Molecular signatures of complex photodissociation reactions. All energy on earth comes from the sun, either directly (e.g photosynthesis) or indirectly (e.g fossil fuels). Photochemistry is the study of how this light is absorbed and what happens to a molecule afterwards. Despite significant experimental and theoretical advances in the past decade (some in our lab), scientists still cannot predict the outcomes of most photochemical reactions. In this project we will determine the reactivity o ....Molecular signatures of complex photodissociation reactions. All energy on earth comes from the sun, either directly (e.g photosynthesis) or indirectly (e.g fossil fuels). Photochemistry is the study of how this light is absorbed and what happens to a molecule afterwards. Despite significant experimental and theoretical advances in the past decade (some in our lab), scientists still cannot predict the outcomes of most photochemical reactions. In this project we will determine the reactivity of several small, fundamental organic molecules. Not only are these molecules pollutants around our cities, but discovery of how they react in the presence of light will allow us to understand and predict the photochemistry of a much wider range of organic species.Read moreRead less
Process Chemistry for Distributed Manufacture of Nitric Acid. This project will benefit Australia by enabling a new approach to the manufacture of explosives for the country's mining industry which will provide the entire explosives supply chain with greater safety and security. Development of this technology will enhance Orica's competitive position as the largest manufacturer of mining explosives in the world and will produce wealth for the country through the continued success of this ASX Top ....Process Chemistry for Distributed Manufacture of Nitric Acid. This project will benefit Australia by enabling a new approach to the manufacture of explosives for the country's mining industry which will provide the entire explosives supply chain with greater safety and security. Development of this technology will enhance Orica's competitive position as the largest manufacturer of mining explosives in the world and will produce wealth for the country through the continued success of this ASX Top 50 company and the export of the technology.Read moreRead less
Design of reactive foils for joining amorphous alloys. Amorphous alloys or metallic glasses are special materials that retain the random structure of a liquid but in a solid form. They can show special properties of very high strength, toughness and corrosion resistance. The enormous difficulty in joining amorphous alloys to make larger assemblies is greatly curbing their uptake in technology. In this research, state of the art experimental and computational tools will be used to investigate the ....Design of reactive foils for joining amorphous alloys. Amorphous alloys or metallic glasses are special materials that retain the random structure of a liquid but in a solid form. They can show special properties of very high strength, toughness and corrosion resistance. The enormous difficulty in joining amorphous alloys to make larger assemblies is greatly curbing their uptake in technology. In this research, state of the art experimental and computational tools will be used to investigate the extremely fast high temperature reactions occurring in reactive foils of layered metals which, when inserted at the proposed join and ignited, quickly produce a bond. The research will lay the foundation for a robust and reliable means for joining amorphous alloys by means of reactive foils. Read moreRead less
Thermal characterisation of iron ores and coals for HIsmelt operation. Substantial developments in direct reduction ironmaking (DRI) have been recently conducted providing sustainable way for metallurgical operations. The largest advantage of DRI is that it does not require cokemaking and sintering, two processes which are consistently causing environmental concerns. This project aims to thermally investigate coals and iron ores for optimising direct smelting, and to provide insight into effect ....Thermal characterisation of iron ores and coals for HIsmelt operation. Substantial developments in direct reduction ironmaking (DRI) have been recently conducted providing sustainable way for metallurgical operations. The largest advantage of DRI is that it does not require cokemaking and sintering, two processes which are consistently causing environmental concerns. This project aims to thermally investigate coals and iron ores for optimising direct smelting, and to provide insight into effect of the properties of ores and coals on the process. Structural changes using hot stage optical microscopy will be carefully clarified. Finally, a predictive model for DRI and energy requirements for direct smelting based on the experimental outcomes will be developed.Read moreRead less
Anomalous isotope effects in atmospheric ozone and carbon dioxide. The anomalous isotopic composition of atmospheric ozone, which has been a puzzle for over twenty years, will be investigated by laboratory and atmospheric measurements. An understanding of the source of this anomaly and its effect on the isotopic composition of other trace atmospheric gases, especially CO2, would provide unique opportunities for constraining the tropospheric and stratospheric ozone budgets and determining the his ....Anomalous isotope effects in atmospheric ozone and carbon dioxide. The anomalous isotopic composition of atmospheric ozone, which has been a puzzle for over twenty years, will be investigated by laboratory and atmospheric measurements. An understanding of the source of this anomaly and its effect on the isotopic composition of other trace atmospheric gases, especially CO2, would provide unique opportunities for constraining the tropospheric and stratospheric ozone budgets and determining the history of a particular air mass. The method of detection will be high resolution FTIR spectroscopy which, in contrast to traditional mass-spectrometric methods, provides information about the position of the heavy atom in an enriched ozone molecule and requires no sample preparation.Read moreRead less
Helium droplets: a nanoscale laboratory for studying intermolecular bonding and chemical reactivity. This type of research requires a rather complicated apparatus capable of creating a stream of helium droplets, embedding molecules and interrogating their properties using laser spectroscopy. The apparatus built in Sydney is the only one capable of this in Australia and using this new apparatus we will create many novel, bizarre and intriguing aggregates of molecules and atoms. The project involv ....Helium droplets: a nanoscale laboratory for studying intermolecular bonding and chemical reactivity. This type of research requires a rather complicated apparatus capable of creating a stream of helium droplets, embedding molecules and interrogating their properties using laser spectroscopy. The apparatus built in Sydney is the only one capable of this in Australia and using this new apparatus we will create many novel, bizarre and intriguing aggregates of molecules and atoms. The project involves cutting-edge scientific methods and will shift the boundaries of can-do science in the laser laboratory at the University of Sydney and in Australia in general.Read moreRead less
Predicting Environmental Effects on Structure and Reactivity. This project tackles one of the most important and fundamental problems in theoretical chemistry: solvent effects on chemical reactions. The new methods and computer programs generated will be freely available to the Australian (and international) scientific communitities and will further enhance Australia's strong reputation in Theoretical Chemistry.
The applications chosen will allow new technologies in biosensing and strategies in ....Predicting Environmental Effects on Structure and Reactivity. This project tackles one of the most important and fundamental problems in theoretical chemistry: solvent effects on chemical reactions. The new methods and computer programs generated will be freely available to the Australian (and international) scientific communitities and will further enhance Australia's strong reputation in Theoretical Chemistry.
The applications chosen will allow new technologies in biosensing and strategies in computational drug design to be investigated. This will benefit the Australian biotechnology and pharmaceutical industries and may substantially aid in understanding the mechanism and treatment of disease. Read moreRead less