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Fabrication of Magnesium Diboride (MgB2) thick films. The recent discovery of superconductivity at 39 K in MgB2 has stimulated considerable interest in terms of both fundamental research and applications. The purpose of the proposed project is to conduct fundamental studies on the synthesis, structures and microstructures, and physical properties of doped and undoped MgB2 thick films. The ultimate goal of this study is to fabricate high quality MgB2 thick films on different substrates and to gai ....Fabrication of Magnesium Diboride (MgB2) thick films. The recent discovery of superconductivity at 39 K in MgB2 has stimulated considerable interest in terms of both fundamental research and applications. The purpose of the proposed project is to conduct fundamental studies on the synthesis, structures and microstructures, and physical properties of doped and undoped MgB2 thick films. The ultimate goal of this study is to fabricate high quality MgB2 thick films on different substrates and to gain a better understanding of their various properties with a view to device application.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0237384
Funder
Australian Research Council
Funding Amount
$156,000.00
Summary
Raman Spectroscopy Mapping Facility. This proposal seeks to provide a confocal Raman spectrometer for researchers at the Universities of Wollongong, Western Sydney, Newcastle and University of Technology, Sydney. The Facility will have the exceptional capability of characterising and mapping, at the micron level, the chemical nature of a wide range of advanced materials under development in our laboratories. The information derived will be of critical value for potential applications such as new ....Raman Spectroscopy Mapping Facility. This proposal seeks to provide a confocal Raman spectrometer for researchers at the Universities of Wollongong, Western Sydney, Newcastle and University of Technology, Sydney. The Facility will have the exceptional capability of characterising and mapping, at the micron level, the chemical nature of a wide range of advanced materials under development in our laboratories. The information derived will be of critical value for potential applications such as new corrosion-protection coatings, highly selective chemical and biochemical sensors, and new solar energy materials. The Facility will also be invaluable for the quantitative characterisation of forensic and geological samples that are otherwise difficult to identify due to their heterogeneous nature.Read moreRead less
Atomistic Mechanisms of Stress Relaxation in Amorphous Materials. Amorphous materials represent a major thrust in the search for new materials. Metallic glasses have very high strength and can be cast to much finer tolerances than regular (polycrystalline) metals. Ceramic glasses are finding increasing applications in data storage, photoelectronics and fibre optics. The greatest obstacle to the application of amorphous solids is their brittleness. The goal of this project is to use accurate comp ....Atomistic Mechanisms of Stress Relaxation in Amorphous Materials. Amorphous materials represent a major thrust in the search for new materials. Metallic glasses have very high strength and can be cast to much finer tolerances than regular (polycrystalline) metals. Ceramic glasses are finding increasing applications in data storage, photoelectronics and fibre optics. The greatest obstacle to the application of amorphous solids is their brittleness. The goal of this project is to use accurate computer simulations to provide detailed pictures of how atomic motions relax stress in very different types of glasses and, through this insight, explore ways of modifying the mechanical properties of these materials.Read moreRead less
Cooperativity in Spin Crossover Systems: Memory, Magnetism and Microporosity. Spin-crossover centres are a well known form of inorganic electronic switch for which variation of temperature, pressure and irradiation leads to a change in d-electron configuration and therefore changes to structure, colour and magnetism. Here we aim to synthesise and study a wide variety of new spin-crossover systems where cooperativitiy between centres, induced by careful supramolecular design, will lead to molecul ....Cooperativity in Spin Crossover Systems: Memory, Magnetism and Microporosity. Spin-crossover centres are a well known form of inorganic electronic switch for which variation of temperature, pressure and irradiation leads to a change in d-electron configuration and therefore changes to structure, colour and magnetism. Here we aim to synthesise and study a wide variety of new spin-crossover systems where cooperativitiy between centres, induced by careful supramolecular design, will lead to molecules and materials having memory retention, magnetic ordering and/or microporosity. The significance of these aims covers several fundamental questions in the science of electronic systems. We also identify a number of potential nanochemical switching applications for the unique systems proposed.Read moreRead less
The First Chemically Accurate Tools in Theoretical Materials Research. Non-metallic materials are widely used in catalytic, separation and sensing applications. This project will create a new, accurate, general and systematic approach to the computational study of non-metallic materials and will provide an enormous step forward in our ability to design these materials for specific applications. With ever increasing demand, growing world population and shrinking natural resources, the benefits of ....The First Chemically Accurate Tools in Theoretical Materials Research. Non-metallic materials are widely used in catalytic, separation and sensing applications. This project will create a new, accurate, general and systematic approach to the computational study of non-metallic materials and will provide an enormous step forward in our ability to design these materials for specific applications. With ever increasing demand, growing world population and shrinking natural resources, the benefits of such rational materials design impact on the development of new, safer, more efficient, reusable materials in chemical, engineering, electronic and biological applications. Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0989127
Funder
Australian Research Council
Funding Amount
$400,000.00
Summary
A High-Throughput Neutron Spectrometer for The Study of Atomic and Molecular Motion at ANSTO. Neutron scattering enables new science across a broad range of disciplines, and for this reason it is undergoing major expansion in the USA, Europe, Japan and Australia. Various diffactometers and spectrometers have recently been built at ANSTO, but an instrumental option for a high-throughput cross-discipline spectroscopy is urgently needed. Fortunately, it is fairly straightforward to add this type of ....A High-Throughput Neutron Spectrometer for The Study of Atomic and Molecular Motion at ANSTO. Neutron scattering enables new science across a broad range of disciplines, and for this reason it is undergoing major expansion in the USA, Europe, Japan and Australia. Various diffactometers and spectrometers have recently been built at ANSTO, but an instrumental option for a high-throughput cross-discipline spectroscopy is urgently needed. Fortunately, it is fairly straightforward to add this type of option to an existing spectrometer that will broaden its user-base from specialised applications in physics to more general applications in physics, chemistry, materials-science and biology. This additional option provides a totally new way for Australian scientists to study atomic and molecular motions. Read moreRead less
Polynuclear Spin-Crossover Molecular Switches: Host-Guest Chemistry, Magnetism and Memory. The generation of advanced nanomaterials requires both a control of nanoscale structure and the incorporation of specific properties into that structure. This project will lead to significant new developments in this area, with the assembly of complex molecular systems containing electronic switches. The unique combination of nanoscale switching and guest-binding and/or magnetic ordering in these systems ....Polynuclear Spin-Crossover Molecular Switches: Host-Guest Chemistry, Magnetism and Memory. The generation of advanced nanomaterials requires both a control of nanoscale structure and the incorporation of specific properties into that structure. This project will lead to significant new developments in this area, with the assembly of complex molecular systems containing electronic switches. The unique combination of nanoscale switching and guest-binding and/or magnetic ordering in these systems will lead to entirely new materials properties, leading in turn to fundamental advances in the science of molecular electronics and nanomaterials. Benefits of the research are wide-ranging, and include the development of innovative new technologies for molecular sensing, molecular separations, data storage and visual displays.Read moreRead less
Investigation of a series of metallic sustrate materials suitable for developing long Y-Ba-Cu-O superconductors. Aims: Researchers from Institute for Superconducting and Electronic Materials, the University of Wollongong (UoW) & the Dept. Mat. Sci & Eng., University of Cincinnati (UC) in USA will build strong collaborations through joint research on a series of metallic substrate materials. Significance: The research work will contribute to the development of the second generation of high temper ....Investigation of a series of metallic sustrate materials suitable for developing long Y-Ba-Cu-O superconductors. Aims: Researchers from Institute for Superconducting and Electronic Materials, the University of Wollongong (UoW) & the Dept. Mat. Sci & Eng., University of Cincinnati (UC) in USA will build strong collaborations through joint research on a series of metallic substrate materials. Significance: The research work will contribute to the development of the second generation of high temperature superconducting wire technology. Expected outcomes: strengthen international research experience for junior researchers and develop new collaborations between senior researchers from UoW in Australia and UC in USA.Read moreRead less
Metal Directed Assembly of New Discrete and Framework Supramolecular Systems. An important aspect of this project is the development of strategies for assembling molecules and metals into larger units - leading to novel compounds and materials for which unusual and potentially useful properties can be anticipated. These may include materials that act as catalysts for chemical reactions or absorb and store gases (such as hydrogen for use as a fuel). More generally, the area is one that will under ....Metal Directed Assembly of New Discrete and Framework Supramolecular Systems. An important aspect of this project is the development of strategies for assembling molecules and metals into larger units - leading to novel compounds and materials for which unusual and potentially useful properties can be anticipated. These may include materials that act as catalysts for chemical reactions or absorb and store gases (such as hydrogen for use as a fuel). More generally, the area is one that will underpin the 'bottom-up' approach (building tiny components from individual molecules and ions) in the rapidly expanding field of nanotechnology. Clearly, if Australia is to remain internationally competitive in such new technologies then an understanding of processes of the type outlined in this proposal will be essential.Read moreRead less
Cooperativity in Spin-Crossover Systems: Memory, Magnetism and Microporosity. Spin-crossover centres are a well known form of inorganic electronic switch for which variation of temperature, pressure and irradiation leads to a change in d-electron configuration and therefore changes to structure, colour and magnetism. Here we aim to synthesise and study a wide variety of new spin-crossover systems where cooperativity between centres, induced by careful supramolecular design, will lead to molecule ....Cooperativity in Spin-Crossover Systems: Memory, Magnetism and Microporosity. Spin-crossover centres are a well known form of inorganic electronic switch for which variation of temperature, pressure and irradiation leads to a change in d-electron configuration and therefore changes to structure, colour and magnetism. Here we aim to synthesise and study a wide variety of new spin-crossover systems where cooperativity between centres, induced by careful supramolecular design, will lead to molecules and materials having memory retention, magnetic ordering and/or microporosity. The significance of these aims covers several fundamental questions in the science of electronic systems. We also identify a number of potential nanochemical switching applications for the unique systems proposed.Read moreRead less