Three-dimensional structures, substrate specificities and catalytic mechanisms of polysaccharide synthases. Plant wall polysaccharides are extensively used for food and fibre, and are important dietary components in human nutrition. A precise knowledge of mechanisms used by plants to synthesize these polysaccharides is unavailable, but would reveal potential routes to manipulate their biosynthesis in important crop species. For example, the levels or structures of polysaccharides might be modif ....Three-dimensional structures, substrate specificities and catalytic mechanisms of polysaccharide synthases. Plant wall polysaccharides are extensively used for food and fibre, and are important dietary components in human nutrition. A precise knowledge of mechanisms used by plants to synthesize these polysaccharides is unavailable, but would reveal potential routes to manipulate their biosynthesis in important crop species. For example, the levels or structures of polysaccharides might be modified to improve their efficacy as anti-cancer agents in human diets, to enhance digestibility of animal stock feeds, or to synthesise pharmologically valuable compounds. Thus, economic, social and environmental benefits will flow to both producers and consumers. Read moreRead less
Nickel iron sulphide mineralogy: the link between mineral transformations and microstructure and magnetic properties. This project is about measuring the rate at which minerals transform or react and how metal diffusion controls these reactions. Metal diffusion in sulphides is much more rapid that in silicates and is still very significant at low temperatures (< 300 C). In this project, we are trying to measure the rate at which the principal ore of nickel, pentlandite, transforms to violarite ....Nickel iron sulphide mineralogy: the link between mineral transformations and microstructure and magnetic properties. This project is about measuring the rate at which minerals transform or react and how metal diffusion controls these reactions. Metal diffusion in sulphides is much more rapid that in silicates and is still very significant at low temperatures (< 300 C). In this project, we are trying to measure the rate at which the principal ore of nickel, pentlandite, transforms to violarite, another important nickel rich sulphide that forms from it in the upper parts of ore bodies. The arrangement of the metal atoms in these minerals is sensitive to temperature, so it may be used as a geothermometer.Read moreRead less