Discovery Early Career Researcher Award - Grant ID: DE120102967
Funder
Australian Research Council
Funding Amount
$375,000.00
Summary
Interaction between silver ions, silver nanoparticles and reactive oxygen species: implication to toxicity. The project investigates the ability of various different (supported and stabilised) types of nanosized silver particles (SNPs) to oxidatively degrade selected contaminants and or kill microorganism. The project also aims to determine the effect of solution condition (for example pH) and light on SNP longevity and hence their oxidative capacity.
Degradation of Trace Contaminants Using Sonochemistry and Peroxide Scavenging Advanced Oxidation Processes. Sonochemical degradation of hazardous organic compounds in aqueous solution has been examined extensively in recent years and found to be an effective means of waste treatment however the scavenging of hydroxyl radicals by the relatively high concentrations of hydrogen peroxide produced limits the amount of reactive radicals accessible to target molecules. In this project we will investiga ....Degradation of Trace Contaminants Using Sonochemistry and Peroxide Scavenging Advanced Oxidation Processes. Sonochemical degradation of hazardous organic compounds in aqueous solution has been examined extensively in recent years and found to be an effective means of waste treatment however the scavenging of hydroxyl radicals by the relatively high concentrations of hydrogen peroxide produced limits the amount of reactive radicals accessible to target molecules. In this project we will investigate, by both experimental and computational means, options for the regeneration of hydroxyl radicals through use of hydrogen peroxide. Methods of particular interest include use of Fenton's reagent and ozone.Read moreRead less
Application of nano-sized zero valent iron particles to agrochemicals degradation through Fenton's reagent oxidation. Zero-valent iron (ZVI) has been successfully used for the degradation of a wide range of contaminant organics in groundwaters in recent years. The rates of degradation however are relatively slow and render the process unsuitable for situations where there are limits on the time available for reaction. An innovative approach is to couple the dissolution of ZVI with hydrogen perox ....Application of nano-sized zero valent iron particles to agrochemicals degradation through Fenton's reagent oxidation. Zero-valent iron (ZVI) has been successfully used for the degradation of a wide range of contaminant organics in groundwaters in recent years. The rates of degradation however are relatively slow and render the process unsuitable for situations where there are limits on the time available for reaction. An innovative approach is to couple the dissolution of ZVI with hydrogen peroxide addition thereby generating hydroxyl radicals as a result of Fenton's reagent reactions. The efficacy of using this innovative ZVI/H2O2 process to degrade herbicides and pesticides of concern to Australian agriculture is investigated at laboratory and field scale in this project.Read moreRead less
Design tools for optimising data centre layout to minimise energy usage. Data centres are major consumers of energy worldwide, mainly through the need to cool the equipment. It has become imperative to develop the science for reducing this consumption. Rising computing demand, increasing power density, and increasing infrastructure and energy costs are major issue for data centres around the world. Our research will provide a powerful alternative to conventional thermal management techniques for ....Design tools for optimising data centre layout to minimise energy usage. Data centres are major consumers of energy worldwide, mainly through the need to cool the equipment. It has become imperative to develop the science for reducing this consumption. Rising computing demand, increasing power density, and increasing infrastructure and energy costs are major issue for data centres around the world. Our research will provide a powerful alternative to conventional thermal management techniques for cooling high-density heat loads in mixed-density environments. We will address the key issue of energy minimisation through a detailed flow analyses by the use of numerical simulations and optimisation algorithms.Read moreRead less
Floc Characteristics in Sheared Systems: Implications to Low Pressure Membrane Filtration in Water Treatment. In this project, we examine the effect of coagulant choice and coagulation conditions on the nature of the flocs formed in drinking water treatment using submerged membrane systems and on the extent of fouling, contaminant removal and difficulties in backwash. We will develop both underpinning knowledge and operational protocols that will assist in improving the efficiency and thus reduc ....Floc Characteristics in Sheared Systems: Implications to Low Pressure Membrane Filtration in Water Treatment. In this project, we examine the effect of coagulant choice and coagulation conditions on the nature of the flocs formed in drinking water treatment using submerged membrane systems and on the extent of fouling, contaminant removal and difficulties in backwash. We will develop both underpinning knowledge and operational protocols that will assist in improving the efficiency and thus reducing the operating costs of submerged membrane water systems. The outcomes of this project will assist our industry partner in developing more cost effective water treatment processes in Australia which will, in turn, assist in increasing market share in the Asian region.Read moreRead less
Reactive oxygen species generation by zerovalent silver nanoparticles; implications to toxicity and contaminant degradation. Nanoparticulate silver is now being used for the purification of drinking water yet many questions remain concerning its mode of purifying action. Here we investigate the generation of reactive oxygen species (ROS) by nanoparticulate silver and examine the relationship between ROS generation and the purifying action of "nano-silver".
Development and calibration of aquatic passive sampler technologies for emerging water pollutants. Contaminated water is a key exposure source for many emerging pollutants either direct via consumption of water or indirect via consumption of aquatic biota. Monitoring of emerging aquatic pollutants remains a challenge. In this project we will develop cost effective monitoring technologies for emerging aquatic pollutants. The outcome will allow a more comprehensive and cost-effective monitoring ....Development and calibration of aquatic passive sampler technologies for emerging water pollutants. Contaminated water is a key exposure source for many emerging pollutants either direct via consumption of water or indirect via consumption of aquatic biota. Monitoring of emerging aquatic pollutants remains a challenge. In this project we will develop cost effective monitoring technologies for emerging aquatic pollutants. The outcome will allow a more comprehensive and cost-effective monitoring of these pollutants and related to that a decrease in risk related to water pollution. Furthermore it will enhance consumer confidence, improve water management and allow more comprehensive identification of emerging risks related to aquatic pollutants.Read moreRead less
Development and evaluation of a Phytotox-Test for field and laboratory testing of phytotoxic chemicals in water. Monitoring of trace pollutants in water is expensive, laborious and requires sophisticated analytical techniques. Building on the research team's new technique, which uses a phyto-tox test based on photosynthesis inhibition in algae, this study will further develop and evaluate methodologies and applications for measuring phyto-toxic chemicals in environmental water samples. The proj ....Development and evaluation of a Phytotox-Test for field and laboratory testing of phytotoxic chemicals in water. Monitoring of trace pollutants in water is expensive, laborious and requires sophisticated analytical techniques. Building on the research team's new technique, which uses a phyto-tox test based on photosynthesis inhibition in algae, this study will further develop and evaluate methodologies and applications for measuring phyto-toxic chemicals in environmental water samples. The project aims specifically to:
- identify suitable algae, sensitive to phyto-toxic chemicals
- determine dose-response for priority pollutants in selected algae
- evaluate critical parameters affecting measurements
- develop pre-concentration techniques.
The outcomes will provide the first on-site trace pollutant testing method allowing more effective management of water pollution
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Application and evaluation of passive samplers for monitoring aquatic pollution. Pollutants in water bodies pose a threat to environmental and human health. Monitoring of chemicals in water has thus become a key challenge for environmental authorities. Sampling based on the
analysis of grab samples is expensive, complicated and provides only patchy data. Passive sampling devices that allow time integrated sampling of pollutants are a promising alternative. This collaborative research aims t ....Application and evaluation of passive samplers for monitoring aquatic pollution. Pollutants in water bodies pose a threat to environmental and human health. Monitoring of chemicals in water has thus become a key challenge for environmental authorities. Sampling based on the
analysis of grab samples is expensive, complicated and provides only patchy data. Passive sampling devices that allow time integrated sampling of pollutants are a promising alternative. This collaborative research aims to evaluate a series of existing and novel passive samplers both in laboratory and field conditions and determine sensitive parameters that significantly influence sampler behaviour.
The project should provide a set of new tools for more effective management of water pollution.Read moreRead less
An innovative strategy for stormwater remediation and reduction of contaminant supply from catchments. Many urbanised harbours world-wide are polluted and the main source is stormwater. Currently, emphasis is to remove gross pollutants from stormwater using numerous devices scattered through the catchment. In a radical shift from traditional approaches, we will identify primary contaminant sources in the catchment for later targeted education and regulation and a single remediation device will r ....An innovative strategy for stormwater remediation and reduction of contaminant supply from catchments. Many urbanised harbours world-wide are polluted and the main source is stormwater. Currently, emphasis is to remove gross pollutants from stormwater using numerous devices scattered through the catchment. In a radical shift from traditional approaches, we will identify primary contaminant sources in the catchment for later targeted education and regulation and a single remediation device will remove most toxic substances in stormwater currently discharged to estuaries. Stormwater reuse will provide a new valuable urban resource. This paradigm shift in traditional stormwater strategy will ensure biodiversity and ecologically sustainable development of urbanised ports. Port Jackson is used as a test case.Read moreRead less