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Synthetic and theoretical studies of metal complexes containing carbon-rich ligands. Previous studies in my group, in conjunction with synthetic and theoretical chemistry groups at the Université de Rennes 1, France, have delineated the properties of a series of complexes containing carbon chains linking two metal centres. Having achieved a partial understanding of the features which result in good electronic communication between the metal centres via the carbon chain, the present proposal see ....Synthetic and theoretical studies of metal complexes containing carbon-rich ligands. Previous studies in my group, in conjunction with synthetic and theoretical chemistry groups at the Université de Rennes 1, France, have delineated the properties of a series of complexes containing carbon chains linking two metal centres. Having achieved a partial understanding of the features which result in good electronic communication between the metal centres via the carbon chain, the present proposal seeks to extend this collaboration to further studies which will generate related compounds in which actual eletron exchange can occur, i.e. leading to oxidation/reduction, by using compounds in which two or more different metal centres are present. This may lead to development of nano devices, e.g. molecular-scale switches. If one of the centres is activated by light, a photo-active sensor may result.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0989127
Funder
Australian Research Council
Funding Amount
$400,000.00
Summary
A High-Throughput Neutron Spectrometer for The Study of Atomic and Molecular Motion at ANSTO. Neutron scattering enables new science across a broad range of disciplines, and for this reason it is undergoing major expansion in the USA, Europe, Japan and Australia. Various diffactometers and spectrometers have recently been built at ANSTO, but an instrumental option for a high-throughput cross-discipline spectroscopy is urgently needed. Fortunately, it is fairly straightforward to add this type of ....A High-Throughput Neutron Spectrometer for The Study of Atomic and Molecular Motion at ANSTO. Neutron scattering enables new science across a broad range of disciplines, and for this reason it is undergoing major expansion in the USA, Europe, Japan and Australia. Various diffactometers and spectrometers have recently been built at ANSTO, but an instrumental option for a high-throughput cross-discipline spectroscopy is urgently needed. Fortunately, it is fairly straightforward to add this type of option to an existing spectrometer that will broaden its user-base from specialised applications in physics to more general applications in physics, chemistry, materials-science and biology. This additional option provides a totally new way for Australian scientists to study atomic and molecular motions. Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0668017
Funder
Australian Research Council
Funding Amount
$1,047,000.00
Summary
Membrane Protein Structure and Interaction Facility. While it is estimated that a third of the human genome encodes for membrane proteins, the structures of only relatively few membrane proteins are currently known. It will be some time before membrane protein structure determination becomes routine, yet over 50% of the drugs on the market today rely on the activity of membrane proteins for their efficacy. This application seeks to establish a Membrane Protein Structure and Interaction Facility ....Membrane Protein Structure and Interaction Facility. While it is estimated that a third of the human genome encodes for membrane proteins, the structures of only relatively few membrane proteins are currently known. It will be some time before membrane protein structure determination becomes routine, yet over 50% of the drugs on the market today rely on the activity of membrane proteins for their efficacy. This application seeks to establish a Membrane Protein Structure and Interaction Facility for the development and application of novel techniques and approaches to study the structure and interactions of membrane proteins. Research progress will be greatly enhanced by the establishment of this dedicated facility with cutting-edge technologies for the study of membrane proteins.Read moreRead less
Synthesis and Fundamental Understanding of Low-Dimensional Metal Oxide Nanoparticles for Gas Sensing Application. This project is primarily devoted to material science and nanotechnology, one of the cutting-edge areas in Australia's National Research Priority. Successful completion of this project will result in controlled synthesis, functional assembly and fundamental understanding of low-dimensional metal oxide nanostructures. The research findings will be useful for developing new and complex ....Synthesis and Fundamental Understanding of Low-Dimensional Metal Oxide Nanoparticles for Gas Sensing Application. This project is primarily devoted to material science and nanotechnology, one of the cutting-edge areas in Australia's National Research Priority. Successful completion of this project will result in controlled synthesis, functional assembly and fundamental understanding of low-dimensional metal oxide nanostructures. The research findings will be useful for developing new and complex nanostructures for functional applications in lithium ionic batteries, catalysts and gas sensors. The conduct of this project will significantly expand the knowledge creativity of Australia in advanced materials.
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Understanding, prediction and control of polymorphism in pharmaceuticals. The proposed research will lead, through a better understanding of polymorphism, to more efficient production of pharmaceuticals and will enhance the establishment and protection of patents. The work will have flow-on in other areas such as the manufacture of pigments, dyes and explosives. The project uses methodology for the elucidation of local structure and function at the atomic to nanoscale level in which Australia is ....Understanding, prediction and control of polymorphism in pharmaceuticals. The proposed research will lead, through a better understanding of polymorphism, to more efficient production of pharmaceuticals and will enhance the establishment and protection of patents. The work will have flow-on in other areas such as the manufacture of pigments, dyes and explosives. The project uses methodology for the elucidation of local structure and function at the atomic to nanoscale level in which Australia is a world leader. The project will further enhance our standing in this field and will provide excellent research training opportunities in areas particularly pertinent to future exploitation of the Australian Synchrotron and the new Research Reactor OPAL, which open in 2007. Read moreRead less
Nanoporous bioaffinity adsorbents for separations in the pharmaceutical industry. This proposal aims to develop new high performance adsorbents for bioprocess engineering based on templated nanoporous silica materials. This research will lead to significant advances in advanced materials and adsorbent technology, downstream processing for the biotechnology industries, and understanding of highly specific affinity interactions used for difficult bioseparations. It will have important benefits for ....Nanoporous bioaffinity adsorbents for separations in the pharmaceutical industry. This proposal aims to develop new high performance adsorbents for bioprocess engineering based on templated nanoporous silica materials. This research will lead to significant advances in advanced materials and adsorbent technology, downstream processing for the biotechnology industries, and understanding of highly specific affinity interactions used for difficult bioseparations. It will have important benefits for processes involving protein purification, such as bioplasma processing, as well as flow on effects to other applications of adsorbent technology such as food processing and water treatment. The new adsorbents will lead to reductions in the costs, energy usage and waste generation of Australian industries.Read moreRead less
Pre-blast screening of improvised explosive devices - a National counter-terrorism initiative. The proposed research is focused on the specific needs of Australian counter-terrorism interests, including those of border protection, the customs service, transport authorities, forensic laboratories, etc. The support of this proposal will ensure that Australia, and its States and Territories are protected against terrorist threats. The support provided by the collaborating organisations from the var ....Pre-blast screening of improvised explosive devices - a National counter-terrorism initiative. The proposed research is focused on the specific needs of Australian counter-terrorism interests, including those of border protection, the customs service, transport authorities, forensic laboratories, etc. The support of this proposal will ensure that Australia, and its States and Territories are protected against terrorist threats. The support provided by the collaborating organisations from the various Federal and State police and forensic agencies, and the customs service, etc, highlights the importance of this project to the nation. Finally, a PhD student and a research assistant will be involved with the project and will gain specialised skills positioning them to make strong contributions to Australia's counter-terrorism measures.Read moreRead less
Reactions of Coordinated Dinitrogen. The program will develop novel metal-based catalysts and reagents that will transform nitrogen gas into ammonia and other nitrogen-containing compounds (nitrogen fixation). This fundamental chemical transformation underpins major chemical industries and this new approach using organometallic catalysts will significantly improve the efficiency of ammonia production and reduce the energy and harsh reaction conditions currently required. This program will desi ....Reactions of Coordinated Dinitrogen. The program will develop novel metal-based catalysts and reagents that will transform nitrogen gas into ammonia and other nitrogen-containing compounds (nitrogen fixation). This fundamental chemical transformation underpins major chemical industries and this new approach using organometallic catalysts will significantly improve the efficiency of ammonia production and reduce the energy and harsh reaction conditions currently required. This program will design catalysts with multiple complementary metal centres tailored to bind and activate nitrogen gas to facilitate its reaction with hydrogen or other reagents.Read moreRead less
Materials World Network: Nanostructured Polymer Templating of Liquid Crystals. Liquid crystals have a range of technological applications, with the most successful being displays used in computers, watches and calculators. These applications are dependent on controlling the interfaces of liquid crystals. This project will combine the areas of liquid crystals and polymer adsorption for the preparation of a new class of intelligent nanomaterials with well-defined properties. These engineered mater ....Materials World Network: Nanostructured Polymer Templating of Liquid Crystals. Liquid crystals have a range of technological applications, with the most successful being displays used in computers, watches and calculators. These applications are dependent on controlling the interfaces of liquid crystals. This project will combine the areas of liquid crystals and polymer adsorption for the preparation of a new class of intelligent nanomaterials with well-defined properties. These engineered materials are of interest in industrial applications, including the development of chemical and biological sensors and drug delivery vehicles. This program also strengthens the ties between two world-class nanotechnology groups, capturing new opportunities in nanostructured materials.Read moreRead less
Lipid and Carbohydrate Based Systems to Target and Deliver Peptide Drug Candidates to Specific Cells. The demand for novel effective, orally available medicines to treat a wide range of diseases (cancer, pain - ageing Australian population) is increasing exponentially. Conjugation of peptide drug or vaccine candidates with lipids and/or sugars represents an important, novel strategy in the drug delivery and targeting field. Increasing the lipophilicity improves absorption through intestinal muco ....Lipid and Carbohydrate Based Systems to Target and Deliver Peptide Drug Candidates to Specific Cells. The demand for novel effective, orally available medicines to treat a wide range of diseases (cancer, pain - ageing Australian population) is increasing exponentially. Conjugation of peptide drug or vaccine candidates with lipids and/or sugars represents an important, novel strategy in the drug delivery and targeting field. Increasing the lipophilicity improves absorption through intestinal mucosal membranes. The carbohydrates increase the compound's aqueous solubility and can utilize active transport systems and can target the site required for its biological function. There is no limit to the areas of medicine and public health that would benefit from this revolutionary new technology.Read moreRead less