The systematic development of fundamentally important group 15 compounds: their applications to innovative industrial and environmental processes. The strong coordinating ability of organo-phosphorus/arsonic acids will be harnessed to support a series of metallic clusters that will be exploited for their use as magnetic materials in gas storage and as catalysts. The novel acids will be investigated for use as water soluble purification agents for, for example, mercury, uranium and lead.
Discovery Early Career Researcher Award - Grant ID: DE170100200
Funder
Australian Research Council
Funding Amount
$360,000.00
Summary
Anion-templated functional architectures. This project aims to introduce a method for preparing large, complex materials from relatively simple precursors. Negatively-charged species, anions, will be used to assemble positively-charged organic molecules into three-dimensional structures, including cages and porous framework materials. This will increase fundamental understanding of how anions behave and their use in self-assembly processes. The structures made using this approach are expected to ....Anion-templated functional architectures. This project aims to introduce a method for preparing large, complex materials from relatively simple precursors. Negatively-charged species, anions, will be used to assemble positively-charged organic molecules into three-dimensional structures, including cages and porous framework materials. This will increase fundamental understanding of how anions behave and their use in self-assembly processes. The structures made using this approach are expected to remove dangerous environmental pollutants from water and store the industrially-relevant gases, hydrogen and carbon dioxide. This offers potential applications in clean energy technology (e.g. hydrogen storage for fuel cells) and environmental remediation (carbon dioxide storage, polycyclic aromatic hydrocarbon removal).Read moreRead less
Electronic functionality in nanoscale materials: from discovery to design. This project will develop innovative multifunctional carbon/boron-nitride nanomaterials by devising new strategies to manipulate their electronic functionality. Outcomes will include technological breakthroughs leading to smart materials for energy storage, greenhouse gas emission reduction and nanoelectronics.
Functional molecular nanomaterials. The design and construction of advanced nanomaterials is a key step in the push towards more efficient energy systems and smarter technologies. Through the strategic assembly of new classes of molecular nanomaterials, this project will lead to important fundamental advances in nanoscience and will underpin a range of new high-level technologies.
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE120100223
Funder
Australian Research Council
Funding Amount
$340,000.00
Summary
Advanced X-ray diffraction facility for high energy and extreme conditions. X-ray powder diffraction is a powerful technique for determining the structure of matter at the atomic scale. This project will establish a new Australian capability for X-ray powder diffraction under extreme conditions that emulate real harsh service environments for advanced functional materials.
Borametallacycles: confluence of metallacycle and boracycle chemistries. Metallacycles are cyclic structures constructed from a transition metal and the first row elements, such as carbon, nitrogen and oxygen. They underpin numerous technological applications in catalysis and materials chemistry. Borametallacycles which include the missing element boron will be explored with a view to developing new materials with novel properties.
Discovery Early Career Researcher Award - Grant ID: DE190100005
Funder
Australian Research Council
Funding Amount
$404,000.00
Summary
Perovskite-based electrocatalysts for water electrolysis. This project aims to develop novel perovskite-based catalysts with high catalytic activity and long-term stability for the practical application of alkaline water splitting. A new family of overall water-splitting materials in alkaline media based on low-cost and earth-abundant perovskite oxides will be developed, which offer a viable alternative to the benchmark noble metal-based catalysts. Clean hydrogen energy generated by these effici ....Perovskite-based electrocatalysts for water electrolysis. This project aims to develop novel perovskite-based catalysts with high catalytic activity and long-term stability for the practical application of alkaline water splitting. A new family of overall water-splitting materials in alkaline media based on low-cost and earth-abundant perovskite oxides will be developed, which offer a viable alternative to the benchmark noble metal-based catalysts. Clean hydrogen energy generated by these efficient perovskite catalysts will not only reduce carbon dioxide emissions and alleviate air pollution, but also create opportunities for Australian industries, such as the widespread use of renewable solar and wind energy and fuel cell vehicles.Read moreRead less
Low oxidation state magnesium complexes: multitalented reagents for sustainable chemical synthesis. The chemistry of stable low oxidation state s-block compounds was initiated at Monash in 2007. In addition to being of major fundamental importance, applications of these highly reactive systems have rapidly developed. To cement Australia's international lead in this emerging and competitive field, this project aims to develop a new generation of magnesium(I) (and related) compounds, and to instal ....Low oxidation state magnesium complexes: multitalented reagents for sustainable chemical synthesis. The chemistry of stable low oxidation state s-block compounds was initiated at Monash in 2007. In addition to being of major fundamental importance, applications of these highly reactive systems have rapidly developed. To cement Australia's international lead in this emerging and competitive field, this project aims to develop a new generation of magnesium(I) (and related) compounds, and to install them as sought after reagents for sustainable synthetic methodologies. For the first time, environmentally benign s-block compounds will be utilised for the low energy stoichiometric and catalytic transformation of abundant, often inert gaseous small molecules, for example, hydrogen, nitrogen, carbon dioxide, carbon monoxide, to value added products important to industry and academia.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE120100026
Funder
Australian Research Council
Funding Amount
$480,000.00
Summary
A surface characterisation facility. This surface characterisation facility will provide scientists with an understanding of material's surfaces and interfaces. This will lead to a range of new technologies and innovative solutions required to address the many resource and environmental challenges facing our planet now and in the future.
Concentrating solar thermal energy storage using metal hydrides. This project will investigate energy storage for concentrating solar thermal energy systems. These systems can be used to efficiently generate electricity in remote locations, day and night, using solar energy. The solar energy is converted to heat energy and then chemical energy stored in a metal-hydrogen compound.