinement (which enhances performance). The intended outcomes of the computation, fabrication, and validation approach are a fundamental knowledge of the processing-performance matrix and reproducible photocatalysts of optimised performance. Whil ....Engineering quantum-size bioceramics: Photocatalytic / sonocatalytic ceria. This project aims to design and engineer photocatalytic ceria of systematically controlled grain sizes and morphologies, using doping methods to achieve pure and mixed quantum confinement (which enhances performance). The intended outcomes of the computation, fabrication, and validation approach are a fundamental knowledge of the processing-performance matrix and reproducible photocatalysts of optimised performance. While these ceramics will be applied as bioceramics, which can be activated by ultraviolet light, X-rays and ultrasound, the benefits will be applicable in energy (solar cells, photoelectrodes) and the environment (air and water purification).Read moreRead less
Atomistic mechanisms of the mechanical behaviour of nanostructured silicon carbide films. Advanced silicon carbide (SiC) ceramics are leading candidates for applications in high-power, high-speed machining and high-temperature structural components. Superhardness and high ductility (or high fracture toughness), which have been realized in some nanostructured (ns) SiC films and nanowires, respectively, are desirable properties for many applications. This project aims to understand the mechanisms ....Atomistic mechanisms of the mechanical behaviour of nanostructured silicon carbide films. Advanced silicon carbide (SiC) ceramics are leading candidates for applications in high-power, high-speed machining and high-temperature structural components. Superhardness and high ductility (or high fracture toughness), which have been realized in some nanostructured (ns) SiC films and nanowires, respectively, are desirable properties for many applications. This project aims to understand the mechanisms behind the exceptional properties in ns SiC and to explore the possibility of realizing the two properties in the same ns SiC. The results obtained from this research will be very important for guiding the structural design of SiC with exceptional mechanical properties which will have a wide range of structural applications.Read moreRead less
Design of hollow nanoparticles of titania for the sustainable production of hydrogen from water using sunlight. Hydrogen is a clean and non-polluting fuel that is the natural and sustainable replacement for greenhouse gas emitting fossil fuels. Because of its abundant sunlight and vast titanium reserves (the world's largest) Australia is especially well-placed to develop the technology of producing hydrogen directly from water and sunlight using a titanium dioxide photo-anode. This research, whi ....Design of hollow nanoparticles of titania for the sustainable production of hydrogen from water using sunlight. Hydrogen is a clean and non-polluting fuel that is the natural and sustainable replacement for greenhouse gas emitting fossil fuels. Because of its abundant sunlight and vast titanium reserves (the world's largest) Australia is especially well-placed to develop the technology of producing hydrogen directly from water and sunlight using a titanium dioxide photo-anode. This research, which consists of computational and experimental parts, is focused on laying the scientific foundation for that technology to be commercially viable. The national and community benefits are the availability of an inexpensive, limitless and clean fuel, reduction in reliance on energy imports, reduction in greenhouse gas emissions and resultant global warming.Read moreRead less
Unravelling the structural origin of cyclic fatigue in ferroelectrics. Ferroelectric materials have extensive applications in electromechanical devices and memories and in service are often subjected to repeat mechanical and/or electrical loading, leading to cyclic fatigue and failure. This project aims to apply in-situ electron microscopy techniques and computational modelling to explore cyclic ferroelectric fatigue behaviour and to understand the relationships between local atomic scale struct ....Unravelling the structural origin of cyclic fatigue in ferroelectrics. Ferroelectric materials have extensive applications in electromechanical devices and memories and in service are often subjected to repeat mechanical and/or electrical loading, leading to cyclic fatigue and failure. This project aims to apply in-situ electron microscopy techniques and computational modelling to explore cyclic ferroelectric fatigue behaviour and to understand the relationships between local atomic scale structure and fatigue. The structural origin of ferroelectric fatigue has not been clear because of the limitations of previous measurement capabilities. This project will provide guidance in materials design to increase ferroelectric fatigue lifetime for more reliable ferroelectric-based electronic devices.Read moreRead less
Ceramic matrix nanocomposites. Using a novel process developed by the applicant, this project will create and study ceramic matrix nanocomposites of two types: (i) those in which the nanoparticles are homogeneously distributed in alumina and (ii) functionally-graded nanocomposites of controlled heterogeneity, that is, nanocomposites in which the nanoparticles are distributed heterogeneously in glass. Homogeneous nanocomposites of alumina are potentially of great importance to the mining industry ....Ceramic matrix nanocomposites. Using a novel process developed by the applicant, this project will create and study ceramic matrix nanocomposites of two types: (i) those in which the nanoparticles are homogeneously distributed in alumina and (ii) functionally-graded nanocomposites of controlled heterogeneity, that is, nanocomposites in which the nanoparticles are distributed heterogeneously in glass. Homogeneous nanocomposites of alumina are potentially of great importance to the mining industry as they can increase the toughness and wear resistance of mining components. Heterogeneous nanocomposities have the potential to revolutionise the dental restoration industry by combining greatly increased toughness with the aesthetic benefit of controllable translucency.Read moreRead less
Computational design of titanium dioxide-based ceramics for the renewable energy technology platform: Solar-Hydrogen. Hydrogen is a clean non-polluting fuel. Production of hydrogen (Solar-Hydrogen) directly from water and sunlight is a very appealing renewable energy technology. The key requirement to allow this technology to be adopted is finding an electrically suitable material. This research program takes an innovative approach by combining state of the art computational techniques to engine ....Computational design of titanium dioxide-based ceramics for the renewable energy technology platform: Solar-Hydrogen. Hydrogen is a clean non-polluting fuel. Production of hydrogen (Solar-Hydrogen) directly from water and sunlight is a very appealing renewable energy technology. The key requirement to allow this technology to be adopted is finding an electrically suitable material. This research program takes an innovative approach by combining state of the art computational techniques to engineer advanced ceramics having sophisticated electrical signatures. These ceramics will be synthesized in a partner experimental program to gauge their efficiencies for hydrogen production. The program will provide the foundation for a renewable energy technology that will provide clean energy and energy independence for Australia.Read moreRead less
Fibre-reinforced composites: Single-crystal mullite fibres from topaz. The project aims to develop the means of fabricating single-crystal mullite fibres from topaz that are suitable for reinforcement of metal and ceramic matrix composites. Single-crystal mullite is the most sought after fibrous additive, but is not available commercially. It is expected to attract an immediate clientele in laboratories and companies servicing the aviation industry and the military. This will allow large depos ....Fibre-reinforced composites: Single-crystal mullite fibres from topaz. The project aims to develop the means of fabricating single-crystal mullite fibres from topaz that are suitable for reinforcement of metal and ceramic matrix composites. Single-crystal mullite is the most sought after fibrous additive, but is not available commercially. It is expected to attract an immediate clientele in laboratories and companies servicing the aviation industry and the military. This will allow large deposit of topaz in Torrington, NSW to be used to develop a high-value niche product (fibres) and a large-volume, low-value product (fluoride). This will provide significant economic and environmental benefits and it addresses the research priorities - Resources and Advanced Manufacturing.Read moreRead less