Novel fuel-cell structures based on electroactive polymers. This project will tackle some of the challenges currently hindering progression of our society into a post-petroleum era via materials developments that will lead to in-expensive, more efficient fuel cell technologies. Specifically, a new class of organic catalysts and novel ion conducting membranes will be integrated into functional fuel-cells.
Engineering the Microstructure of Electrodes for Advanced Fuel Cells. A polymer solution-based integration technique is proposed to be developed to fabricate polymer electrolyte membrane fuel cells, allowing for effective engineering of the porous networks and interfaces within electrodes and cells. This novel systems materials engineering approach is expected to overcome the drawbacks of the conventional hot pressing method, enabling precise integration of nanostructured electrodes and membrane ....Engineering the Microstructure of Electrodes for Advanced Fuel Cells. A polymer solution-based integration technique is proposed to be developed to fabricate polymer electrolyte membrane fuel cells, allowing for effective engineering of the porous networks and interfaces within electrodes and cells. This novel systems materials engineering approach is expected to overcome the drawbacks of the conventional hot pressing method, enabling precise integration of nanostructured electrodes and membrane into high-performance, flexible fuel cells. The outcomes of this research aim to provide a unique opportunity for Australia to become a world leader in the rapidly-emerging clean energy technology, and critical manufacturing of new energy generation systems for domestic uses and exports, thereby producing important economic benefits.Read moreRead less
High Performance Monolithic Perovskite Photocapacitors. Monolithic perovskite photocapacitor (MPPC) consisted of integrated energy harvesting perovskite solar cell and energy storage supercapacitor through an internally shared electrode can deliver stable electricity by harnessing solar energy. The performance of MPPC is dependent of properties of the shared electrode materials. This project aims to synthesis carbon materials with tailored surface, electrical and structure properties that are re ....High Performance Monolithic Perovskite Photocapacitors. Monolithic perovskite photocapacitor (MPPC) consisted of integrated energy harvesting perovskite solar cell and energy storage supercapacitor through an internally shared electrode can deliver stable electricity by harnessing solar energy. The performance of MPPC is dependent of properties of the shared electrode materials. This project aims to synthesis carbon materials with tailored surface, electrical and structure properties that are required to make a highly functioning shared electrode in MPPC. The goal is to fabricate stable, high performance MPPC. Successful achievement of the outcomes will enable cost-effective, reliable, solar electricity, placing Australia at the forefront of exploiting photovoltaics technologies.Read moreRead less
Cadmium telluride/Germanium (CdTe/Ge) tandem-junction solar cells for efficiency enhancement in thin-film photovoltaics. The purpose of this project is to improve the efficiency of large-area, thin-film CdTe solar cells by using them in a tandem arrangement with thin-film Ge cells. An increase of 25 per cent in efficiency appears possible, which would greatly improve the prospects for cost-competitive photovoltaic power generation.
Bandgap engineered mercury cadmium telluride heterostructures on gallium antimonide alternative substrates. This project aims to develop bandgap engineered mercury cadmium telluride heterostructures on gallium antimonide alternative substrates to enable high performance lower-cost infrared sensors with high yield, large array size, multiband detection and higher operating temperature. High performance infrared sensors and systems are core enabling technologies in civilian and defence application ....Bandgap engineered mercury cadmium telluride heterostructures on gallium antimonide alternative substrates. This project aims to develop bandgap engineered mercury cadmium telluride heterostructures on gallium antimonide alternative substrates to enable high performance lower-cost infrared sensors with high yield, large array size, multiband detection and higher operating temperature. High performance infrared sensors and systems are core enabling technologies in civilian and defence applications such as remote sensing, environmental monitoring, night vision and national security. This project expects to research into defect generation mechanisms in epitaxial growth of semiconducting mercury cadmium telluride on lattice mismatched substrates. This is expected to contribute to Australian industry sectors, thereby benefiting the Australian economy, society, environment, and national security.Read moreRead less
New carbon nanotube electrocatalysts for water splitting and fuel cells. The demand for clean, secure and sustainable energy sources has stimulated great interest in electrochemical energy storage and conversion technologies such as water splitting and fuel cells. The efficiency of water splitting and fuel cells is however strongly dependent on the activity of the electrocatalysts. The objective of the project is to develop new electrocatalysts based on the recently discovered phenomena that car ....New carbon nanotube electrocatalysts for water splitting and fuel cells. The demand for clean, secure and sustainable energy sources has stimulated great interest in electrochemical energy storage and conversion technologies such as water splitting and fuel cells. The efficiency of water splitting and fuel cells is however strongly dependent on the activity of the electrocatalysts. The objective of the project is to develop new electrocatalysts based on the recently discovered phenomena that carbon nanotubes with specific size and number of walls are very active and significantly promote the reaction of water splitting and fuel cells. The proposed project is expected to open a new research field in the development of new electrocatalysts and photoelectrocatalysts for advanced energy conversion and storage technologies.Read moreRead less
Corrosion of heat resisting alloys in steam/hydrogen-rich environment . Hydrogen is a clean fuel for energy future. Its production and utilisation unavoidably involve water vapour and hydrogen at high temperature which is however corrosive to materials used in the system. This project aims to investigate corrosion behaviour of heat resistant alloys in the presence of both hydrogen and water vapour, mechanisms of water transport in oxide scale, and the effect of hydrogen on water vapour corrosion ....Corrosion of heat resisting alloys in steam/hydrogen-rich environment . Hydrogen is a clean fuel for energy future. Its production and utilisation unavoidably involve water vapour and hydrogen at high temperature which is however corrosive to materials used in the system. This project aims to investigate corrosion behaviour of heat resistant alloys in the presence of both hydrogen and water vapour, mechanisms of water transport in oxide scale, and the effect of hydrogen on water vapour corrosion. Alloying effects on corrosion rates will be defined and methods of slowing or preventing water vapour corrosion in the presence of hydrogen will be devised. The results will provide a basis for improved design/selection of heat resisting alloys for hydrogen production and hydrogen utilisation industries.Read moreRead less
Oxide-based high temperature proton exchange membrane fuel cells. Proton exchange membrane fuel cells (PEMFCs) are one of the most efficient energy conversion technologies for producing electricity from fuels such as hydrogen and methanol. Current PEMFCs use precious metal catalysts, and the performance of liquid methanol fuel is disappointingly low due to the inability of polymer or hybrid membranes to operate at temperatures above 160-180 degrees centigrade. This work aims to develop an all ox ....Oxide-based high temperature proton exchange membrane fuel cells. Proton exchange membrane fuel cells (PEMFCs) are one of the most efficient energy conversion technologies for producing electricity from fuels such as hydrogen and methanol. Current PEMFCs use precious metal catalysts, and the performance of liquid methanol fuel is disappointingly low due to the inability of polymer or hybrid membranes to operate at temperatures above 160-180 degrees centigrade. This work aims to develop an all oxide-based PEMFC technology using a recently developed sintered and heteropolyacid functionalised mesoporous silica membrane. The utilisation of all-oxide-PEMFCs using non-precious metal catalysts is expected to significantly enhance the power density, reduce costs, and enhance the commercial viability of PEMFC technologies.Read moreRead less
Defect generation in hetero-epitaxy on lattice mismatched substrates. High quality lattice mismatched semiconductor heterostructures are core enabling technologies for next generation electronic and optoelectronic devices with new functions and features such as monolithic integration, lower production costs, larger wafer size, and better system robustness. This project will generate new science on defect generation in lattice mismatched hetero-epitaxy with the aim of developing novel strategies ....Defect generation in hetero-epitaxy on lattice mismatched substrates. High quality lattice mismatched semiconductor heterostructures are core enabling technologies for next generation electronic and optoelectronic devices with new functions and features such as monolithic integration, lower production costs, larger wafer size, and better system robustness. This project will generate new science on defect generation in lattice mismatched hetero-epitaxy with the aim of developing novel strategies for their minimisation. The direct outcome will be higher quality HgCdTe materials on lattice mismatched Si or III-V substrates with defect density low enough for fabricating high performance mid-wave and long-wave infrared arrays with features of lower cost, larger array format size, and higher operating temperature.Read moreRead less
Efficient photovoltaic-electrochemical water splitting for clean hydrogen. This project aims to develop a novel, low cost and high performance monolithic photovoltaic-electrochemical (PV-EC) device for clean hydrogen production. This device tailors and integrates low cost and high performance thin film and tandem photovoltaics for water splitting with the aim of achieving high solar to hydrogen conversion efficiency towards 20%. Earth abundant and stable catalysts will be developed in this proje ....Efficient photovoltaic-electrochemical water splitting for clean hydrogen. This project aims to develop a novel, low cost and high performance monolithic photovoltaic-electrochemical (PV-EC) device for clean hydrogen production. This device tailors and integrates low cost and high performance thin film and tandem photovoltaics for water splitting with the aim of achieving high solar to hydrogen conversion efficiency towards 20%. Earth abundant and stable catalysts will be developed in this project to replace noble based catalysts, as well as novel architectures for electrical contacting, feed-through and catalyst integration in PV-EC devices. These innovations offer high performance and the potential for device costs 2 to 3 orders of magnitude lower than recent world record photoelectrochemical devices. Read moreRead less