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Heat-resisting iron-nickel base alloys in challenging new applications: oxygen permeabilities and resistance to internal oxidation. There is a pressing need to develop heat resisting alloys which can function adequately in higher operating temperatures and gas mixtures rich in carbon and hydrogen to be handled in advanced technologies for power generation. The expected outcomes of this project will provide the basis for design/selection of these more corrosion-resistant alloys.
Bio-oil/char slurry from biomass for co-combustion in coal power plants: achieving power generation with a significant reduction of CO2 emission. This project will develop an advanced co-combustion technology of bio-oil/char slurry (i.e. bioslurry), prepared from biomass pyrolysis products, and coal in the existing coal-fired power plants for achieving significant CO2 reduction. It will enhance Australia's competitive advantage through high impact scientific and technological innovations.
Numerical and experimental studies of the gas-particle flow and dust collection in electrostatic precipitation systems. This project will generate an integrated computer model to describe the gas-solid flow and dust collection in an ElectroStatic Precipitator (ESP). The model can be used to aid the design and control of ESP systems which are widely used for dust collection, leading to more competitive energy and related industries.
Fundamental mechanisms of metaplast formation during coal and biomass pyrolysis. This project investigates the reasons behind why some coals become fluid at high temperatures and apply these findings to biomass. This fluid phase (metaplast) represents the main area of uncertainty in pyolysis. This project builds on current research into coal macerals (the constituents of coal) using specifically developed novel thermal techniques to capture the dynamic behaviour of the fluid phase during its tra ....Fundamental mechanisms of metaplast formation during coal and biomass pyrolysis. This project investigates the reasons behind why some coals become fluid at high temperatures and apply these findings to biomass. This fluid phase (metaplast) represents the main area of uncertainty in pyolysis. This project builds on current research into coal macerals (the constituents of coal) using specifically developed novel thermal techniques to capture the dynamic behaviour of the fluid phase during its transformation. Critically, these techniques offer a new method of characterising tar compounds and in particular the extracted components of the metaplast. It will provide fundamental insight into an area governed by "black art" and empiricism, guide renewable fuel substitution and optimise Australia's coal and biomass reserves.Read moreRead less
Reducing gas and ash corrosion in advanced power generation. Advanced power generation using new coal combustion technologies increases energy efficiency and makes carbon dioxide capture possible, but increases the corrosion problems. This project aims to determine the corrosion behaviour of chromia-scale forming iron- and nickel-base alloys in the presence of deposits (coal ashes and salts) under carbon dioxide rich gas atmospheres. The increased understanding of alloy behaviour in hot corrosiv ....Reducing gas and ash corrosion in advanced power generation. Advanced power generation using new coal combustion technologies increases energy efficiency and makes carbon dioxide capture possible, but increases the corrosion problems. This project aims to determine the corrosion behaviour of chromia-scale forming iron- and nickel-base alloys in the presence of deposits (coal ashes and salts) under carbon dioxide rich gas atmospheres. The increased understanding of alloy behaviour in hot corrosive ashes and gases, will permit more effective materials design and selection leading to more efficient and economic technologies for reliable and low cost carbon capture in energy production, waste-energy conversion and related industries.Read moreRead less
High temperature corrosion induced by multiple secondary oxidants . Heat resisting chromia-forming alloys passivate successfully in clean, dry air at temperatures up to about 950°C. However, this performance is degraded by secondary oxidants (carbon, sulphur, chlorine, water vapour), leading to corrosion failure in important industries. The project aims to investigate the effect of these secondary oxidants on corrosion behaviour of chromia-forming alloys, to identify interactions between multipl ....High temperature corrosion induced by multiple secondary oxidants . Heat resisting chromia-forming alloys passivate successfully in clean, dry air at temperatures up to about 950°C. However, this performance is degraded by secondary oxidants (carbon, sulphur, chlorine, water vapour), leading to corrosion failure in important industries. The project aims to investigate the effect of these secondary oxidants on corrosion behaviour of chromia-forming alloys, to identify interactions between multiple oxidants within the scale, to establish the mechanisms of oxide scale penetration by foreign species, and to evaluate scales on different alloy types. The results will provide a basis for improved design/selection of heat resisting chromia-forming alloys, key to power generation industries.Read moreRead less
Engineered functional metal silica membranes for hydrogen processing. This project focuses on hydrogen processing technologies for the petrochemical, agricultural and coal/energy industries. These sectors employ 110,000 people with annual combined revenues of $80 billion. Advanced technologies are vital for the competitiveness of the Australian economy, and to sustain Australia's social stability and economic growth.
Data-driven modelling of complex reactive flows. Complex reactive flow is dominant in many chemicals, physical and biological processes and should be optimised online for operational efficiency and stability, yet it is hindered by the lack of reliable model techniques. The project tackles this challenge by developing a next-generation data-driven modelling approach via integrating continuum/discrete-scale fluid-particle dynamics with system/control theories, supported by lab/plant experiments. D ....Data-driven modelling of complex reactive flows. Complex reactive flow is dominant in many chemicals, physical and biological processes and should be optimised online for operational efficiency and stability, yet it is hindered by the lack of reliable model techniques. The project tackles this challenge by developing a next-generation data-driven modelling approach via integrating continuum/discrete-scale fluid-particle dynamics with system/control theories, supported by lab/plant experiments. Driven by online data, the generic approach can open up a powerful way to reliably describe the inner state of reactors and online predict operation anomalies. The outcomes can help transform a range of industries to smart manufacturing and design, which is vital to Australia's technological future.Read moreRead less
Engineering the Building Blocks of Novel Interfacial Metastable Oxide Materials. This project aims to engineer the building blocks of a new family of materials recently discovered and patented as interfacial metastable oxide (i-MOx). A key discovery is the interfacial columnar atom alignment adjacent to crystal structures, conferring the materials exceptional ionic conduction well beyond the state-of-the-art, with a broad appeal to ionic transport membranes, electrodes in fuel cells and thermal ....Engineering the Building Blocks of Novel Interfacial Metastable Oxide Materials. This project aims to engineer the building blocks of a new family of materials recently discovered and patented as interfacial metastable oxide (i-MOx). A key discovery is the interfacial columnar atom alignment adjacent to crystal structures, conferring the materials exceptional ionic conduction well beyond the state-of-the-art, with a broad appeal to ionic transport membranes, electrodes in fuel cells and thermal cycling oxygen production. Advanced characterisation techniques will be employed to fundamentally elucidate the role that the interfacial structure plays to deliver remarkable performance. The outcomes will lead to possible breakthroughs in advanced materials for emerging green energy applications.Read moreRead less
Oxy-cofiring of bio-slurry and coal for carbon-negative power generation. This project aims to study co-firing characteristics of bio-slurry fuels and coal under oxy-pulverised-fuel (oxy-PF) conditions. Oxy-PF stationary systems can capture the renewable carbon embedded in bio-slurry fuel from biomass pyrolysis for sequestration, leading to carbon-negative power generation. The expected outcomes are critical knowledge and data regarding the underlying thermochemical reactions responsible for the ....Oxy-cofiring of bio-slurry and coal for carbon-negative power generation. This project aims to study co-firing characteristics of bio-slurry fuels and coal under oxy-pulverised-fuel (oxy-PF) conditions. Oxy-PF stationary systems can capture the renewable carbon embedded in bio-slurry fuel from biomass pyrolysis for sequestration, leading to carbon-negative power generation. The expected outcomes are critical knowledge and data regarding the underlying thermochemical reactions responsible for the co-pyrolysis, volatiles/char co-firing and ash formation from bio-slurry/coal co-firing under oxy-PF conditions. This is expected to enhance Australia's competitive advantage in clean power generation through high-impact scientific and technological innovations, and strengthen the related knowledge and skill base in the country.Read moreRead less