New Methods to Harvest Light: Towards Better Dye-Sensitized Solar Cells. Dye-sensitized solar cell (DSC) technology has emerged as a complementary energy source to silicon photovoltaic technology. The efficiency of the DSC relies heavily on sensitizing molecules to absorb solar photons and then transfer electrons to a semi-conducting particle. This project will investigate new sensitizing methods using a combination of different dyes which work cooperatively to absorb a large part of the solar ....New Methods to Harvest Light: Towards Better Dye-Sensitized Solar Cells. Dye-sensitized solar cell (DSC) technology has emerged as a complementary energy source to silicon photovoltaic technology. The efficiency of the DSC relies heavily on sensitizing molecules to absorb solar photons and then transfer electrons to a semi-conducting particle. This project will investigate new sensitizing methods using a combination of different dyes which work cooperatively to absorb a large part of the solar spectrum and efficiently inject electrons into a semi-conducting particles. The development and understanding of these new methods to sensitize the dye-sensitized solar cell should lead to new and better solar cells.Read moreRead less
Porphyrin Based Supramolecular Assemblies and Arrays III - Model Systems for the Construction of Photosynthetic Mimics and Devices. Solar cells that convert light to electricity are an excellent solution to bringing energy to remote locations with abundant sunlight. This research proposal aims to provide an intellectual grounding in the development of molecular systems and supramolecular arrays that are capable of such solar energy conversion (photovoltaics & artificial photosynthesis) or that ....Porphyrin Based Supramolecular Assemblies and Arrays III - Model Systems for the Construction of Photosynthetic Mimics and Devices. Solar cells that convert light to electricity are an excellent solution to bringing energy to remote locations with abundant sunlight. This research proposal aims to provide an intellectual grounding in the development of molecular systems and supramolecular arrays that are capable of such solar energy conversion (photovoltaics & artificial photosynthesis) or that have potential applications in photonics. Developments in this project may also lead to breakthroughs in areas such as nano-scale computing and cleaner and more sustainable energy productionRead moreRead less
Designing New Visible-light Active Photocatalysts for Efficient CO2 Reduction. The increasing concern over Climate Change has triggered great efforts in developing new CO2 capture technologies. The outcomes of this program will lead to a new class of photocatalysts that underpin the development of economical CO2 reduction for clean fuel production using sunlight. Such technologies will speed up the transition of Australian environmental and energy industries from fossil fuel economy to renewable ....Designing New Visible-light Active Photocatalysts for Efficient CO2 Reduction. The increasing concern over Climate Change has triggered great efforts in developing new CO2 capture technologies. The outcomes of this program will lead to a new class of photocatalysts that underpin the development of economical CO2 reduction for clean fuel production using sunlight. Such technologies will speed up the transition of Australian environmental and energy industries from fossil fuel economy to renewable energy economy. The research program will contribute significantly to knowledge advancement in nanomaterials, surface chemistry, and photochemistry, and falls in the National Research Priority Area of 'Environmentally Sustainable Australia' addressing the key goals of Climate Change and low emission energy supply.Read moreRead less
Scanning Probe Microscopy for Fabrication and Analysis of Polymer Photovoltaics. Australian economic growth will depend increasingly on the provision of devices using materials designed at the molecular level. Scanning probe microscopy, which uses tips placed very close to surfaces to analyse or modify the surfaces with molecular precision, is an indispensible tool in designing such materials. In this project, scanning probe microscopy will be used to analyse and build structures on polymer sola ....Scanning Probe Microscopy for Fabrication and Analysis of Polymer Photovoltaics. Australian economic growth will depend increasingly on the provision of devices using materials designed at the molecular level. Scanning probe microscopy, which uses tips placed very close to surfaces to analyse or modify the surfaces with molecular precision, is an indispensible tool in designing such materials. In this project, scanning probe microscopy will be used to analyse and build structures on polymer solar cells in order to maximise the efficiency of the cells and build prototype nanoscale polymer devices. This will lead to the improvement in devices delivering sustainable energy production - a technology which has the promise of producing energy cheaply from sunlight.Read moreRead less
Single molecule spectroscopy of functional luminescent materials. This project will provide new insights into the light induced processes occurring in individual molecules of potentially useful luminescent materials. The molecules to be studied include new fluorescent probes of biological and polymer systems and single light harvesting nanoparticles with applications in solar energy collection and conversion. The program of work proposed will increase our understanding of light induced chemical ....Single molecule spectroscopy of functional luminescent materials. This project will provide new insights into the light induced processes occurring in individual molecules of potentially useful luminescent materials. The molecules to be studied include new fluorescent probes of biological and polymer systems and single light harvesting nanoparticles with applications in solar energy collection and conversion. The program of work proposed will increase our understanding of light induced chemical processes and assist the design of advanced materials for photomolecular devices.Read moreRead less
Electronically Conducting Nanofibres and Assemblies. With the use of new techniques that have just emerged in the last two years and are receiving rapidly growing interest throughout the world, this project will bring to Australia a new nanofabrication platform for making a variety of complex nanostructures. Fundamental researches on these complex nanostructures will greatly advance nanoscience. New nanotechnologies will be developed to address some world-wide challenging problems, e.g. energy ....Electronically Conducting Nanofibres and Assemblies. With the use of new techniques that have just emerged in the last two years and are receiving rapidly growing interest throughout the world, this project will bring to Australia a new nanofabrication platform for making a variety of complex nanostructures. Fundamental researches on these complex nanostructures will greatly advance nanoscience. New nanotechnologies will be developed to address some world-wide challenging problems, e.g. energy conversion and storage, chemical/biological sensing and other micro- and nanoelectronic devices. This project will bring both breakthrough science and frontier technologies for building and transforming Australian industries and help place Australia at the forefront of nanotechnology. Read moreRead less
Solution Processable, High Dimensional Dendrimers for Plastic Electronics. Microelectronics are present in our everyday life, from numerous chips in our vehicles to our mobile telephones; and the list is almost infinite. The electronics used today are limited to rigid surfaces, and are incompatible for the next generation of technology such as rollable displays and radio frequency identification cards. This proposal describes the development of a new class of high performance flexible electronic ....Solution Processable, High Dimensional Dendrimers for Plastic Electronics. Microelectronics are present in our everyday life, from numerous chips in our vehicles to our mobile telephones; and the list is almost infinite. The electronics used today are limited to rigid surfaces, and are incompatible for the next generation of technology such as rollable displays and radio frequency identification cards. This proposal describes the development of a new class of high performance flexible electronic inks that could be used in the next generation of microelectronics. There is a huge commercial interest in these electronic ink materials and this market is projected to be $7.7 billion by 2012. The proposed electronic inks address issues with current materials such as processability, performance and reproducibility.Read moreRead less
Advanced Ionic Materials for Organic Photovoltaics. Australia will greatly benefit from the development of improved solar energy technology, as a means of addressing the issue of climate change as a result of continued fossil fuel use. Solar power is also advantageous as it also allows electricity to be generated locally where it is needed, which is particularly important for the many remote areas of Australia. The climate in Australia is ideally suited for the electricity production through pho ....Advanced Ionic Materials for Organic Photovoltaics. Australia will greatly benefit from the development of improved solar energy technology, as a means of addressing the issue of climate change as a result of continued fossil fuel use. Solar power is also advantageous as it also allows electricity to be generated locally where it is needed, which is particularly important for the many remote areas of Australia. The climate in Australia is ideally suited for the electricity production through photovoltaics, and this project will focus on improving the performance of these devices to enable their widespread use. Read moreRead less
Photoactive Semiconducting Biopolymers. The basic aims of this project are to elucidate, manipulate, and utilise the unique chemical and physical properties of a class of biopolymers called the melanins. These materials are the only known solid state semiconducting biopolymers, and are non-toxic, biocompatible, and biodegradable. Their use as active components in biomimetic soft electonic, optoelectronic or photovoltaic devices, has not hitherto been demonstrated. It is anticipated that the k ....Photoactive Semiconducting Biopolymers. The basic aims of this project are to elucidate, manipulate, and utilise the unique chemical and physical properties of a class of biopolymers called the melanins. These materials are the only known solid state semiconducting biopolymers, and are non-toxic, biocompatible, and biodegradable. Their use as active components in biomimetic soft electonic, optoelectronic or photovoltaic devices, has not hitherto been demonstrated. It is anticipated that the key outcomes from the project will be a demonstration of biopolymer-based photoelectrochemical and solid-state p-i-n solar cells, and an improved understanding of the physics and chemistry of these important biological macromolecules.Read moreRead less
Characterization and design of new soft electrolyte materials. The use of fossil fuels for energy generation contributes heavily to global warming. The development of new types of energy sources (e.g. fuel cells) and energy storage devices (e.g. batteries) is of crucial importance to ease this pressure on the environment. The search for new, high energy-density electrolyte materials for these applications is intense. Recently, plastic crystal materials have been identified as potential electroly ....Characterization and design of new soft electrolyte materials. The use of fossil fuels for energy generation contributes heavily to global warming. The development of new types of energy sources (e.g. fuel cells) and energy storage devices (e.g. batteries) is of crucial importance to ease this pressure on the environment. The search for new, high energy-density electrolyte materials for these applications is intense. Recently, plastic crystal materials have been identified as potential electrolytes in a variety of electrochemical devices. These materials show high conductivity at ambient temperatures in their plastic (or soft) phase. This project aims to further investigate and develop these novel materials.Read moreRead less