Hybrid Toughening of Carbon Fibre Composites for Liquid Hydrogen Storage. This project aims to develop hybrid toughening technologies to overcome the major problem of transverse matrix cracking and splitting in existing carbon fibre composites when subjected to thermal-mechanical loading at the ultracold liquid hydrogen temperature. Nano-toughened thin-ply carbon fibre layers will be hybridised with standard-ply laminates to sustain internal pressure and external impact loading at cryogenic temp ....Hybrid Toughening of Carbon Fibre Composites for Liquid Hydrogen Storage. This project aims to develop hybrid toughening technologies to overcome the major problem of transverse matrix cracking and splitting in existing carbon fibre composites when subjected to thermal-mechanical loading at the ultracold liquid hydrogen temperature. Nano-toughened thin-ply carbon fibre layers will be hybridised with standard-ply laminates to sustain internal pressure and external impact loading at cryogenic temperatures without leaks. The hybrid composites are expected to enable Australian companies to engineer, manufacture and export lightweight carbon fibre tanks for storing and exporting liquid hydrogen, which is emerging as a transformational opportunity for Australia to become a global supplier of green energy.Read moreRead less
Borametallacycles: confluence of metallacycle and boracycle chemistries. Metallacycles are cyclic structures constructed from a transition metal and the first row elements, such as carbon, nitrogen and oxygen. They underpin numerous technological applications in catalysis and materials chemistry. Borametallacycles which include the missing element boron will be explored with a view to developing new materials with novel properties.
Low oxidation state magnesium complexes: multitalented reagents for sustainable chemical synthesis. The chemistry of stable low oxidation state s-block compounds was initiated at Monash in 2007. In addition to being of major fundamental importance, applications of these highly reactive systems have rapidly developed. To cement Australia's international lead in this emerging and competitive field, this project aims to develop a new generation of magnesium(I) (and related) compounds, and to instal ....Low oxidation state magnesium complexes: multitalented reagents for sustainable chemical synthesis. The chemistry of stable low oxidation state s-block compounds was initiated at Monash in 2007. In addition to being of major fundamental importance, applications of these highly reactive systems have rapidly developed. To cement Australia's international lead in this emerging and competitive field, this project aims to develop a new generation of magnesium(I) (and related) compounds, and to install them as sought after reagents for sustainable synthetic methodologies. For the first time, environmentally benign s-block compounds will be utilised for the low energy stoichiometric and catalytic transformation of abundant, often inert gaseous small molecules, for example, hydrogen, nitrogen, carbon dioxide, carbon monoxide, to value added products important to industry and academia.Read moreRead less
A thermal battery for dish-Stirling concentrated solar power systems. This project will investigate new high temperature (> 600 degrees Celsius) metal hydrides and carbonates suitable for thermochemical energy storage in dish-Stirling Concentrated Solar Power systems. The intended outcome is to discover cost effective, energy dense materials that are capable of operating over a 30 year life span in a solar power plant. This will enable 24/7 electricity production from renewable sources in a disp ....A thermal battery for dish-Stirling concentrated solar power systems. This project will investigate new high temperature (> 600 degrees Celsius) metal hydrides and carbonates suitable for thermochemical energy storage in dish-Stirling Concentrated Solar Power systems. The intended outcome is to discover cost effective, energy dense materials that are capable of operating over a 30 year life span in a solar power plant. This will enable 24/7 electricity production from renewable sources in a dispatchable solar platform, ideal for remote locations. The successful development of high temperature metal hydrides and carbonates will finally provide an energy storage solution to dish-Stirling Concentrated Solar Power systems, which will greatly reduce our reliance on fossil fuels to produce electricity.Read moreRead less
Exploration of highly regenerable boron-nitrogen based hydrides for hydrogen storage. The project will design and synthesise novel boron-nitrogen hydrides. It will employ material design strategies, such as new synthesis techniques, dopant destabilisation, and dehydrogenation catalysts to design and experimentally validate novel multicomponent hydride systems with high storage capacities (above 9 wt% under near-ambient conditions) and high reversibility. The outcomes of this project will make a ....Exploration of highly regenerable boron-nitrogen based hydrides for hydrogen storage. The project will design and synthesise novel boron-nitrogen hydrides. It will employ material design strategies, such as new synthesis techniques, dopant destabilisation, and dehydrogenation catalysts to design and experimentally validate novel multicomponent hydride systems with high storage capacities (above 9 wt% under near-ambient conditions) and high reversibility. The outcomes of this project will make a significant enhancement in the performance of solid state hydrogen storage materials and will deliver a viable storage technology for a range of fuel cell applications.Read moreRead less
Liquid-phase hydrogen carriers for energy storage and delivery. This project aims to overcome hydrogen storage and delivery issues by developing liquid-phase hydrogen storage materials with high hydrogen capacity, exceptional stability and that do not change phase during hydrogen evolution. This project will build on the recent synthesis of strategically important hydrogen storage compounds. The innovative liquid-phase hydrogen storage and delivery technology will enable effective usage of estab ....Liquid-phase hydrogen carriers for energy storage and delivery. This project aims to overcome hydrogen storage and delivery issues by developing liquid-phase hydrogen storage materials with high hydrogen capacity, exceptional stability and that do not change phase during hydrogen evolution. This project will build on the recent synthesis of strategically important hydrogen storage compounds. The innovative liquid-phase hydrogen storage and delivery technology will enable effective usage of established liquid fuel distribution techniques and infrastructure throughout the country. The project would benefit renewable energy, chemical, and manufacturing industries, where new employment opportunities would be created.Read moreRead less
Novel hydrogen-rich liquids for storing and transporting hydrogen at scale. Hydrogen is proposed as the best candidate to store large amounts of energy produced by intermittent sources such as wind and solar. This project aims to address challenges in storing and transporting large amounts of hydrogen in a safe and effective way by developing novel liquid-phase compounds that contain light elements including boron, carbon, nitrogen, and hydrogen. Expected outcomes of this project include new liq ....Novel hydrogen-rich liquids for storing and transporting hydrogen at scale. Hydrogen is proposed as the best candidate to store large amounts of energy produced by intermittent sources such as wind and solar. This project aims to address challenges in storing and transporting large amounts of hydrogen in a safe and effective way by developing novel liquid-phase compounds that contain light elements including boron, carbon, nitrogen, and hydrogen. Expected outcomes of this project include new liquid compounds that can effectively and safely store hydrogen at scale using the exisiting liquid hydrocarbon fuel infrastructure. This should provide significant benefits in the establishment of renewable hydrogen for domestic consumption and more for exporting sustainable and clean fuel using hydrogen as the energy carrier.Read moreRead less
Improved hydrogen geological storage via zeta potential measurements. Hydrogen is a clean fuel which has the potential to revolutionize the energy supply chain by complete decarbonisation. An estimated 50-fold increase in the global hydrogen market is expected by 2050, totalling AUD$16.3 trillion. However, the key barrier to a hydrogen economy is hydrogen storage, as hydrogen is highly volatile, compressible and flammable. Underground hydrogen storage, i.e. storage of hydrogen in sedimentary geo ....Improved hydrogen geological storage via zeta potential measurements. Hydrogen is a clean fuel which has the potential to revolutionize the energy supply chain by complete decarbonisation. An estimated 50-fold increase in the global hydrogen market is expected by 2050, totalling AUD$16.3 trillion. However, the key barrier to a hydrogen economy is hydrogen storage, as hydrogen is highly volatile, compressible and flammable. Underground hydrogen storage, i.e. storage of hydrogen in sedimentary geologic formations, is a potential option to solve this problem. In this project we will provide fundamental data required to establish hydrogen underground monitoring techniques, and to develop associated large-scale models with which underground hydrogen storage efficiency and security can be predicted.Read moreRead less
Large-scale and long-term storage of Hydrogen in underground reservoirs. This project aims to test effective strategies to re-use Australia’s depleted gas fields for large-scale, long-term, renewable energy storage. With Australia’s energy system undergoing a radical hydrogen-based energy transformation, a critical challenge in the years ahead will be to effectively store massive volumes of hydrogen for long periods (months and years). The overall expected outcome of this research is to fully un ....Large-scale and long-term storage of Hydrogen in underground reservoirs. This project aims to test effective strategies to re-use Australia’s depleted gas fields for large-scale, long-term, renewable energy storage. With Australia’s energy system undergoing a radical hydrogen-based energy transformation, a critical challenge in the years ahead will be to effectively store massive volumes of hydrogen for long periods (months and years). The overall expected outcome of this research is to fully understand the performance and the geological and environmental implications of long-term storage of hydrogen in empty gas fields. Benefit: this foundational scientific knowledge is crucial if Australia is to effectively bring about this new, sustainable, affordable, long-term, hydrogen-storage solution. Read moreRead less
A New Spin on Liquid Hydrogen: Controlled Cold Energy. While hydrogen is set to play a leading role in global decarbonisation, significant challenges remain regarding methods for its reliable storage and transportation. Hydrogen liquefaction has emerged as a promising approach in this regard due to its high energy density and hydrogen purity, but is currently prohibitively expensive. In this project we will exploit the peculiar spin physics of hydrogen to alleviate liquefactions costs through t ....A New Spin on Liquid Hydrogen: Controlled Cold Energy. While hydrogen is set to play a leading role in global decarbonisation, significant challenges remain regarding methods for its reliable storage and transportation. Hydrogen liquefaction has emerged as a promising approach in this regard due to its high energy density and hydrogen purity, but is currently prohibitively expensive. In this project we will exploit the peculiar spin physics of hydrogen to alleviate liquefactions costs through the provision of controllable refrigeration (so-called 'cold energy') following regasification. In particular we will measure, optimise and exploit the highly endothermic catalysed conversion of para- to ortho- hydrogen, which can provide up to 525 kJ/kg of cooling at convenient temperatures. Read moreRead less