Early Career Industry Fellowships - Grant ID: IE230100365
Funder
Australian Research Council
Funding Amount
$462,237.00
Summary
Solar-driven catalytic production of high-value product from waste glycerol. Sustainable bio-refining requires an efficient and economical way of utilising the surplus amount of glycerol generated as a by-product in biodiesel industries. This project aims to construct an industry-scale solar-driven catalytic system to generate high-value-added chemicals and green hydrogen fuel from biomass wastes simultaneously. The structure-reactivity relationship of working catalysts will be established to fi ....Solar-driven catalytic production of high-value product from waste glycerol. Sustainable bio-refining requires an efficient and economical way of utilising the surplus amount of glycerol generated as a by-product in biodiesel industries. This project aims to construct an industry-scale solar-driven catalytic system to generate high-value-added chemicals and green hydrogen fuel from biomass wastes simultaneously. The structure-reactivity relationship of working catalysts will be established to fit the up-scale applications. The gained cutting-edge knowledge and technology will significantly contribute to biomass waste utilisation and sustainable fabrication, further bringing significant economic and social benefits by creating a new competitive business for Australian chemical and fuel areas. Read moreRead less
Biomass-derived Carbon Dots Enable Flexible, On-Demand Hydrogen Delivery . Methanol is a promising liquid hydrogen carrier for long distance H2 transportation and exportation, because it is rich in hydrogen content, cheap, recyclable between methanol-formaldehyde and easier to manufacture from renewable resources including biomass waste. The critical bottleneck in adopting methanol as the carrier is the demanding dehydrogenation process. The project aims to create a new class of photocatalyst ba ....Biomass-derived Carbon Dots Enable Flexible, On-Demand Hydrogen Delivery . Methanol is a promising liquid hydrogen carrier for long distance H2 transportation and exportation, because it is rich in hydrogen content, cheap, recyclable between methanol-formaldehyde and easier to manufacture from renewable resources including biomass waste. The critical bottleneck in adopting methanol as the carrier is the demanding dehydrogenation process. The project aims to create a new class of photocatalyst based on biomass-derived carbon nanodots grown on transition metal (di)chalcogenide nanosheets that can effectively enable a light-controlled methanol H2 release of desired quantity. The key outcomes will be a new class of photocatalysts and flexible, on-demand hydrogen delivery technology for liquid hydrogen carriers.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE230100789
Funder
Australian Research Council
Funding Amount
$397,613.00
Summary
Photo-thermal ammonia decomposition . This project aims to develop of novel catalysts targeted to utilise light and heat for the photo-thermal decomposition of ammonia to produce hydrogen and generate new understanding on the role of light in thermal catalytic reactions. The emergence of the hydrogen economy has resulted in the urgent need for safe and efficient hydrogen transport and storage vectors. Ammonia, a hydrogen carrier, is being increasingly considered as a potential key to facilitate ....Photo-thermal ammonia decomposition . This project aims to develop of novel catalysts targeted to utilise light and heat for the photo-thermal decomposition of ammonia to produce hydrogen and generate new understanding on the role of light in thermal catalytic reactions. The emergence of the hydrogen economy has resulted in the urgent need for safe and efficient hydrogen transport and storage vectors. Ammonia, a hydrogen carrier, is being increasingly considered as a potential key to facilitate the hydrogen economy due to its relative ease of storage. The development of catalysts tailored toward capturing light for ammonia decomposition will enable a new potential pathway for the hydrogen economy, with ammonia as a hydrogen vector. Read moreRead less
A New Spin on Liquid Hydrogen: Controlled Cold Energy. While hydrogen is set to play a leading role in global decarbonisation, significant challenges remain regarding methods for its reliable storage and transportation. Hydrogen liquefaction has emerged as a promising approach in this regard due to its high energy density and hydrogen purity, but is currently prohibitively expensive. In this project we will exploit the peculiar spin physics of hydrogen to alleviate liquefactions costs through t ....A New Spin on Liquid Hydrogen: Controlled Cold Energy. While hydrogen is set to play a leading role in global decarbonisation, significant challenges remain regarding methods for its reliable storage and transportation. Hydrogen liquefaction has emerged as a promising approach in this regard due to its high energy density and hydrogen purity, but is currently prohibitively expensive. In this project we will exploit the peculiar spin physics of hydrogen to alleviate liquefactions costs through the provision of controllable refrigeration (so-called 'cold energy') following regasification. In particular we will measure, optimise and exploit the highly endothermic catalysed conversion of para- to ortho- hydrogen, which can provide up to 525 kJ/kg of cooling at convenient temperatures. Read moreRead less
Integrated nonmetal-metal single-atom catalysis for selective synthesis. Single atom catalysts can achieve the maximum efficiency of active sites for a reaction. This project will develop integrated nonmetal and metal single atom-based catalysts for selective oxidation towards clean production and organic waste conversion to value-added polymers for carbon recycle. The project will result in new functional materials and green catalytic processes for chemical synthesis and waste reduction, and ad ....Integrated nonmetal-metal single-atom catalysis for selective synthesis. Single atom catalysts can achieve the maximum efficiency of active sites for a reaction. This project will develop integrated nonmetal and metal single atom-based catalysts for selective oxidation towards clean production and organic waste conversion to value-added polymers for carbon recycle. The project will result in new functional materials and green catalytic processes for chemical synthesis and waste reduction, and advance fundamental understanding of molecular structure of materials for catalyst design and process engineering for industrial applications. The outcomes will promote the development of chemical industry, waste recycle and green environment in Australia, making significant benefits to economics and society.Read moreRead less
Nano-engineering of hierarchical catalysts for renewable chemicals. Producing high-value chemicals based on renewable alternatives -biomass resources is vital for the climate and a sustainable economy. This project will develop a unique nano-engineering approach to design hierarchical catalysts for the selective conversion of biomass into tailor-made products. Advanced in situ spectroscopic techniques will be employed to establish the structure-reactivity relationship of working catalysts and th ....Nano-engineering of hierarchical catalysts for renewable chemicals. Producing high-value chemicals based on renewable alternatives -biomass resources is vital for the climate and a sustainable economy. This project will develop a unique nano-engineering approach to design hierarchical catalysts for the selective conversion of biomass into tailor-made products. Advanced in situ spectroscopic techniques will be employed to establish the structure-reactivity relationship of working catalysts and thereby manipulate the key factors governing the activity/selectivity. Such cutting-edge knowledge gained is crucial for optimising process efficiency and resource utilisation, which is essential for the success of the biorefining industry and a more environmentally-friendly chemical economy in Australia.Read moreRead less
Three-dimensional solar-energy-driven hydrogen generation from ammonia. This project aims to address the challenges of hydrogen generation, transportation and storage by conceptualising a novel three-dimensional, solar-driven system for ammonia splitting on ultralight catalyst materials. The project expects to generate new knowledge in the area of advanced materials enabled hydrogen technologies through interdisciplinary approaches involving materials science, novel catalysis, and nanotechnology ....Three-dimensional solar-energy-driven hydrogen generation from ammonia. This project aims to address the challenges of hydrogen generation, transportation and storage by conceptualising a novel three-dimensional, solar-driven system for ammonia splitting on ultralight catalyst materials. The project expects to generate new knowledge in the area of advanced materials enabled hydrogen technologies through interdisciplinary approaches involving materials science, novel catalysis, and nanotechnology. Expected outcomes include new catalyst materials, design strategies, and advanced ammonia splitting technologies. This should provide significant benefits, such as newly created knowledge, technological innovation, research training, contributing to hydrogen economy and net zero for a greener environment.Read moreRead less
CO2-coupled photothermal catalysis on superlattice structures. This project aims to develop a structure-tailored platform of superlattice materials for photothermal catalytic conversion of natural gases to valuable fuels and chemicals. Innovations lie in engineered atomic and bulk scale nanocrystals for high-efficiency sunlight harvesting to drive CO2-coupled catalysis of C-H bond activation. Advanced characterisations and multiscale computations will enable mechanistic insights into the synergy ....CO2-coupled photothermal catalysis on superlattice structures. This project aims to develop a structure-tailored platform of superlattice materials for photothermal catalytic conversion of natural gases to valuable fuels and chemicals. Innovations lie in engineered atomic and bulk scale nanocrystals for high-efficiency sunlight harvesting to drive CO2-coupled catalysis of C-H bond activation. Advanced characterisations and multiscale computations will enable mechanistic insights into the synergy of photo and thermal catalysis in hydrocarbon conversions. The projects will result in next-generation intelligent materials and clean technologies for solar fuels production and CO2 recycling. Outcomes will benefit Australia’s long-term energy security and sustainability toward a carbon-neutral society. Read moreRead less