THEORETICAL AND EXPERIMENTAL STUDIES OF BLOCK COPOLYMER MELTS AS NANO-MATERIALS. We shall theoretically study and predict the possible morphologies of a wide range of block copolymer architectures with a combination of simulations and accurate numerical theories. These block copolymer melts are of great technological importance because they can self-assemble into morphological patterns which are periodic on a nano-scale. Hence they are now being intensively investigated for uses in applications ....THEORETICAL AND EXPERIMENTAL STUDIES OF BLOCK COPOLYMER MELTS AS NANO-MATERIALS. We shall theoretically study and predict the possible morphologies of a wide range of block copolymer architectures with a combination of simulations and accurate numerical theories. These block copolymer melts are of great technological importance because they can self-assemble into morphological patterns which are periodic on a nano-scale. Hence they are now being intensively investigated for uses in applications as diverse as lithographic templates for electronic and optical devices, nano-porous membranes and photonic band gap materials. We shall verify our theoretical predictions by carrying out experiments on the various molecular architectures that we have studied theoretically.Read moreRead less
Development of inorganic-conducting polymer composites and ionic liquid-based electrolytes for rechargeable lithium batteries. The project will lead to development of safe lithium batteries for electric vehicles and hybrid electric vehicles to contribute to the national priority goal of reducing and capturing emissions in transport to improve our environment. Small, flexible batteries for new implantable medical devices will also be developed to treat millions of people suffering from different ....Development of inorganic-conducting polymer composites and ionic liquid-based electrolytes for rechargeable lithium batteries. The project will lead to development of safe lithium batteries for electric vehicles and hybrid electric vehicles to contribute to the national priority goal of reducing and capturing emissions in transport to improve our environment. Small, flexible batteries for new implantable medical devices will also be developed to treat millions of people suffering from different diseases. The development of new scientific knowledge related to this project will place Australia at the forefront of an emerging domain of research. The project will take the incentive in establishing a leading national position in development of new energy storage technology.
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Advanced Polymer Electrolytes for Device Applications. The future of an energy sustainable society relies upon the development of a range of technologies that will involve devices such as lithium batteries, supercapacitors, sensors and fuel cells. One of the key challenges is the discovery and development of high performance materials which overcome performance limiting issues such as conductivity, durability and stability in current devices. Our recent discovery of novel successful approaches ....Advanced Polymer Electrolytes for Device Applications. The future of an energy sustainable society relies upon the development of a range of technologies that will involve devices such as lithium batteries, supercapacitors, sensors and fuel cells. One of the key challenges is the discovery and development of high performance materials which overcome performance limiting issues such as conductivity, durability and stability in current devices. Our recent discovery of novel successful approaches to the design of improved electrolyte materials will be systematically exploited to develop materials that will provide the significant advance in device performance that is required.Read moreRead less
Structure-Property Relationships of Polymers with Controlled Architecture. Mechanical properties of a polymer (e.g., how elastic it is and how it dissipates energy when compressed) govern how well it performs as an adhesive, or its behaviour when melted and shaped into a consumer item. This project aims to relate molecular architecture to mechanical properties, using new techniques which permit the creation of polymers wherein each architectural characteristic is separately controlled. This has ....Structure-Property Relationships of Polymers with Controlled Architecture. Mechanical properties of a polymer (e.g., how elastic it is and how it dissipates energy when compressed) govern how well it performs as an adhesive, or its behaviour when melted and shaped into a consumer item. This project aims to relate molecular architecture to mechanical properties, using new techniques which permit the creation of polymers wherein each architectural characteristic is separately controlled. This has the potential to develop fundamental understanding for structure-property relations for the type of branched polymers that are in common use in industry and for which adequate models do not currently exist.Read moreRead less
Advanced Ionic Materials for Organic Photovoltaics. Australia will greatly benefit from the development of improved solar energy technology, as a means of addressing the issue of climate change as a result of continued fossil fuel use. Solar power is also advantageous as it also allows electricity to be generated locally where it is needed, which is particularly important for the many remote areas of Australia. The climate in Australia is ideally suited for the electricity production through pho ....Advanced Ionic Materials for Organic Photovoltaics. Australia will greatly benefit from the development of improved solar energy technology, as a means of addressing the issue of climate change as a result of continued fossil fuel use. Solar power is also advantageous as it also allows electricity to be generated locally where it is needed, which is particularly important for the many remote areas of Australia. The climate in Australia is ideally suited for the electricity production through photovoltaics, and this project will focus on improving the performance of these devices to enable their widespread use. Read moreRead less
Nanoporous Epoxy Thermosets via Microphase Separation of Block Copolymers. This project has many expected outcomes and benefits to Australia: (1) Development of the first technology to produce nanoporous epoxy thermosets (i.e. epoxy nanofoams) that may have many applications in microelectronics, optical waveguides and biological separations; (2) Providing impetus for an advanced materials synthesis and manufacturing industry for Australia and contributing to the Frontier Technologies National Re ....Nanoporous Epoxy Thermosets via Microphase Separation of Block Copolymers. This project has many expected outcomes and benefits to Australia: (1) Development of the first technology to produce nanoporous epoxy thermosets (i.e. epoxy nanofoams) that may have many applications in microelectronics, optical waveguides and biological separations; (2) Providing impetus for an advanced materials synthesis and manufacturing industry for Australia and contributing to the Frontier Technologies National Research Priority-Advanced Materials Priority Goals; (3) The development of new niche markets with these new materials and the new technologies, which is an excellent vehicle for Australia to move to a high-value added industrial portfolio that maximises return and promotes job growth.Read moreRead less
Photoactive Semiconducting Biopolymers. The basic aims of this project are to elucidate, manipulate, and utilise the unique chemical and physical properties of a class of biopolymers called the melanins. These materials are the only known solid state semiconducting biopolymers, and are non-toxic, biocompatible, and biodegradable. Their use as active components in biomimetic soft electonic, optoelectronic or photovoltaic devices, has not hitherto been demonstrated. It is anticipated that the k ....Photoactive Semiconducting Biopolymers. The basic aims of this project are to elucidate, manipulate, and utilise the unique chemical and physical properties of a class of biopolymers called the melanins. These materials are the only known solid state semiconducting biopolymers, and are non-toxic, biocompatible, and biodegradable. Their use as active components in biomimetic soft electonic, optoelectronic or photovoltaic devices, has not hitherto been demonstrated. It is anticipated that the key outcomes from the project will be a demonstration of biopolymer-based photoelectrochemical and solid-state p-i-n solar cells, and an improved understanding of the physics and chemistry of these important biological macromolecules.Read moreRead less
New Transparent Polymer Nanocomposite Coatings Using Multireactive Inorganic Cages. New polymeric nanocomposite coatings are proposed with enhanced abrasion resistance, toughness and optical functionality, suitable for the coating of optical plastic substrates. These composites contain inorganic cages, dispersed and chemically-coupled within the crosslinked organic matrix. In addition to good mechanical behaviour, high value properties such as colorisation on exposure to light and resistance to ....New Transparent Polymer Nanocomposite Coatings Using Multireactive Inorganic Cages. New polymeric nanocomposite coatings are proposed with enhanced abrasion resistance, toughness and optical functionality, suitable for the coating of optical plastic substrates. These composites contain inorganic cages, dispersed and chemically-coupled within the crosslinked organic matrix. In addition to good mechanical behaviour, high value properties such as colorisation on exposure to light and resistance to damage from high energy lasers will be achieved by attachment to the cages of chemical units with optical activity. These cages are of nanometre size and an important aspect of the project involves probing the resultant structure at the molecular level, using advanced characterisation techniques.Read moreRead less
Switchable interfaces. The discovery project will challenge some of the most demanding issues regarding adhesion and molecular separation: - Surfaces that can release/prevent bio-film formation can provide novel solutions for corrosion-protection, implants, anti-fouling in medical devices as well as in industrial piping and reactors. - Materials for separation on the molecular level, which can bring new possibilities for fast and selective processes to the pharmaceutical industry. The novel comb ....Switchable interfaces. The discovery project will challenge some of the most demanding issues regarding adhesion and molecular separation: - Surfaces that can release/prevent bio-film formation can provide novel solutions for corrosion-protection, implants, anti-fouling in medical devices as well as in industrial piping and reactors. - Materials for separation on the molecular level, which can bring new possibilities for fast and selective processes to the pharmaceutical industry. The novel combination of the two materials research fields - plasma-polymerisation and electroactive materials- will lead to an international capability at the forefront of separation and adhesion research.Read moreRead less
The Synthesis and Evaluation of White Nano Particles that Reinforce the Mechanical Properties of Elastomers. This project will introduce admicellar polymerization technique to produce a bound polymer layer on the surface of fillers used for reinforcement of elastomers. The novel approach in this project will provide advanced material with excellent mechanical properties. Such composites can be used in various high performance elastomer applications such as rubber for tyres in automotive vehicles ....The Synthesis and Evaluation of White Nano Particles that Reinforce the Mechanical Properties of Elastomers. This project will introduce admicellar polymerization technique to produce a bound polymer layer on the surface of fillers used for reinforcement of elastomers. The novel approach in this project will provide advanced material with excellent mechanical properties. Such composites can be used in various high performance elastomer applications such as rubber for tyres in automotive vehicles. Products based on this new technology will produce significantly improved properties. The development of this new technology will not only advance polymer science, it will also provide great opportunities for new elastomer applications in a number of industries.Read moreRead less