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Development of a New Type of Large-Area Robust Superhydrophobic Surfaces (MWN). Electrochemical manipulation will be used to produce robust metal surfaces of controlled roughness and characteristic size of the surface features in the 10-1000 nanometre range. Subsequent surface modification (e.g. self-assembled monolayers, silane chemisorption, plasma polymer deposition) will render these surfaces superhydrophobic. The surfaces will have highly depressed adhesion properties and hence a significan ....Development of a New Type of Large-Area Robust Superhydrophobic Surfaces (MWN). Electrochemical manipulation will be used to produce robust metal surfaces of controlled roughness and characteristic size of the surface features in the 10-1000 nanometre range. Subsequent surface modification (e.g. self-assembled monolayers, silane chemisorption, plasma polymer deposition) will render these surfaces superhydrophobic. The surfaces will have highly depressed adhesion properties and hence a significantly improved chemical resistance and corrosion stability. A viable procedure for the making of polymer imprints from the metal surfaces will be developed. This will form the basis of a new method for cheap fabrication of various superhydrophobic surfaces with large areas and specific functionality.Read moreRead less
Correlation between surface force and morphology of self-assembled monolayer. As a most potential solid support for biological molecules without denaturing their functions, gold thiol self-assembled monolayers (SAMs) have been studied extensively for surface fabrication. In this project we will prepare functional monolayers using newly synthesized thiol derivatives, evaluate correlation between surface force and surface morphology of the SAMs using the surface forces apparatus, and optimize the ....Correlation between surface force and morphology of self-assembled monolayer. As a most potential solid support for biological molecules without denaturing their functions, gold thiol self-assembled monolayers (SAMs) have been studied extensively for surface fabrication. In this project we will prepare functional monolayers using newly synthesized thiol derivatives, evaluate correlation between surface force and surface morphology of the SAMs using the surface forces apparatus, and optimize the condition to fabricate biological devices such as immune sensors.Read moreRead less
Synthesis of substrate analogues for probing catalytic mechanisms and specificity of enzymes involved in the metabolism of plant polysaccharides. The project is aimed at strengthening collaborations between research groups in Adelaide and France, with the specific objective of synthesizing substrate analogues as probes of enzymatic mechanisms and substrate specificity in polysaccharide hydrolases and synthases of barley. The chemical expertise resides in France, while the enzymatic work will be ....Synthesis of substrate analogues for probing catalytic mechanisms and specificity of enzymes involved in the metabolism of plant polysaccharides. The project is aimed at strengthening collaborations between research groups in Adelaide and France, with the specific objective of synthesizing substrate analogues as probes of enzymatic mechanisms and substrate specificity in polysaccharide hydrolases and synthases of barley. The chemical expertise resides in France, while the enzymatic work will be conducted largely in Australia. Exchange of research staff, particularly at the postgraduate student and research associate levels, is considered essential to capture the benefits of the complementary expertise and to extend an existing international collaboration. The target enzymes are of central importance in cell wall metabolism during development of higher plants.Read moreRead less