Synthesis of oligomers in dense carbon dioxide. The aim of the project is to develop a novel technique for the synthesis of low molecular weight polymers (oligomers) using dense carbon dioxide as a polymerisation solvent. The use of elevated pressure is the major impediment to the commercialisation of such technology. The technique proposed in this project will enable oligomers to be produced at greatly reduced operating pressures and may lead to a more general procedure for conducting other t ....Synthesis of oligomers in dense carbon dioxide. The aim of the project is to develop a novel technique for the synthesis of low molecular weight polymers (oligomers) using dense carbon dioxide as a polymerisation solvent. The use of elevated pressure is the major impediment to the commercialisation of such technology. The technique proposed in this project will enable oligomers to be produced at greatly reduced operating pressures and may lead to a more general procedure for conducting other types of polymer synthesis in dense carbon dioxide.Read moreRead less
An Integrated Framework for Optimisation and Control of Key Product Properties in Emulsion Polymerisation. Emulsion polymerization is of major industrial importance. In addition to process efficiency, the use of water as the reactor medium provides environmental benefits. This proposal is aimed at building an integrated framework to analyse, model, control and optimise emulsion polymerisation systems in order to understand, design and operate such complex systems to obtain desired polymer produc ....An Integrated Framework for Optimisation and Control of Key Product Properties in Emulsion Polymerisation. Emulsion polymerization is of major industrial importance. In addition to process efficiency, the use of water as the reactor medium provides environmental benefits. This proposal is aimed at building an integrated framework to analyse, model, control and optimise emulsion polymerisation systems in order to understand, design and operate such complex systems to obtain desired polymer product characteristics. Complex kinetic, transport and evolution equations will be analysed and solved for predicting and controlling key product properties. This project will provide not only a significant advance in fundamental knowledge of polymerisation systems but will also enable production of cost-effective ?designer polymers? for a wide-range of applications.Read moreRead less
Particle motion and particle-convective heat transfer near the walls of fluidized beds. Background: Fluidized bed technology has important industrial applications ranging from petrol production to mineral processing for metal production. Such processes take advantage of the high rates of heat transfer in gas-fluidized beds.
Objective of project: To improve understanding and modelling of heat transfer in gas fluidized beds through the application of state-of-the-art experimental (Positron Emiss ....Particle motion and particle-convective heat transfer near the walls of fluidized beds. Background: Fluidized bed technology has important industrial applications ranging from petrol production to mineral processing for metal production. Such processes take advantage of the high rates of heat transfer in gas-fluidized beds.
Objective of project: To improve understanding and modelling of heat transfer in gas fluidized beds through the application of state-of-the-art experimental (Positron Emission Particle Tracking) and modelling (Discrete Element Method simulation) techniques.
Expected outcomes of project: New knowledge of the mechanisms of fluidized bed heat transfer. Improved the prediction of heat transfer coefficients with consequent improvements in the design and operation of fluidized bed processes.
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