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Adhesive Bonding for LoadBearing Joints in Aluminium Fast Ferries. The aim of this project is to investigate new chemical pre-treatment techniques and new sensor technologies for specific use in adhesively bonding aluminium in the Australian Fast Ferry industry. These technologies are important in increasing the use of adhesives in ships, possibly leading to considerable weight savings, which, in turn increases the payload of the vessel. These advances in shipbuilding practice can help maintain ....Adhesive Bonding for LoadBearing Joints in Aluminium Fast Ferries. The aim of this project is to investigate new chemical pre-treatment techniques and new sensor technologies for specific use in adhesively bonding aluminium in the Australian Fast Ferry industry. These technologies are important in increasing the use of adhesives in ships, possibly leading to considerable weight savings, which, in turn increases the payload of the vessel. These advances in shipbuilding practice can help maintain the world-leading status of the Australian Fast Ferry industry. The technology also has the potential to expand the market for Australian-manufactured adhesives. The project also offers a stimulating learning environment for a PhD student.Read moreRead less
Improving Energy Efficiency through Cool Polymers in Building Materials. The advantages of using cool polymers in industrial applications such as building materials are significant. Cooler buildings are a positive contribution to our global environment with reductions in urban heat and smog through energy efficiency. Moreover, by reducing the overall temperature of the surface coating through inclusion and optimization of IR-reflective pigments, this should lead to polymers which are more durabl ....Improving Energy Efficiency through Cool Polymers in Building Materials. The advantages of using cool polymers in industrial applications such as building materials are significant. Cooler buildings are a positive contribution to our global environment with reductions in urban heat and smog through energy efficiency. Moreover, by reducing the overall temperature of the surface coating through inclusion and optimization of IR-reflective pigments, this should lead to polymers which are more durable when exposed in exterior environments. It is anticipated that the results from this work will have direct impact on the Australian paint market and potentially the commercial and residential building industries of Australia, combined with obvious economic benefits.Read moreRead less
Reversible Addition Fragmentation Chain Transfer (RAFT) Free Radical Copolymerizations of Various Monomers. The proposed project will investigate the structure and properties of statistical copolymers prepared via living free radical polymerization. We will study the characteristics of a wide variety of Reversible Addition Fragmentation Chain Transfer (RAFT) copolymerizations using a range of monomers, including those interesting for biomedical and material science applications. We expect to gai ....Reversible Addition Fragmentation Chain Transfer (RAFT) Free Radical Copolymerizations of Various Monomers. The proposed project will investigate the structure and properties of statistical copolymers prepared via living free radical polymerization. We will study the characteristics of a wide variety of Reversible Addition Fragmentation Chain Transfer (RAFT) copolymerizations using a range of monomers, including those interesting for biomedical and material science applications. We expect to gain a deeper understanding of the influence of the RAFT process on the kinetics and mechanism of copolymerization and the properties of the resulting polymers in order to tailor specific polymer materials for biomedial applications.Read moreRead less
Performance Chemistry of Thermoset Surface Coatings. Surface coatings employed in the COLORBOND® range of pre-painted steel products are remarkable materials that are warranted against fading, peeling and cracking for 25 years. Unfortunately, the desired durability can never be uniform across all applications and performance failures do occur and are costly. Classic durability testing often provides misleading information. This project aims to develop a sound mechanistic model for polyester-is ....Performance Chemistry of Thermoset Surface Coatings. Surface coatings employed in the COLORBOND® range of pre-painted steel products are remarkable materials that are warranted against fading, peeling and cracking for 25 years. Unfortunately, the desired durability can never be uniform across all applications and performance failures do occur and are costly. Classic durability testing often provides misleading information. This project aims to develop a sound mechanistic model for polyester-isocyanate performance chemistry and to develop strategies for 'superdurable polyester' formulations based on these findings. This research will provide recommendations to BHP Coated Steel Australia on adoption of isocyanate based technology in the COLORBOND® range of products.Read moreRead less
Structure-Property Relationships of Polymers with Controlled Architecture. Mechanical properties of a polymer (e.g., how elastic it is and how it dissipates energy when compressed) govern how well it performs as an adhesive, or its behaviour when melted and shaped into a consumer item. This project aims to relate molecular architecture to mechanical properties, using new techniques which permit the creation of polymers wherein each architectural characteristic is separately controlled. This has ....Structure-Property Relationships of Polymers with Controlled Architecture. Mechanical properties of a polymer (e.g., how elastic it is and how it dissipates energy when compressed) govern how well it performs as an adhesive, or its behaviour when melted and shaped into a consumer item. This project aims to relate molecular architecture to mechanical properties, using new techniques which permit the creation of polymers wherein each architectural characteristic is separately controlled. This has the potential to develop fundamental understanding for structure-property relations for the type of branched polymers that are in common use in industry and for which adequate models do not currently exist.Read moreRead less
Accessing Chain Length Dependent Rate Coefficients in Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerisations. The proposed project combines two exciting research areas, namely the chain length dependencies of kinetic coefficients and reversible addition fragmentation chain transfer (RAFT) polymerisations. The starting point of the project will be a novel technique recently invented by our team for termination rate measurement utilizing the RAFT process. Detailed knowledge of cha ....Accessing Chain Length Dependent Rate Coefficients in Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerisations. The proposed project combines two exciting research areas, namely the chain length dependencies of kinetic coefficients and reversible addition fragmentation chain transfer (RAFT) polymerisations. The starting point of the project will be a novel technique recently invented by our team for termination rate measurement utilizing the RAFT process. Detailed knowledge of chain length dependent rate coefficients in both homo- and copolymerisations is essential from both an academic and industrial perspective, because polymerisation kinetics not only govern the reaction rates but influence directly the polymeric material properties.Read moreRead less
Blends of reactive plasticizers with thermoplastic composites for improved processing and properties. This proposal is directed at novel methods of enhancing the processibility, properties and applications of polymers and should have a significant economic impact on the $7 billion commodity polymer market for Australian polymer producers and polymer converters.
The project would also extend the research opportunities of students and researchers in the rapidly growing fields of nano-composites a ....Blends of reactive plasticizers with thermoplastic composites for improved processing and properties. This proposal is directed at novel methods of enhancing the processibility, properties and applications of polymers and should have a significant economic impact on the $7 billion commodity polymer market for Australian polymer producers and polymer converters.
The project would also extend the research opportunities of students and researchers in the rapidly growing fields of nano-composites and reactive polymer processing.Read moreRead less
Mechanisms in Catalytic Chain Transfer Polymerization. The aim of the proposed research is to gain more insight into the mechanisms underlying catalytic chain transfer polymerization, a relatively recent controlled radical polymerization technique which is finding an increasing number of industrial applications, especially in the paint and coatings industry. An improved understanding of the catalytic chain transfer process, of which some very important features are still poorly understood, will ....Mechanisms in Catalytic Chain Transfer Polymerization. The aim of the proposed research is to gain more insight into the mechanisms underlying catalytic chain transfer polymerization, a relatively recent controlled radical polymerization technique which is finding an increasing number of industrial applications, especially in the paint and coatings industry. An improved understanding of the catalytic chain transfer process, of which some very important features are still poorly understood, will ultimately lead to better catalyst design and improved process and product control. This in turn will lead to novel polymeric materials.Read moreRead less
Synthesis of stimuli-responsive star polymers for controlled drug delivery. The project aims to prepare novel star polymers suitable for drug delivery via controlled radical polymerization techniques. Such star polymers can be employed to release drugs within the human body in a controlled manner over time and are thus able to target specific sites, i.e. a tumor. The release characterisitics are be influenced by the structure and the size of the star polymer, which can easily be altered via cont ....Synthesis of stimuli-responsive star polymers for controlled drug delivery. The project aims to prepare novel star polymers suitable for drug delivery via controlled radical polymerization techniques. Such star polymers can be employed to release drugs within the human body in a controlled manner over time and are thus able to target specific sites, i.e. a tumor. The release characterisitics are be influenced by the structure and the size of the star polymer, which can easily be altered via controlled radical polymerization techniques. These novel stars are expected to improve the release kinetics of the drug comparing to similar structured micelles due to their higher stability upon injection.Read moreRead less
Molecular archaeology: new knowledge from molecular weight distributions of synthetic and natural polymers. This project will lead to new understanding of how natural and synthetic polymers are formed. Examples are the enzymatic processes that produce the subtle architecture of rice grains, and the processes that pose problems for developing new techniques for making novel polymer-based materials. The fundamental scientific knowledge from this project will provide a platform for the future devel ....Molecular archaeology: new knowledge from molecular weight distributions of synthetic and natural polymers. This project will lead to new understanding of how natural and synthetic polymers are formed. Examples are the enzymatic processes that produce the subtle architecture of rice grains, and the processes that pose problems for developing new techniques for making novel polymer-based materials. The fundamental scientific knowledge from this project will provide a platform for the future development of improved materials, and for superior grain varieties for food and industrial use. These advances will be of significant benefit to Australian industry and consumers.Read moreRead less