The energetics and dynamics of chemical reactions of polyatomic molecules involving multiple electronic states. This project will produce, from first principles, the first quantitatively accurate computer simulations of chemical reactions which involve several atoms and multiple electronic states. Many of the most important chemical reactions in the atmosphere (and elsewhere) involve changing both the shape of the molecules and their electronic structure. Many of these reactions are difficult to ....The energetics and dynamics of chemical reactions of polyatomic molecules involving multiple electronic states. This project will produce, from first principles, the first quantitatively accurate computer simulations of chemical reactions which involve several atoms and multiple electronic states. Many of the most important chemical reactions in the atmosphere (and elsewhere) involve changing both the shape of the molecules and their electronic structure. Many of these reactions are difficult to study in the laboratory, and consequently computer simulation is an essential component of the study of such reactions. U nderstanding how these reactions occur, and how fast they proceed, are important to our understanding of the dynamics of the atmosphere and other large scale reactors.Read moreRead less
Isotopic fractionation in planetary atmospheres. Ongoing changes in the Earth's atmosphere, such as ozone depletion, demonstrate the need to understand atmospheric photochemical processes. Isotopic fractionation is one vehicle for obtaining
detailed insight into these processes. The proposed research will
increase our understanding of fundamental molecular processes and use these new results to improve our knowledge of isotopic fractionation in planetary atmospheres. The resulting models wil ....Isotopic fractionation in planetary atmospheres. Ongoing changes in the Earth's atmosphere, such as ozone depletion, demonstrate the need to understand atmospheric photochemical processes. Isotopic fractionation is one vehicle for obtaining
detailed insight into these processes. The proposed research will
increase our understanding of fundamental molecular processes and use these new results to improve our knowledge of isotopic fractionation in planetary atmospheres. The resulting models will lead to new insight into the Earth's ozone chemistry and the recent evolution of Titan's and Venus' atmospheres, including how much water may have been present on Venus in the recent past. The research program also enables Australian participation in three international spacecraft
missions.
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Photochemistry of the Middle Atmospheres of Venus and the Earth. Ongoing changes in the Earth's atmosphere, such as ozone depletion, demonstrate the need to understand the processes that control atmospheric chemistry. The proposed research will improve the fidelity of photochemical models, provide additional insight into the recent evolution of the Venus atmosphere, and examine how atmospheric chemistry and climate change interact(ed) on Venus. This research will improve our understanding of l ....Photochemistry of the Middle Atmospheres of Venus and the Earth. Ongoing changes in the Earth's atmosphere, such as ozone depletion, demonstrate the need to understand the processes that control atmospheric chemistry. The proposed research will improve the fidelity of photochemical models, provide additional insight into the recent evolution of the Venus atmosphere, and examine how atmospheric chemistry and climate change interact(ed) on Venus. This research will improve our understanding of long-standing issues, such as how much water might have been present on Venus in the recent past. The research program will provide an opportunity for Australian science to participate in at least one spacecraft mission to Venus. Read moreRead less
Sulfuric acid formation from atmospheric sulfur trioxide and disulfur oxide: is one water molecule enough? Sulfate aerosols significantly affect the amount of solar radiation reaching the Earth, influencing the nett energy balance, and mitigating the greenhouse effect. A major source of these aerosols is sulfuric acid. Understanding the sources and formation rates of sulfuric acid production is of considerable importance for global climate models. This project will provide significant insight in ....Sulfuric acid formation from atmospheric sulfur trioxide and disulfur oxide: is one water molecule enough? Sulfate aerosols significantly affect the amount of solar radiation reaching the Earth, influencing the nett energy balance, and mitigating the greenhouse effect. A major source of these aerosols is sulfuric acid. Understanding the sources and formation rates of sulfuric acid production is of considerable importance for global climate models. This project will provide significant insight into the sulfur oxides and their water clusters, relevant to sulfuric acid formation, providing data applicable to the modelling of planetary atmospheres, especially timely for the Venus Express mission, and more importantly, the building of comprehensive climate models.Read moreRead less
Quantum Mechanics and Planetary Atmospheres. The project will increase the visibility and status of Australian research, by the participation of researchers and students in a wide international collaboration, covering experiments, theory, and computation, which will solve a fundamental research problem that has previously defied understanding. The resulting nitrogen model will be relevant to the important fields of global and planetary atmospheric change, and will find immediate application in t ....Quantum Mechanics and Planetary Atmospheres. The project will increase the visibility and status of Australian research, by the participation of researchers and students in a wide international collaboration, covering experiments, theory, and computation, which will solve a fundamental research problem that has previously defied understanding. The resulting nitrogen model will be relevant to the important fields of global and planetary atmospheric change, and will find immediate application in the analysis of results from the NASA missions, Voyager, Cassini, and (later) New Horizons. In the experimental part of the project, an Australian-first extreme-ultraviolet laser facility will be developed which will provide research opportunities complementary to the Australian Synchrotron.Read moreRead less
Understanding the chemistry and evolution of planets and their atmospheres: Integrating experiments, observations, and quantum mechanical models. Ongoing changes in the Earth's atmosphere, demonstrate the need to understand photochemical processes and their role in atmospheric evolution. The proposed research will increase our understanding of the evolution of planetary atmospheres, with concomitant insight into the Earth's evolution. This proposal will greatly enhance the visibility of Australi ....Understanding the chemistry and evolution of planets and their atmospheres: Integrating experiments, observations, and quantum mechanical models. Ongoing changes in the Earth's atmosphere, demonstrate the need to understand photochemical processes and their role in atmospheric evolution. The proposed research will increase our understanding of the evolution of planetary atmospheres, with concomitant insight into the Earth's evolution. This proposal will greatly enhance the visibility of Australian research, through formal, direct connections to NASA and ESA (European Space Agency) planetary exploration missions, along with publications in Nature, Science, and/or PNAS (Proceedings of the National Academy of Sciences) that will likely result from the high-profile problems to be studied. Furthermore, as a result of this collaboration, Australian students and postdoctoral researchers will benefit from interactions with top international scientists.Read moreRead less
Reaction transition states of halide-cluster complexes via velocity-map imaging of photoelectrons. This study will investigate the transition point between the reactants and products of a chemical reaction using a novel photoelectron imaging technique, velocity-map imaging. It is this region of chemical reactions that is the least understood. By combining the use of weakly bound negatively charged clusters and laser photodetachment of these clusters, information can be gleaned about these transi ....Reaction transition states of halide-cluster complexes via velocity-map imaging of photoelectrons. This study will investigate the transition point between the reactants and products of a chemical reaction using a novel photoelectron imaging technique, velocity-map imaging. It is this region of chemical reactions that is the least understood. By combining the use of weakly bound negatively charged clusters and laser photodetachment of these clusters, information can be gleaned about these transition states. The technique will be applied to an important class of halide-cluster complexes that form a set of prototypical reactions. These species also play important roles ranging from ozone depletion through to industrial chemistry.Read moreRead less
Imaging chemical reaction dynamics from the transition state to reaction products. Chemical reactions play a key role in many atmospheric, environmental and industrial processes. An understanding of reactions at the molecular level will lead to significant economic benefits, through more efficient reaction control, and through the identification of the key environmental factors which influence why particular reactions proceed. Our study of chemical reaction dynamics has been driven by technolo ....Imaging chemical reaction dynamics from the transition state to reaction products. Chemical reactions play a key role in many atmospheric, environmental and industrial processes. An understanding of reactions at the molecular level will lead to significant economic benefits, through more efficient reaction control, and through the identification of the key environmental factors which influence why particular reactions proceed. Our study of chemical reaction dynamics has been driven by technological advances which enable key stages of a reaction to be imaged and studied at the molecular level. Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0989539
Funder
Australian Research Council
Funding Amount
$250,000.00
Summary
Purchase of a state-of-the-art high resolution inductively coupled plasma mass spectrometer. This new state-of-the-art mass spectrometer with enhanced capability will allow Tasmanian researchers to accurately determine the elemental composition of their samples of interest. The instrument will be extremely sensitive and will be able to detect elements to very low concentrations. It will be used to support a diverse range of local research projects of international significance, for example the ....Purchase of a state-of-the-art high resolution inductively coupled plasma mass spectrometer. This new state-of-the-art mass spectrometer with enhanced capability will allow Tasmanian researchers to accurately determine the elemental composition of their samples of interest. The instrument will be extremely sensitive and will be able to detect elements to very low concentrations. It will be used to support a diverse range of local research projects of international significance, for example the environmental assessment of clean and contaminated sites, chemical synthesis on a miniature scale using micro-chips, and the monitoring of selected elements of key importance for human health.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0560940
Funder
Australian Research Council
Funding Amount
$229,326.00
Summary
Stable Isotope Ratio Mass Spectrometry Facility. This application for a Stable Isotope Ratio Mass Spectrometer Facility provides a focus for research collaboration and training in northern Australia. The Facility will enhance strong collaboration between organisations committed to increasing understanding of unique northern environments, and will include the Arafura Timor Research Facility, a Major National Research Facility. The Facility will contribute to studies of conservation biology, nat ....Stable Isotope Ratio Mass Spectrometry Facility. This application for a Stable Isotope Ratio Mass Spectrometer Facility provides a focus for research collaboration and training in northern Australia. The Facility will enhance strong collaboration between organisations committed to increasing understanding of unique northern environments, and will include the Arafura Timor Research Facility, a Major National Research Facility. The Facility will contribute to studies of conservation biology, natural resource management, environmental and marine science and resource development in the tropical north. It will help develop knowledge bases, innovative approaches to environmental management and sustainable development and high levels of research and research training for regional development.Read moreRead less