Design of Nanoporous BCN with Tunable Pores for CO2 Capture and Conversion. This project aims to design and develop advanced boron carbon nitride-based materials with high specific surface areas, tunable pores and functional groups, guided by theoretical calculations for the capture of CO2 at ambient conditions. By introducing single metal atoms in the above nanostructures, we also aim to design a novel catalytic system for the effective conversion of CO2 into fine chemicals. This project will o ....Design of Nanoporous BCN with Tunable Pores for CO2 Capture and Conversion. This project aims to design and develop advanced boron carbon nitride-based materials with high specific surface areas, tunable pores and functional groups, guided by theoretical calculations for the capture of CO2 at ambient conditions. By introducing single metal atoms in the above nanostructures, we also aim to design a novel catalytic system for the effective conversion of CO2 into fine chemicals. This project will offer new knowledge on the design of low-cost advanced materials with specific functionalities for the simultaneous capture and conversion of CO2. This project will make a significant impact on Australian industries and further offer job opportunities and economic benefits by offering new technologies for a clean environment.Read moreRead less
Tandem Photocatalytic Conversion of CO2 to High Value Hydrocarbon Products. Converting carbon dioxide (CO2) into hydrocarbon products is ideal for combating anthropogenic emissions whilst reducing our reliance on fossil fuels. Despite the significant advantages, CO2 valorisation is hindered by barriers such as high energy requirements and low-value products (methane and carbon monoxide). This project will establish a sustainable approach to CO2 valorisation using a unique tandem solar-driven hie ....Tandem Photocatalytic Conversion of CO2 to High Value Hydrocarbon Products. Converting carbon dioxide (CO2) into hydrocarbon products is ideal for combating anthropogenic emissions whilst reducing our reliance on fossil fuels. Despite the significant advantages, CO2 valorisation is hindered by barriers such as high energy requirements and low-value products (methane and carbon monoxide). This project will establish a sustainable approach to CO2 valorisation using a unique tandem solar-driven hierarchical catalyst array to offset energy requirements and directly yield high-value hydrocarbon products, such as ethane (C2H6) and ethanol (CH3CH2OH), from captured CO2.Read moreRead less
Novel conversion process for carbon dioxide to chemicals. This project aims to develop a novel sorption enhanced material and system to convert atmospheric carbon dioxide (CO2) to methanol. Climate change is one of the primary long-term problems confronting humankind today. Since the production of CO2 through burning fossil fuel is far greater than the current usage of CO2, there is currently little alternative to storage. As a result, there is concerted effort globally to develop alternate use ....Novel conversion process for carbon dioxide to chemicals. This project aims to develop a novel sorption enhanced material and system to convert atmospheric carbon dioxide (CO2) to methanol. Climate change is one of the primary long-term problems confronting humankind today. Since the production of CO2 through burning fossil fuel is far greater than the current usage of CO2, there is currently little alternative to storage. As a result, there is concerted effort globally to develop alternate uses and conversion technologies for CO2. This project will help further this goal.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE150100820
Funder
Australian Research Council
Funding Amount
$390,000.00
Summary
Nanowire photoelectrodes for carbon dioxide conversion. Returning carbon dioxide (CO2) to a useful state is a significant and challenging problem which requires appropriate devices and energy input. By utilising sunlight as a promising and green energy input, the conversion of CO2 into liquid fuel would positively impact the global carbon balance. This project aims to prepare abundant, non-toxic and sufficiently active photoelectrodes with one dimensional nanostructure, then develop appropriate ....Nanowire photoelectrodes for carbon dioxide conversion. Returning carbon dioxide (CO2) to a useful state is a significant and challenging problem which requires appropriate devices and energy input. By utilising sunlight as a promising and green energy input, the conversion of CO2 into liquid fuel would positively impact the global carbon balance. This project aims to prepare abundant, non-toxic and sufficiently active photoelectrodes with one dimensional nanostructure, then develop appropriate and robust photoelectrochemical devices to convert CO2 into liquid fuels. This project aims to help reduce the atmospheric CO2 concentrations and explore a new energy source.Read moreRead less
Designing high performance gas separation by interfacial diffusion membrane. This project aims to develop a new generation of interfacial diffusion membranes for industrial gas separations including carbon dioxide removal, nitrogen gas enrichment, methane purification and air separation. The project focuses on advancing separation technologies for the petrochemical, natural gas, and clean energy industries in the mining sector. The project is expected to reveal new separation properties and perf ....Designing high performance gas separation by interfacial diffusion membrane. This project aims to develop a new generation of interfacial diffusion membranes for industrial gas separations including carbon dioxide removal, nitrogen gas enrichment, methane purification and air separation. The project focuses on advancing separation technologies for the petrochemical, natural gas, and clean energy industries in the mining sector. The project is expected to reveal new separation properties and performance based on highly selective interfacial diffusion membranes. The project will also create new scientific knowledge about the role of functional surfaces and nanostructures that will not only facilitate new membrane designs but also offer new, more cost-effective devices for solar conversion, energy storage and harvesting, biomedical applications, sensing and information technology.Read moreRead less
Engineering the Building Blocks of Novel Interfacial Metastable Oxide Materials. This project aims to engineer the building blocks of a new family of materials recently discovered and patented as interfacial metastable oxide (i-MOx). A key discovery is the interfacial columnar atom alignment adjacent to crystal structures, conferring the materials exceptional ionic conduction well beyond the state-of-the-art, with a broad appeal to ionic transport membranes, electrodes in fuel cells and thermal ....Engineering the Building Blocks of Novel Interfacial Metastable Oxide Materials. This project aims to engineer the building blocks of a new family of materials recently discovered and patented as interfacial metastable oxide (i-MOx). A key discovery is the interfacial columnar atom alignment adjacent to crystal structures, conferring the materials exceptional ionic conduction well beyond the state-of-the-art, with a broad appeal to ionic transport membranes, electrodes in fuel cells and thermal cycling oxygen production. Advanced characterisation techniques will be employed to fundamentally elucidate the role that the interfacial structure plays to deliver remarkable performance. The outcomes will lead to possible breakthroughs in advanced materials for emerging green energy applications.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE140101094
Funder
Australian Research Council
Funding Amount
$395,220.00
Summary
Precision Spectroscopy of CO2 Exchange in Hydrates for Clean Energy Production. Carbon dioxide capture and sequestration is a widely considered climate change mitigation strategy. Clathrate hydrates of natural gas, found in deep-water ocean sediments, represent a tremendous opportunity for simultaneous carbon dioxide sequestration and clean energy production. By injecting carbon dioxide into the hydrate reservoir, methane can be displaced and replaced by carbon dioxide. This project will use Ram ....Precision Spectroscopy of CO2 Exchange in Hydrates for Clean Energy Production. Carbon dioxide capture and sequestration is a widely considered climate change mitigation strategy. Clathrate hydrates of natural gas, found in deep-water ocean sediments, represent a tremendous opportunity for simultaneous carbon dioxide sequestration and clean energy production. By injecting carbon dioxide into the hydrate reservoir, methane can be displaced and replaced by carbon dioxide. This project will use Raman spectroscopy and nuclear magnetic resonance imaged core-flood experiments to develop a fundamental understanding of the exchange mechanisms governing the replacement of the methane molecule in the hydrate cage with carbon dioxide. This knowledge will be critical for future development of these resources to safely extract methane from sub-sea hydrates.Read moreRead less
Novel Characterization of Porous Structure and Surface Chemistry of Carbon. The aim of this project is to develop novel characterisation methods that probe the structure and surface chemistry of carbons, ranging from highly graphitised thermal carbon black through ordered mesoporous carbon to disordered porous activated carbon. The project plans to develop a new generic molecular model based on wedge-shaped pores. Conventional parallel sided pore models fail to account for real structures and th ....Novel Characterization of Porous Structure and Surface Chemistry of Carbon. The aim of this project is to develop novel characterisation methods that probe the structure and surface chemistry of carbons, ranging from highly graphitised thermal carbon black through ordered mesoporous carbon to disordered porous activated carbon. The project plans to develop a new generic molecular model based on wedge-shaped pores. Conventional parallel sided pore models fail to account for real structures and therefore for the physics of adsorption in real materials. The project then plans to back the theoretical model with high-resolution experimental measurements. It is expected that the model will unify the structural analysis for all carbons and account for all experimental isotherms within a rational and physically plausible framework.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE210100680
Funder
Australian Research Council
Funding Amount
$423,275.00
Summary
Solar electrolysis for manufacture of sustainable energy storage materials. This project aims to develop a novel solar-driven manufacturing process able to produce advanced carbon materials which effectively sequester carbon dioxide (negative emission). The project expects to provide key data and insights into a new method of carbon capture and utilisation through advancement of the fundamental science of carbon electrolysis and carbonate regeneration. A combination of advanced electrochemical a ....Solar electrolysis for manufacture of sustainable energy storage materials. This project aims to develop a novel solar-driven manufacturing process able to produce advanced carbon materials which effectively sequester carbon dioxide (negative emission). The project expects to provide key data and insights into a new method of carbon capture and utilisation through advancement of the fundamental science of carbon electrolysis and carbonate regeneration. A combination of advanced electrochemical and engineering techniques will be utilised to achieve this from lab-scale experimental work through to process modelling. Expected outcomes of this project include a clear understanding of the practical potential of this negative emission technology in contributing to offsetting global carbon dioxide emissions.Read moreRead less
Root effects on soil organic matter: a double-edged sword. This project aims to understand how plant roots build and destroy soil organic matter in grasslands and what the impacts are of drought. Soil organic matter is the largest terrestrial reservoir of nutrients for plant growth, but paradoxically, formation of new soil organic matter by plant roots also requires external nutrients. This project will address this apparent paradox by using a new root-centric framework and stable isotope techni ....Root effects on soil organic matter: a double-edged sword. This project aims to understand how plant roots build and destroy soil organic matter in grasslands and what the impacts are of drought. Soil organic matter is the largest terrestrial reservoir of nutrients for plant growth, but paradoxically, formation of new soil organic matter by plant roots also requires external nutrients. This project will address this apparent paradox by using a new root-centric framework and stable isotope techniques. The project will use state-of-the art computer models that incorporate the latest frameworks on soil organic matter interacting with plant roots. Benefits include an improved capacity to manage and predict grassland productivity and soil organic matter dynamics with greater resolution and accuracy.Read moreRead less