A Direct Approach to Crystal Structure Determination - a solution to the phase problem. The purpose of this research is to determine the positions of atoms in crystals and nano-crystals. We have developed a theory that shows how to extract all of the information required to determine atomic positions from such crystals and we have carried through initial successful tests on simple materials. In particular, we have found that crystallographic phase, hitherto not directly measurable, can in fact b ....A Direct Approach to Crystal Structure Determination - a solution to the phase problem. The purpose of this research is to determine the positions of atoms in crystals and nano-crystals. We have developed a theory that shows how to extract all of the information required to determine atomic positions from such crystals and we have carried through initial successful tests on simple materials. In particular, we have found that crystallographic phase, hitherto not directly measurable, can in fact be extracted uniquely from a single electron diffraction pattern. This constitutes a solution to the phase problem in crystallography. It is now our aim to develop this method into a routine technique.Read moreRead less
The effects of local strain on the crystal chemistry of solid solutions. The concept of the solid solution, the substitution of one kind of atom for another in a crystal structure, is a central idea in both mineral sciences and solid state chemistry. Such atomic substitutions alter local crystal chemistry and hence always introduce strain into crystal lattices. In this project we aim to characterize this substitutional strain. Ultimately this should lead to a better understanding of the geologic ....The effects of local strain on the crystal chemistry of solid solutions. The concept of the solid solution, the substitution of one kind of atom for another in a crystal structure, is a central idea in both mineral sciences and solid state chemistry. Such atomic substitutions alter local crystal chemistry and hence always introduce strain into crystal lattices. In this project we aim to characterize this substitutional strain. Ultimately this should lead to a better understanding of the geological history of rocks, improvements in metal recovery from ores and to the design and synthesis of new materials.Read moreRead less
SYNCHROTRON MICROPROBE METALLURGICAL CASE STUDIES. The micro-focus capabilities of synchrotron techniques (XRF, XRD, XAS) will enable the high resolution spatial correlations required to advance the understanding of the three systems to be studied:
- Activation for flotation of sphalerite with varying iron contents;
- Arsenic leaching as a function of local structure, phase and mineral assemblage;
- Optimisation of ferrous alloy microstructure on cryogenic treatment.
These case studies have ....SYNCHROTRON MICROPROBE METALLURGICAL CASE STUDIES. The micro-focus capabilities of synchrotron techniques (XRF, XRD, XAS) will enable the high resolution spatial correlations required to advance the understanding of the three systems to be studied:
- Activation for flotation of sphalerite with varying iron contents;
- Arsenic leaching as a function of local structure, phase and mineral assemblage;
- Optimisation of ferrous alloy microstructure on cryogenic treatment.
These case studies have been chosen to specifically target the minerals processing and manufacturing industrial sectors and will be used to increase industrial awareness of the potentials of synchrotron techniques prior to the commissioning of the Australian Synchrotron in 2007.
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Nickel iron sulphide mineralogy: the link between mineral transformations and microstructure and magnetic properties. This project is about measuring the rate at which minerals transform or react and how metal diffusion controls these reactions. Metal diffusion in sulphides is much more rapid that in silicates and is still very significant at low temperatures (< 300 C). In this project, we are trying to measure the rate at which the principal ore of nickel, pentlandite, transforms to violarite ....Nickel iron sulphide mineralogy: the link between mineral transformations and microstructure and magnetic properties. This project is about measuring the rate at which minerals transform or react and how metal diffusion controls these reactions. Metal diffusion in sulphides is much more rapid that in silicates and is still very significant at low temperatures (< 300 C). In this project, we are trying to measure the rate at which the principal ore of nickel, pentlandite, transforms to violarite, another important nickel rich sulphide that forms from it in the upper parts of ore bodies. The arrangement of the metal atoms in these minerals is sensitive to temperature, so it may be used as a geothermometer.Read moreRead less