In the Driver's seat: role of trace elements in enabling crustal fluid flow. This proposal aims to systematically investigate the role of trace elements in controlling the kinetics, product composition, and feed-back between fluid flow and the reaction interface, in fluid-driven mineral reactions. This project expects to provide a framework for the integration of activator trace elements in models of crustal fluid flow and their application in the recovery of base, precious, and critical metals, ....In the Driver's seat: role of trace elements in enabling crustal fluid flow. This proposal aims to systematically investigate the role of trace elements in controlling the kinetics, product composition, and feed-back between fluid flow and the reaction interface, in fluid-driven mineral reactions. This project expects to provide a framework for the integration of activator trace elements in models of crustal fluid flow and their application in the recovery of base, precious, and critical metals, using interdisciplinary approaches across geochemistry, mineral engineering and material sciences. Expected outcomes include improved prediction of the transport of metals and fluids in geo-systems. This should provide significant benefits towards integrating the mineral value chain from exploration to mining and metallurgy.Read moreRead less
Cracking the sulfate isotopic composition problem in ancient hydrothermal systems: application of the Carbonate-Associated Sulfate (CAS) method. Successful exploration of the deep Earth for valuable ores requires better knowledge of ore formation conditions, to feed to predictive deposit models. Our work shows great promise of improving the quality of this raw data. Smarter ore deposit prediction would likely exert its influence over the next ten years, rather than be immediate. It will increase ....Cracking the sulfate isotopic composition problem in ancient hydrothermal systems: application of the Carbonate-Associated Sulfate (CAS) method. Successful exploration of the deep Earth for valuable ores requires better knowledge of ore formation conditions, to feed to predictive deposit models. Our work shows great promise of improving the quality of this raw data. Smarter ore deposit prediction would likely exert its influence over the next ten years, rather than be immediate. It will increase exploration efficiency, saving tens of millions of dollars currently devoted to unproductive exploration. Exploration and mining are conducted primarily in regional Australia, and a healthy mining industry is therefore directly benefits hinterland communities. It also benefits all Australians through the payment of royalties and contributions to Australia's GDP from mineral exports.Read moreRead less
Organic geochemistry of the McArthur River hydrothermal deposit. Exploration for hydrothermal ore deposits in sedimentary basins has many problems because of the lack of any general agreement on the mechanisms of formation of major deposits. This proposed research will focus on the fundamental issue of the interaction of organic matter and mineralizing fluids in contributing to ore mineral deposition. Given that the McArthur River orebody is an exquisitely preserved example of a hydrothermal dep ....Organic geochemistry of the McArthur River hydrothermal deposit. Exploration for hydrothermal ore deposits in sedimentary basins has many problems because of the lack of any general agreement on the mechanisms of formation of major deposits. This proposed research will focus on the fundamental issue of the interaction of organic matter and mineralizing fluids in contributing to ore mineral deposition. Given that the McArthur River orebody is an exquisitely preserved example of a hydrothermal deposit it will thus enable a comprehensive organic geochemical investigation to elucidate the role of organic matter in ore formation. The outcomes will benefit the Australian mineral exploration industry by refining current ore genesis models.Read moreRead less
The hydrothermal solubility of molybdenum: A LA-ICPMS study of synthetic and natural fluid inclusions. The solubility of molybdenum under magmatic-hydrothermal conditions is essentially unknown. This study will, for the first time, identify the fundamental controls on molybdenum solubility in porphyry systems. This information will provide geologists with basic information on the transport and deposition of this important ore metal. In an allied study, the ore metals; copper, gold and molybdenum ....The hydrothermal solubility of molybdenum: A LA-ICPMS study of synthetic and natural fluid inclusions. The solubility of molybdenum under magmatic-hydrothermal conditions is essentially unknown. This study will, for the first time, identify the fundamental controls on molybdenum solubility in porphyry systems. This information will provide geologists with basic information on the transport and deposition of this important ore metal. In an allied study, the ore metals; copper, gold and molybdenum, will be traced through the Kidston porphyry system, Queensland. This will clarify the processes that lead to ore deposition, which will ultimately allow geologists to more effectively explore for porphyry-type deposits, a major target for Australian mining companies in the Pacific region.Read moreRead less
Isotopic fractionation in ore metals (Cu, Fe and Zn): A new window on ore-forming processes. Stable isotopes of common ore metals (e.g, copper and iron) are new tools for investigating ore deposits. Our data suggest that metal isotopic variations can provide new insights into mechanisms operative during formation of ore deposits. Stable metal isotopes also show promise as a new exploration tool for identifying the location of economic mineralisation within large prospective terrains; e.g., weakl ....Isotopic fractionation in ore metals (Cu, Fe and Zn): A new window on ore-forming processes. Stable isotopes of common ore metals (e.g, copper and iron) are new tools for investigating ore deposits. Our data suggest that metal isotopic variations can provide new insights into mechanisms operative during formation of ore deposits. Stable metal isotopes also show promise as a new exploration tool for identifying the location of economic mineralisation within large prospective terrains; e.g., weakly vs. strongly mineralised zones in a volcanic belt.
This project will provide fundamental baseline data that will help elucidate the processes that cause metal isotope variations. This will allow stable metal isotopes to be used much more effectively by the mining and exploration industries.
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The early evolution of the Earth system from multiple sulfur isotope records of sediments and seafloor mineral systems. This project addresses the early evolution of the Earth system that is one of the most important questions in Earth Sciences. It will use Australia's unique rock record and analytical techniques developed in Australia in collaboration with leading international researchers. The National Research Priority area 'An environmentally sustainable Australia: developing deep Earth reso ....The early evolution of the Earth system from multiple sulfur isotope records of sediments and seafloor mineral systems. This project addresses the early evolution of the Earth system that is one of the most important questions in Earth Sciences. It will use Australia's unique rock record and analytical techniques developed in Australia in collaboration with leading international researchers. The National Research Priority area 'An environmentally sustainable Australia: developing deep Earth resources' will benefit through the development of better exploration models for Archaean submarine metal deposits. Students will obtain a high level understanding of the early Earth system, ore deposits, stable isotope and transition metal geochemistry, which are directly applicable in both pure and applied research and mineral exploration.Read moreRead less
Aqueous fluids in the deep earth. This project aims to improve our understanding of the role of fluids in controlling exchanges between the deep Earth, shallow rocks, and atmosphere. The project expects to investigate some of the key weaknesses in the thermodynamic models that are used to predict the behaviour of sulphur, carbon and metals in fluids at high pressure and temperature by using recent advances in computational and experimental (geo)chemistry. Integrated in large-scale geodynamic mod ....Aqueous fluids in the deep earth. This project aims to improve our understanding of the role of fluids in controlling exchanges between the deep Earth, shallow rocks, and atmosphere. The project expects to investigate some of the key weaknesses in the thermodynamic models that are used to predict the behaviour of sulphur, carbon and metals in fluids at high pressure and temperature by using recent advances in computational and experimental (geo)chemistry. Integrated in large-scale geodynamic models, the more reliable predictions will provide a more realistic assessment of the role of sulphur in controlling metal endowment and atmospheric chemistry through geological times. This should provide a useful guide for mineral exploration and planetary science.Read moreRead less
Deep and smelly: exploring the roles of pressure and sulphur in hydrothermal metal transport. Hot, salty fluids carry metals in the Earth's crust and are responsible for the formation of Australia's mineral wealth. This project combines exciting new experiments with molecular-level simulations to predict metal transport, providing a sound basis for improving mineral exploration models and sustaining discovery of new deposits.
The Geochemistry of the Platinum Group Elements, Copper, Rhenium and Gold in Granitic Rocks. Many of the World's largest copper and gold deposits derive their ore fluids from crystallizing granitic magmas. These elements, together with the platinum group elements, are sequestered by immiscible sulfide melts, which when they precipitate from a magma, control the subsequent evolution of these elements. The proposed study takes advantage of platinum's remarkable affinity for sulfides to identify ....The Geochemistry of the Platinum Group Elements, Copper, Rhenium and Gold in Granitic Rocks. Many of the World's largest copper and gold deposits derive their ore fluids from crystallizing granitic magmas. These elements, together with the platinum group elements, are sequestered by immiscible sulfide melts, which when they precipitate from a magma, control the subsequent evolution of these elements. The proposed study takes advantage of platinum's remarkable affinity for sulfides to identify onset of sulfide saturation and then monitor its effect on the subsequent evolution of copper and gold in the evolving magma. It is expected to provide new insights into chemistry of copper and gold in crystallizing granitic melts and explain why some granitic systems are ore bearing and other are not. Read moreRead less
Volatile recycling at the crust-mantle interface: Evidence from halogens and noble gases in deep-crustal fluids. 1) The technique proposed for this study is of proven interest to the mineral exploration industry. This project will: i) increase knowledge of the deep-crustal fluids often implicated in giant hydrothermal ore deposits; and ii) develop laser ablation, which will increase the techniques applicability to Australia's oldest ore deposits. These outcomes will further benefit the mineral e ....Volatile recycling at the crust-mantle interface: Evidence from halogens and noble gases in deep-crustal fluids. 1) The technique proposed for this study is of proven interest to the mineral exploration industry. This project will: i) increase knowledge of the deep-crustal fluids often implicated in giant hydrothermal ore deposits; and ii) develop laser ablation, which will increase the techniques applicability to Australia's oldest ore deposits. These outcomes will further benefit the mineral exploration industry.
2) The experimental data can be applied to testing the long-term storage of CO2 by geo-sequestration.
3) The proposed research is extremely topical and will be presented at international conferences and in high impact journals raising the profile of Australian science. Read moreRead less