Southern Ocean aerosols: sources, sinks and impact on cloud properties. This project aims to provide fundamental process-level understanding of atmospheric aerosol processes over the Southern Ocean, a region that has a profound influence on the Australian and global climate and where climate models perform poorly. Comprehensive observations during 3 Southern Ocean voyages and land-based measurements will enhance our knowledge of aerosols and cloud formation in that region and provide much-needed ....Southern Ocean aerosols: sources, sinks and impact on cloud properties. This project aims to provide fundamental process-level understanding of atmospheric aerosol processes over the Southern Ocean, a region that has a profound influence on the Australian and global climate and where climate models perform poorly. Comprehensive observations during 3 Southern Ocean voyages and land-based measurements will enhance our knowledge of aerosols and cloud formation in that region and provide much-needed data for improving global climate models. Expected outcomes include more accurate seasonal and latitudinal representations of Southern Ocean aerosol populations, properties and sources. The main benefit includes improvements in weather forecasting and future climate projection for Australia and the Southern Hemisphere.Read moreRead less
Atmospheric composition and climate change. Changing composition and distribution of atmospheric trace gases and aerosols are the driving forces behind changes in climate and the environment at the earth's surface. This proposal is to undertake a program of ground based infrared remote sensing measurements as part of the Network for Detection of Stratospheric Change to investigate some of the most relevant atmospheric processes and species central to the greenhouse effect and ozone depletion. S ....Atmospheric composition and climate change. Changing composition and distribution of atmospheric trace gases and aerosols are the driving forces behind changes in climate and the environment at the earth's surface. This proposal is to undertake a program of ground based infrared remote sensing measurements as part of the Network for Detection of Stratospheric Change to investigate some of the most relevant atmospheric processes and species central to the greenhouse effect and ozone depletion. State-of-the-art measurements, advances in analysis techniques, and the measurement of isotopic fractionation will all contribute to advances in capabilities. Validation of satellite-based remote sensing instruments is also an important facet of the work.Read moreRead less
Better greenhouse gas budgets: new techniques and applications. The most recent (2001) international assessment strongly confirms the link between global climate change and human-induced changes in atmospheric composition. However, improved knowledge of atmospheric trace gas budgets is essential for better modelling of future climate change and formulation of public policy. We have developed novel techniques for atmospheric trace gas and isoptic analysis that provide new tools for resolving trac ....Better greenhouse gas budgets: new techniques and applications. The most recent (2001) international assessment strongly confirms the link between global climate change and human-induced changes in atmospheric composition. However, improved knowledge of atmospheric trace gas budgets is essential for better modelling of future climate change and formulation of public policy. We have developed novel techniques for atmospheric trace gas and isoptic analysis that provide new tools for resolving trace gas budgets in ways not previously possible. We will apply these tools to improve our understanding of the Australian and global budgets of greenhouse gases, especially nitrous oxide and methane, for which sources still have unacceptably large uncertainties.Read moreRead less
Nanoparticles with structures that mimic enzymes for electrocatalysis. This project aims to create a new class of electrocatalysts with architectures inspired by enzymes. Electrocatalysts are the backbone of the modern energy economy. In the new electrocatalysts developed by the project, the intention is the active sites will be spatially separated from the bulk solution by nanopores, as enzymes do. This architecture allows the reaction environment to be altered from the bulk solution, active tr ....Nanoparticles with structures that mimic enzymes for electrocatalysis. This project aims to create a new class of electrocatalysts with architectures inspired by enzymes. Electrocatalysts are the backbone of the modern energy economy. In the new electrocatalysts developed by the project, the intention is the active sites will be spatially separated from the bulk solution by nanopores, as enzymes do. This architecture allows the reaction environment to be altered from the bulk solution, active transport of species to the active site and cascade reactions to be performed. This should give advantages in activity, selectivity and the ability to perform multistep reactions. The intended outcomes are better performing hydrogen fuel cells and more effective conversion of carbon dioxide into useful organic compounds.Read moreRead less
The carbon cycle and climate: new approaches to atmospheric measurements and modelling. Earth's climate is intimately connected to the carbon cycle, which controls atmospheric CO2 through processes such as photosynthesis, respiration and ocean uptake. A thorough understanding of the carbon cycle, and potential feedbacks with climate change, is prerequisite knowledge for informed assessments of future climate, impacts, adaptation and mitigation. This proposal improves that understanding through ....The carbon cycle and climate: new approaches to atmospheric measurements and modelling. Earth's climate is intimately connected to the carbon cycle, which controls atmospheric CO2 through processes such as photosynthesis, respiration and ocean uptake. A thorough understanding of the carbon cycle, and potential feedbacks with climate change, is prerequisite knowledge for informed assessments of future climate, impacts, adaptation and mitigation. This proposal improves that understanding through measurements of CO2 and other key Kyoto-protocol greenhouse gases, links to global networks and satellite measurements, and advanced modelling. Australian science has a very important role to play in international networks due to our unique combination of southern hemisphere location and scientific standing. Read moreRead less
Biomass Burning Emissions - An Innovative Technique for Assessing Global Climate Impacts. This proposal will significantly improve our understanding of the impacts of biomass burning on climate and environmental change leading to better predictive powers and more informed political and economic responses to issues such as Australian compliance with international protocols dealing with global climate change (Kyoto). Further, it will help the development of Australian expertise in global chemical ....Biomass Burning Emissions - An Innovative Technique for Assessing Global Climate Impacts. This proposal will significantly improve our understanding of the impacts of biomass burning on climate and environmental change leading to better predictive powers and more informed political and economic responses to issues such as Australian compliance with international protocols dealing with global climate change (Kyoto). Further, it will help the development of Australian expertise in global chemical transport modelling not currently addressed by other Australian research programs.
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The behaviour of geochemical tracers during differentiation of the Earth. This project is aimed at providing fundamental data which Earth Scientists will use to understand the processes by which the Earth separated into its chemically-distinct layers (core, mantle, crust, atmosphere, oceans) and to determine the nature of the continuing interactions between the surface environment in which we live and the deep interior. It will provide training in modern high temperature-high pressure materials- ....The behaviour of geochemical tracers during differentiation of the Earth. This project is aimed at providing fundamental data which Earth Scientists will use to understand the processes by which the Earth separated into its chemically-distinct layers (core, mantle, crust, atmosphere, oceans) and to determine the nature of the continuing interactions between the surface environment in which we live and the deep interior. It will provide training in modern high temperature-high pressure materials-science techniques for Ph.D. students and postdoctoral researchers. This will provide Australia with Earth Scientists who have both traditional skills and the ability to work with Materials Scientists on the synthesis of novel materials under extreme conditions.Read moreRead less
Physical, Chemical and Radiative Characteristics of Australian Continental Aerosols. Australian desert dust, and the biomass burning aerosol particles produced in the top-end burning season, have the potential to impose an environmental burden not only on Australia, but also on the surrounding region. While most of the world's major aerosol types have been well studied in recent years, these two remain largely unknown. There are good reasons to believe that Australian aerosols are different from ....Physical, Chemical and Radiative Characteristics of Australian Continental Aerosols. Australian desert dust, and the biomass burning aerosol particles produced in the top-end burning season, have the potential to impose an environmental burden not only on Australia, but also on the surrounding region. While most of the world's major aerosol types have been well studied in recent years, these two remain largely unknown. There are good reasons to believe that Australian aerosols are different from many others. We therefore intend to fully characterize their relevant properties, so we may monitor them from space, and evaluate their environmental impacts.Read moreRead less
Reactivity and photochemistry of halide anions: atmospheric implications. Bromine and iodine are suspected to be responsible for most of the halogen-induced ozone loss in the stratosphere but are not currently included in atmospheric models due to a paucity of knowledge of the gas-phase chemistry and photochemistry of their anions and radicals. This project will develop and deploy advanced mass spectrometry and laser spectroscopy techniques to enable precision measurements of the reactions and p ....Reactivity and photochemistry of halide anions: atmospheric implications. Bromine and iodine are suspected to be responsible for most of the halogen-induced ozone loss in the stratosphere but are not currently included in atmospheric models due to a paucity of knowledge of the gas-phase chemistry and photochemistry of their anions and radicals. This project will develop and deploy advanced mass spectrometry and laser spectroscopy techniques to enable precision measurements of the reactions and photo-reactions of gas-phase iodide and bromide anions and their oxides. These state-of-the-art measurements of reaction kinetics and products will enable accurate chemical models that predict the impact of bromine and iodine chemistry on ozone levels and will inform future models for global climate.Read moreRead less
GBR as a significant source of climatically relevant aerosol particles. Every cloud drop is formed from a microscopic aerosol particle, known as a cloud condensation nuclei (CCN). In unpolluted environments the CCN particles originate from biogenic sources. Determining the magnitude and driving factors of biogenic aerosol production in different ecosystems is crucial to the development and improvement of climate models. This project aims to determine the mechanisms of new particle production fro ....GBR as a significant source of climatically relevant aerosol particles. Every cloud drop is formed from a microscopic aerosol particle, known as a cloud condensation nuclei (CCN). In unpolluted environments the CCN particles originate from biogenic sources. Determining the magnitude and driving factors of biogenic aerosol production in different ecosystems is crucial to the development and improvement of climate models. This project aims to determine the mechanisms of new particle production from one of the biggest ecosystems in Australia, the Great Barrier Reef. It is expected that the project will establish whether marine aerosol along the Queensland coast is coral-derived and show that this aerosol can affect the CCN concentration and therefore cloud formation and the hydrological cycle.Read moreRead less