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Phosphonium ionic liquids for advanced lithium energy storage systems. This project will develop, along with a leading manufacturer in the world, high performance electrolytes for lithium batteries. The technologies and expertise generated will be of importance to many niche industries in Australia in their shift towards lower carbon operations.
Bioinspired tuneable catalysts for renewable ammonia production. The project will design a new solar-powered system for electrosynthesis of ammonia to replace the current energy intensive, non-sustainable process that generates 1.5% of global CO2 emissions. An innovative new system will be developed by combining cutting edge electrochemical, spectroscopic and theoretical methods. Expected key outcomes include novel concepts in the design of advanced materials, and an efficient process for the gr ....Bioinspired tuneable catalysts for renewable ammonia production. The project will design a new solar-powered system for electrosynthesis of ammonia to replace the current energy intensive, non-sustainable process that generates 1.5% of global CO2 emissions. An innovative new system will be developed by combining cutting edge electrochemical, spectroscopic and theoretical methods. Expected key outcomes include novel concepts in the design of advanced materials, and an efficient process for the green ammonia synthesis. Given the strategic importance of ammonia as a future energy carrier for the export of Australian renewables and as a major source of fertilisers, this project should provide significant national economic and ecological benefits and is expected to have a broad reaching global impact.Read moreRead less
Efficient ionic liquid-based reduction of nitrogen to ammonia. This project aims to develop a hybrid ionic liquid-nanostructured electrode platform to electrochemically convert nitrogen gas to ammonia. Ammonia production, mostly for fertilisers, consumes more than 1% of the global energy supply and contributes 1.6 % of global carbon dioxide emissions. A process that could convert nitrogen to ammonia using renewable energy would be an important alternative approach. This project will develop a pl ....Efficient ionic liquid-based reduction of nitrogen to ammonia. This project aims to develop a hybrid ionic liquid-nanostructured electrode platform to electrochemically convert nitrogen gas to ammonia. Ammonia production, mostly for fertilisers, consumes more than 1% of the global energy supply and contributes 1.6 % of global carbon dioxide emissions. A process that could convert nitrogen to ammonia using renewable energy would be an important alternative approach. This project will develop a platform for electrochemical conversion of nitrogen gas to ammonia and optimise it for use with surplus renewable energy supplies. The project is expected to contribute to mitigation of greenhouse emissions and create a technology for distributed production of ammonia and ammonium fertilisers.Read moreRead less
Redox-gel integrated electrode for ThermoCells. This project aims to synthesise flexible redox gel-electrolyte interpenetrated electrodes for an eco-friendly prototype wearable thermo-electrochemical cell that can power body-worn low-power wearable electronics. Wearable devices in the future are expected to include products related to personal wellness and healthcare and medical technology. These devices require a sustainable power source (without having to change a battery) for real time monito ....Redox-gel integrated electrode for ThermoCells. This project aims to synthesise flexible redox gel-electrolyte interpenetrated electrodes for an eco-friendly prototype wearable thermo-electrochemical cell that can power body-worn low-power wearable electronics. Wearable devices in the future are expected to include products related to personal wellness and healthcare and medical technology. These devices require a sustainable power source (without having to change a battery) for real time monitoring/communication. Turning body-heat into electricity by wearable thermo-electrochemical cells may provide a solution. The project could also contribute to the mitigation of greenhouse emissions.Read moreRead less
Faster interfacial electron transfer: the effect of molecule shape and size. This project aims to explore the effect of shape and size of pi-conjugated molecules on interfacial electron transfer reactions, which are fundamentally important in all applications of photo-electrochemical conversion and storage of energy. By making two series of pi-conjugated molecules and determining electron transfer rates using a combination of transient spectroscopies and computational chemistry, the project expe ....Faster interfacial electron transfer: the effect of molecule shape and size. This project aims to explore the effect of shape and size of pi-conjugated molecules on interfacial electron transfer reactions, which are fundamentally important in all applications of photo-electrochemical conversion and storage of energy. By making two series of pi-conjugated molecules and determining electron transfer rates using a combination of transient spectroscopies and computational chemistry, the project expects to generate new design principles for molecules with the potential to significantly improve the efficiencies of solar energy conversion and photo-catalytic processes. The new materials and findings will be exploited in a novel redox-mediated water splitting device as a practical outcome with potential end user benefits.Read moreRead less
Sustainable nitrogen chemistry. The goal of this project is to develop sustainable methods to produce nitrates from air and water, using renewable electricity. This new electrochemical technology will be based on the design of new electrolytes and catalysts supported by advanced theoretical concepts to provide high rate of production and selectivity. This is expected to generate new fundamental knowledge in materials and catalysis science. As traditional production of nitrates for industry and a ....Sustainable nitrogen chemistry. The goal of this project is to develop sustainable methods to produce nitrates from air and water, using renewable electricity. This new electrochemical technology will be based on the design of new electrolytes and catalysts supported by advanced theoretical concepts to provide high rate of production and selectivity. This is expected to generate new fundamental knowledge in materials and catalysis science. As traditional production of nitrates for industry and agriculture generates significant greenhouse gas emissions, the core anticipated outcome of this project is a new, sustainable era of nitrogen chemistry. This is also expected to benefit farmers by providing a process for the generation of sustainable fertilisers on a local basis.Read moreRead less
Mesoporous conducting carbon-based materials for energy. This project aims to synthesise highly ordered mesoporous conducting polymers and graphitic carbons with a high conductivity, different pore structures, tuneable pore diameters, and functionalised with transition metal oxide nanoparticles. It will make a highly efficient, low cost and stable energy storage device using functionalised mesoporous conducting polymeric and graphitic electrodes that combine pseudo capacitance and electrical dou ....Mesoporous conducting carbon-based materials for energy. This project aims to synthesise highly ordered mesoporous conducting polymers and graphitic carbons with a high conductivity, different pore structures, tuneable pore diameters, and functionalised with transition metal oxide nanoparticles. It will make a highly efficient, low cost and stable energy storage device using functionalised mesoporous conducting polymeric and graphitic electrodes that combine pseudo capacitance and electrical double layer capacitance, high power and energy density and a long cycle life. This electrode system for supercapacitors is expected to address clean energy generation and environmental problems and create opportunities for Australian industries.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE200101076
Funder
Australian Research Council
Funding Amount
$426,985.00
Summary
Resolving nanoscale structure-activity for rational electrocatalyst design. This project aims to investigate the structural and functional properties of electrocatalysts at the nanoscale. The project expects to develop state-of-the-art electrochemical imaging technology that can examine the active sites of electrodes during operation. Understanding electrode performance on this scale is expected to enhance our capability to rationally design cheaper and more-efficient electrocatalysts, notably ....Resolving nanoscale structure-activity for rational electrocatalyst design. This project aims to investigate the structural and functional properties of electrocatalysts at the nanoscale. The project expects to develop state-of-the-art electrochemical imaging technology that can examine the active sites of electrodes during operation. Understanding electrode performance on this scale is expected to enhance our capability to rationally design cheaper and more-efficient electrocatalysts, notably for electrochemical carbon dioxide reduction. This should provide significant socio-economic and environmental benefits, through the development of next-generation energy storage and conversion materials that can be utilized by households and businesses to store renewable energy in the form of carbon-neutral fuels.Read moreRead less
Design of novel nanoporous semiconductor materials for clean environment and energy. This project will develop a low cost nanoporous semiconductor device for the capture and conversion of CO2 into fuels by using water and sunlight. This novel approach will deliver a low cost technology that offers clean energy and will help to mitigate global warming.
Tuning the electrolytes for high efficiency solar splitting of water. This project will develop a new technology that uses ionic liquids and sunlight to split water into hydrogen and oxygen to be used as a clean fuel. Australia has abundant sunlight, is very close to the growing energy markets of the Asia-Pacific region, and is ideally placed to benefit from this new technology.