Gas phase studies of reactive organic radicals: a novel approach using mass spectrometry. Radical reactions play a crucial role in a range of important chemistries, ranging from the formation of photochemical smog to the accumulation of pathogens in the ageing body. Despite their importance, the reactions of many radicals are poorly understood because of current experimental limitations. In this project we propose to develop two new and broadly applicable techniques for probing radical chemistry ....Gas phase studies of reactive organic radicals: a novel approach using mass spectrometry. Radical reactions play a crucial role in a range of important chemistries, ranging from the formation of photochemical smog to the accumulation of pathogens in the ageing body. Despite their importance, the reactions of many radicals are poorly understood because of current experimental limitations. In this project we propose to develop two new and broadly applicable techniques for probing radical chemistry in the gas phase via novel applications of mass spectrometry. Combined with quantum chemical calculations and state-of-the-art thermodynamic measurements these methods will provide a comprehensive understanding of the reactivity of key organic radicals.Read moreRead less
New Bayesian methodology for understanding complex systems using hidden Markov models and expert opinion, environmental, robotics and genomics applications. This project aims to merge four areas of intense international interest in describing complex systems: hidden Markov models and mixtures, semi-parametric and nonparametric approaches, true combination of expert opinion with data, and new Bayesian computational methods based on perfect sampling and particle sampling. The project will signific ....New Bayesian methodology for understanding complex systems using hidden Markov models and expert opinion, environmental, robotics and genomics applications. This project aims to merge four areas of intense international interest in describing complex systems: hidden Markov models and mixtures, semi-parametric and nonparametric approaches, true combination of expert opinion with data, and new Bayesian computational methods based on perfect sampling and particle sampling. The project will significantly contribute to statistical methodology and its ability to inform about real-world problems. A strong focus on applications to genomics, robotics and environmental modelling will bring immediate research and monetary benefit for industry. Expected outcomes include enhanced cross-disciplinary and international linkages, publications, industry-funded projects and highly trained graduates.Read moreRead less
Physical, Chemical and Radiative Characteristics of Australian Continental Aerosols. Australian desert dust, and the biomass burning aerosol particles produced in the top-end burning season, have the potential to impose an environmental burden not only on Australia, but also on the surrounding region. While most of the world's major aerosol types have been well studied in recent years, these two remain largely unknown. There are good reasons to believe that Australian aerosols are different from ....Physical, Chemical and Radiative Characteristics of Australian Continental Aerosols. Australian desert dust, and the biomass burning aerosol particles produced in the top-end burning season, have the potential to impose an environmental burden not only on Australia, but also on the surrounding region. While most of the world's major aerosol types have been well studied in recent years, these two remain largely unknown. There are good reasons to believe that Australian aerosols are different from many others. We therefore intend to fully characterize their relevant properties, so we may monitor them from space, and evaluate their environmental impacts.Read moreRead less
Enhancing the performance of existing industrial enzymes through the application of new chemical modification technology. Enzymes have many uses in industry, replacing undesirable chemicals which adversely effect human & animal health & the environment. Enzymes offer advantages in effectiveness, biodegradability, specificity and safety. The concern with enzymes, in industrial applications, is that enzyme performance is degraded by a harsh chemical and/or physical environment. The aim of this stu ....Enhancing the performance of existing industrial enzymes through the application of new chemical modification technology. Enzymes have many uses in industry, replacing undesirable chemicals which adversely effect human & animal health & the environment. Enzymes offer advantages in effectiveness, biodegradability, specificity and safety. The concern with enzymes, in industrial applications, is that enzyme performance is degraded by a harsh chemical and/or physical environment. The aim of this study is to improve the performance of industrially significant enzymes by enhancing resistance to chemical & physical degradation or inactivation. This will be achieved by modifying the enzymes using new technology that we have developed. This will improve cost effectiveness of existing industrial enzymes & create opportunities for new uses of enzymes.Read moreRead less
Integrated Carbon Accounting and Information Management Systems. The aim of this project is to integrate environmental science and information technology to enhance carbon accounting management. The project is significant because it will provide for the first time a mechanism by which potential investors in forestry/carbon sequestration programs will be able to acquire online advice on what trees and soil types are most compatible, when and how to plant. This project will provide an interactive ....Integrated Carbon Accounting and Information Management Systems. The aim of this project is to integrate environmental science and information technology to enhance carbon accounting management. The project is significant because it will provide for the first time a mechanism by which potential investors in forestry/carbon sequestration programs will be able to acquire online advice on what trees and soil types are most compatible, when and how to plant. This project will provide an interactive web based program to calculate the environmental and economic value of such an investment, assess current market trends and access to scientists, brokers, current legislation and applicable publications.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0775548
Funder
Australian Research Council
Funding Amount
$180,000.00
Summary
Advanced characterisation facilities for functional nanostructured materials. A critical factor that enhances frontier research is a set of advanced core research experimental facilities for material characterisation purposes. The proposed equipment aims to: (1) provide research facilities for advanced nanomaterial research; (2) improve national competitiveness and growth in a knowledge-based economy; and (3) foster local talented researchers in order to meet the strategic needs of the nation fo ....Advanced characterisation facilities for functional nanostructured materials. A critical factor that enhances frontier research is a set of advanced core research experimental facilities for material characterisation purposes. The proposed equipment aims to: (1) provide research facilities for advanced nanomaterial research; (2) improve national competitiveness and growth in a knowledge-based economy; and (3) foster local talented researchers in order to meet the strategic needs of the nation for a sustainable environment. These activities will revitalise Australia's leading role in creating new technologies with particular relevance to using advanced nanostructures for the production of clean air and water, and sustainable energy alternatives.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE100100229
Funder
Australian Research Council
Funding Amount
$160,000.00
Summary
Time-of-flight mass spectrometer for analysis of complex mixtures in oils, ancient rocks, recent sediments, natural products and atmospheric aerosols. Research benefits will be:1. More effective remediation of petroleum spills through better understanding of degradation pathways, and ecotoxicological impact of spills.
2. Better understanding of the role of urban aerosols in human health impacts and climate change.
3. More effective development of finite petroleum resources by better understand ....Time-of-flight mass spectrometer for analysis of complex mixtures in oils, ancient rocks, recent sediments, natural products and atmospheric aerosols. Research benefits will be:1. More effective remediation of petroleum spills through better understanding of degradation pathways, and ecotoxicological impact of spills.
2. Better understanding of the role of urban aerosols in human health impacts and climate change.
3. More effective development of finite petroleum resources by better understanding of processes altering crude oil in the sub-surface.
4. Identification of natural products from algae, cyanobacteria, plants and mushrooms as new sources of pharmaceutical agents. 5. Improved knowledge of early evolution of life on Earth, helping maintain Australian scientists as world leaders in this field. 6. Greater understanding of the source and migration of petroleum in frontier areas.Read moreRead less
Olfactory Characterisation of Odours for Optimising Impact Assessment. The repeated release of obnoxious odours from intensive livestock, waste management and wastewater treatment facilities can constitute a major air quality problem for a local population. Odour management has traditionally been maintained by the use of buffer distances that have significantly decreased with urban encroachment. Odour assessment is conventionally measured in terms of odour concentration; however this standardise ....Olfactory Characterisation of Odours for Optimising Impact Assessment. The repeated release of obnoxious odours from intensive livestock, waste management and wastewater treatment facilities can constitute a major air quality problem for a local population. Odour management has traditionally been maintained by the use of buffer distances that have significantly decreased with urban encroachment. Odour assessment is conventionally measured in terms of odour concentration; however this standardised method does not take into account odour quality characters or their intensity. The project will characterise by sensory means the odour nuisance types and intensity of different odorous emissions to better define and understand the relationship between process operations and olfactory annoyance.Read moreRead less
Anomalous isotope effects in atmospheric ozone and carbon dioxide. The anomalous isotopic composition of atmospheric ozone, which has been a puzzle for over twenty years, will be investigated by laboratory and atmospheric measurements. An understanding of the source of this anomaly and its effect on the isotopic composition of other trace atmospheric gases, especially CO2, would provide unique opportunities for constraining the tropospheric and stratospheric ozone budgets and determining the his ....Anomalous isotope effects in atmospheric ozone and carbon dioxide. The anomalous isotopic composition of atmospheric ozone, which has been a puzzle for over twenty years, will be investigated by laboratory and atmospheric measurements. An understanding of the source of this anomaly and its effect on the isotopic composition of other trace atmospheric gases, especially CO2, would provide unique opportunities for constraining the tropospheric and stratospheric ozone budgets and determining the history of a particular air mass. The method of detection will be high resolution FTIR spectroscopy which, in contrast to traditional mass-spectrometric methods, provides information about the position of the heavy atom in an enriched ozone molecule and requires no sample preparation.Read moreRead less
The best astronomical site on earth? A modern optical/infrared telescope is only as good as its site. We have previously shown that the infrared skies above the South Pole are up to 100 times darker than skies elsewhere, leading to enormous potential gains in sensitivity. We now seek to extend these measurements to Antarctic sites that are even higher, drier and colder than the South Pole. These are expected to be the best observing sites on Earth, paving the way for the deployment of telescop ....The best astronomical site on earth? A modern optical/infrared telescope is only as good as its site. We have previously shown that the infrared skies above the South Pole are up to 100 times darker than skies elsewhere, leading to enormous potential gains in sensitivity. We now seek to extend these measurements to Antarctic sites that are even higher, drier and colder than the South Pole. These are expected to be the best observing sites on Earth, paving the way for the deployment of telescopes of unprecedented sensitivity able to explore the origins of planets, stars and galaxies.
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