Resolving Critical Knowledge Gaps Relating to Light and Free-Radical Mediated Transformations of Iron and Copper in Oxic Natural Waters. Understanding the transformation kinetics of iron and copper species is critical to maintaining Australia's water resources since i) iron transformations are key to generation and transport of acid in Australia's coastal environment; ii) growth of toxic algae are stimulated by dissolution of iron-rich sediments with subsequent release of nutrients phosphorus an ....Resolving Critical Knowledge Gaps Relating to Light and Free-Radical Mediated Transformations of Iron and Copper in Oxic Natural Waters. Understanding the transformation kinetics of iron and copper species is critical to maintaining Australia's water resources since i) iron transformations are key to generation and transport of acid in Australia's coastal environment; ii) growth of toxic algae are stimulated by dissolution of iron-rich sediments with subsequent release of nutrients phosphorus and iron, and iii) algal toxicity is related to iron and copper nutrition and interplay of these metals with oxygen. Additionally, global cycles of carbon, phosphorus and nitrogen are influenced by iron and copper interactions with light and oxygen. Improved understanding of these processes should lead to an awareness of how to prevent these problems and, if they occur, approaches to their mitigation.Read moreRead less
A new paradigm for the geochemistry of mineral precipitation and dissolution in aquatic systems: Polymer-based numerical modelling. The ability to predict the formation and dissolution of solids (minerals and precipitates) in aquatic systems is currently constrained by limitations of the traditional thermodynamic approach. A new approach based on the kinetics of the underlying chemical reactions is expected to overcome these limitations and greatly improve the ability to describe these processes ....A new paradigm for the geochemistry of mineral precipitation and dissolution in aquatic systems: Polymer-based numerical modelling. The ability to predict the formation and dissolution of solids (minerals and precipitates) in aquatic systems is currently constrained by limitations of the traditional thermodynamic approach. A new approach based on the kinetics of the underlying chemical reactions is expected to overcome these limitations and greatly improve the ability to describe these processes. This new fundamental knowledge will be useful in many diverse fields including aquatic geochemistry, soil chemistry, water engineering, and nanotechnology. The new approach will be specifically applied to improve understanding of processes related to the globally significant environmental issues of marine iron fertilisation, ocean acidification and acid sulfate soils.Read moreRead less
Reconstruction of anoxic and toxic conditions in Australian lakes and ancient oceans. Sustainable water quality is a critically important issue for Australia's economic and social development. To be able to predict and plan the future of Australia's lakes and estuaries, it is crucial to understand their ecological past and to determine their state prior to and post-European settlement. This project develops and applies novel methodologies to reconstruct the history of cyanobacterial blooms, eutr ....Reconstruction of anoxic and toxic conditions in Australian lakes and ancient oceans. Sustainable water quality is a critically important issue for Australia's economic and social development. To be able to predict and plan the future of Australia's lakes and estuaries, it is crucial to understand their ecological past and to determine their state prior to and post-European settlement. This project develops and applies novel methodologies to reconstruct the history of cyanobacterial blooms, eutrophication and anoxia in Australian waterways. It will help to identify human impact on water quality. The new methodologies, applied to ancient sedimentary rocks, will also yield information about the effect of environmental changes on early life on Earth, enforcing Australia's position in the study of global geochemical cycles.Read moreRead less
Development of Methods and Strategies for the Measurement, Interpretation and Analysis of Diffuse X-ray Scattering from Disordered Materials. This application seeks to exploit our established lead in the measurement of diffuse scattering from disordered materials and its analysis using large-scale computer simulations. Many industrially important materials such as ceramics, superconductors, catalysts, electro-optical materials and minerals owe their special properties to the disorder in their st ....Development of Methods and Strategies for the Measurement, Interpretation and Analysis of Diffuse X-ray Scattering from Disordered Materials. This application seeks to exploit our established lead in the measurement of diffuse scattering from disordered materials and its analysis using large-scale computer simulations. Many industrially important materials such as ceramics, superconductors, catalysts, electro-optical materials and minerals owe their special properties to the disorder in their structure. This disorder causes diffuse X-ray scattering which can be probed using synchrotron X-rays and powerful computers to reveal details about the material's nanoscale structure. The new methodology being developed will enhance our detailed understanding of the relationships between structure and properties in materials and help promote the design of new materials. Read moreRead less
Photochemistry of the Middle Atmospheres of Venus and the Earth. Ongoing changes in the Earth's atmosphere, such as ozone depletion, demonstrate the need to understand the processes that control atmospheric chemistry. The proposed research will improve the fidelity of photochemical models, provide additional insight into the recent evolution of the Venus atmosphere, and examine how atmospheric chemistry and climate change interact(ed) on Venus. This research will improve our understanding of l ....Photochemistry of the Middle Atmospheres of Venus and the Earth. Ongoing changes in the Earth's atmosphere, such as ozone depletion, demonstrate the need to understand the processes that control atmospheric chemistry. The proposed research will improve the fidelity of photochemical models, provide additional insight into the recent evolution of the Venus atmosphere, and examine how atmospheric chemistry and climate change interact(ed) on Venus. This research will improve our understanding of long-standing issues, such as how much water might have been present on Venus in the recent past. The research program will provide an opportunity for Australian science to participate in at least one spacecraft mission to Venus. Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0668345
Funder
Australian Research Council
Funding Amount
$390,700.00
Summary
A highly sensitive mass spectrometer for trace analysis of biomarker molecules to study changes in recent and ancient environments. Maintaining the quality of water and soil is a critically important issue for Australia's economic and social development. To be able to predict and plan the future of our natural assets, it is critical to understand their ecological past and their state before and after European settlement. We will utilize the new instrument to develop and apply innovative technolo ....A highly sensitive mass spectrometer for trace analysis of biomarker molecules to study changes in recent and ancient environments. Maintaining the quality of water and soil is a critically important issue for Australia's economic and social development. To be able to predict and plan the future of our natural assets, it is critical to understand their ecological past and their state before and after European settlement. We will utilize the new instrument to develop and apply innovative technologies providing Australia with new knowledge about the causes and effects of toxic cyanobacterial blooms, eutrophication, and contamination of reservoirs by bush-fires. The new facility will also supply advanced oil fingerprinting techniques to the petroleum industry minimizing exploration risk and increasing the chance of the discovery of new oil deposits.Read moreRead less
Biomolecular chemical survival strategies of terrestrial extremophiles and the spectroscopic search for life on Mars. This project is aimed to place Australian research at the forefront of developments in the search for extraterrestrial life, the evolution of life on earth, and the design of new probes for the identification of microorganisms. The research will link key centres in Australia and the UK with international space agencies (NASA and the European Space Agency) in the search for cutti ....Biomolecular chemical survival strategies of terrestrial extremophiles and the spectroscopic search for life on Mars. This project is aimed to place Australian research at the forefront of developments in the search for extraterrestrial life, the evolution of life on earth, and the design of new probes for the identification of microorganisms. The research will link key centres in Australia and the UK with international space agencies (NASA and the European Space Agency) in the search for cutting edge techniques to be used in the search for extraterrestrial life forms and their links to paleo and extremophile life forms on Earth. Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0668226
Funder
Australian Research Council
Funding Amount
$186,000.00
Summary
A new X-ray spectrometer facility for VIEPS: major and trace element characterisation of geological materials. Australia has a well-earned reputation as a leading innovator in analytical geochemistry and the acquisition of this instrumentation will reinforce that standing. The equipment will support a broad range of research activities and enhance our capability for research training at Honours and post-graduate student level. In addition this project addresses directly our current National Rese ....A new X-ray spectrometer facility for VIEPS: major and trace element characterisation of geological materials. Australia has a well-earned reputation as a leading innovator in analytical geochemistry and the acquisition of this instrumentation will reinforce that standing. The equipment will support a broad range of research activities and enhance our capability for research training at Honours and post-graduate student level. In addition this project addresses directly our current National Research Priority 'an environmentally sustainable Australia', and priority goals 'Developing deep earth resources' and 'Responding to climate change and variability'Read moreRead less
Dynamics and Chemical Evolution of the Earth's Early Mantle. Preliminary numerical results demonstrate that the Earth's mantle may have been compositionally stratified early in its history through a novel interaction between compositional buoyancies and viscosity stratification. This result has important implications for the evolution of the crust and for the chemical and isotopic evolution of the mantle. It also complements recent geochemical evidence for the extraction of a basaltic componen ....Dynamics and Chemical Evolution of the Earth's Early Mantle. Preliminary numerical results demonstrate that the Earth's mantle may have been compositionally stratified early in its history through a novel interaction between compositional buoyancies and viscosity stratification. This result has important implications for the evolution of the crust and for the chemical and isotopic evolution of the mantle. It also complements recent geochemical evidence for the extraction of a basaltic component from the early upper mantle. It is proposed to explore the robustness of this phenomenon in two and three dimensions, its longer-term behaviour, and the evolution of the stratification as the mantle cools to its present condition.Read moreRead less
Learning to predict polymorphism through simulation of nucleation and nanoparticle evolution. Many substances are capable of exhibiting a myriad of different structures despite having the same composition. This behaviour can have a significant impact on the production of new pharmaceuticals, since the sudden appearance of a new form can lead to instant withdrawal of the drug. By understanding how different forms grow, rather than focusing on just the stability of the product, this research will ....Learning to predict polymorphism through simulation of nucleation and nanoparticle evolution. Many substances are capable of exhibiting a myriad of different structures despite having the same composition. This behaviour can have a significant impact on the production of new pharmaceuticals, since the sudden appearance of a new form can lead to instant withdrawal of the drug. By understanding how different forms grow, rather than focusing on just the stability of the product, this research will lead to more reliable prediction of how pharmaceutical molecules might assemble. The same technology will potentially have impacts in many areas of nanoscience through improvements in efficiency, including the production of minerals, desalination and undersea gas recovery.Read moreRead less