Nanocomposite Mesoporous Materials for Gas Separations of Environmental Significance. The management of greenhouse and other acid gas emissions is vital to a sustainable future of both the economy and the ecosystem. This project will develop novel nano-materials for gas separation by tethering organic functional groups to the surface of porous inorganic supports. These materials offer the promise of combining the high selectivity and high capacity of liquid phase absorption systems with the rapi ....Nanocomposite Mesoporous Materials for Gas Separations of Environmental Significance. The management of greenhouse and other acid gas emissions is vital to a sustainable future of both the economy and the ecosystem. This project will develop novel nano-materials for gas separation by tethering organic functional groups to the surface of porous inorganic supports. These materials offer the promise of combining the high selectivity and high capacity of liquid phase absorption systems with the rapid transport rates of gas-solid adsorption systems. Success would open up several new possibilities for reengineering gas separation systems based on the use of these materials in solution, as solid phase adsorbents (pressure swing adsorption) and/or as permeselective gas membranes.Read moreRead less
Mapping new cathode materials for aqueous rechargeable batteries: The mechanism of intercalation of lithium in aqueous solutions. This technology could power electric vehicles of the future. With the aid of using advanced oxide and phosphate materials for an aqueous battery, the project will establish a widespread use of green energy for national benefit. This will help us to reduce the current emission observed in transport and energy conversion. The project will facilitate an understanding the ....Mapping new cathode materials for aqueous rechargeable batteries: The mechanism of intercalation of lithium in aqueous solutions. This technology could power electric vehicles of the future. With the aid of using advanced oxide and phosphate materials for an aqueous battery, the project will establish a widespread use of green energy for national benefit. This will help us to reduce the current emission observed in transport and energy conversion. The project will facilitate an understanding the electrochemical energy storage technology. The challenging and significant results from this project will contribute to the energy industries to build non-pollutant high energy storage equipments and productivity of Australia's research and development.Read moreRead less
Energy transforming polymers: from single molecules to devices. Climate control and the rapidly increasing demand for energy is driving the search for alternative sustainable energy sources. Flexible plastics will be a primary component of the new generation of solar harvesting and energy conversion materials. The objective of this project is to gain an understanding of the way polymers interact with light and can convert absorbed solar energy into electrical power and other useful forms of ene ....Energy transforming polymers: from single molecules to devices. Climate control and the rapidly increasing demand for energy is driving the search for alternative sustainable energy sources. Flexible plastics will be a primary component of the new generation of solar harvesting and energy conversion materials. The objective of this project is to gain an understanding of the way polymers interact with light and can convert absorbed solar energy into electrical power and other useful forms of energy. The outcomes of the project will allow the improved design of plastics for applications in solar energy conversion.Read moreRead less
Synthesis of Unique Mesoporous Graphitic Carbons and their Application to Fundamental Problems in Adsorption Science. The development of synthesis techniques to create porous graphitic carbons with highly ordered pore structures, easily accessible pore volume and good electrical conductivity can underpin technological advancements in many industrial applications such as energy storage, removal of pollutants from exhaust streams, direct-methanol fuel cells and lithium ion batteries. Techniques de ....Synthesis of Unique Mesoporous Graphitic Carbons and their Application to Fundamental Problems in Adsorption Science. The development of synthesis techniques to create porous graphitic carbons with highly ordered pore structures, easily accessible pore volume and good electrical conductivity can underpin technological advancements in many industrial applications such as energy storage, removal of pollutants from exhaust streams, direct-methanol fuel cells and lithium ion batteries. Techniques developed in this project are also applicable to creating other materials important to advanced sensors and optoelectronics. The fundamental study of water adsorption and hysteresis using these carbons will help us create better models for adsorption. This will underpin theoretical studies, characterisation and optimisation of carbon materials into the future. Read moreRead less
Carbon dioxide conversion over nanostructured mixed metal catalysts. Nanocatalysts are particles of very small size that have the ability to accelerate chemical reactions. This project will develop nanocatalysts to convert carbon dioxide into other small molecules to provide new options for managing greenhouse gas emissions.
TAILORING OF CARBON MATERIALS FOR USE IN DIRECT CARBON FUEL CELLS. This project aims to develop a fundamental understanding of and methods for tailoring carbon materials to be used in high efficiency (80-85%) direct carbon fuel cells (DCFC). This project addresses an important area in clean and efficient energy supply to meet the World's long-term energy and environmental requirements. Specifically, we aim to focus on the carbon particulates based on carbon black materials with a turbostratic st ....TAILORING OF CARBON MATERIALS FOR USE IN DIRECT CARBON FUEL CELLS. This project aims to develop a fundamental understanding of and methods for tailoring carbon materials to be used in high efficiency (80-85%) direct carbon fuel cells (DCFC). This project addresses an important area in clean and efficient energy supply to meet the World's long-term energy and environmental requirements. Specifically, we aim to focus on the carbon particulates based on carbon black materials with a turbostratic structure, and to investigate the relationship between the microstructures of synthetic carbon black materials and their efficacy in DCFC systems. Ultimately, we aim to engineer novel carbon particulates for use in DCFCs.Read moreRead less
Polyoxometalate Clusters: Catalytic Chemistry in Solution and Condensed States. Polyoxometalate cluster anions are soluble metal-oxygen clusters that are cheap, robust and non-toxic.
Conditions for systematic tuning of redox potentials over the range +2 to -3 V have become accessible via certain photo-active polyoxometalates. The same system can provide powerful oxidants (that rival chlorine) and powerful reductants (that rival potassium).
The program will take advantage of this unique ....Polyoxometalate Clusters: Catalytic Chemistry in Solution and Condensed States. Polyoxometalate cluster anions are soluble metal-oxygen clusters that are cheap, robust and non-toxic.
Conditions for systematic tuning of redox potentials over the range +2 to -3 V have become accessible via certain photo-active polyoxometalates. The same system can provide powerful oxidants (that rival chlorine) and powerful reductants (that rival potassium).
The program will take advantage of this unique range of properties to explore:-
(i) coupling of photo- and electro-chemical processes into effective catalytic cycles;
(ii) photo- and electro-chemical processes in ionic liquid solvents;
(iii) synthesis and redox reactivity of nanoparticles stabilised by polyoxometalates.
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