Discovery Early Career Researcher Award - Grant ID: DE190101618
Funder
Australian Research Council
Funding Amount
$389,000.00
Summary
Tailoring multifunctional single site catalysts for carbon dioxide conversion. This project aims to develop multifunctional single site catalysts and collaborative surface sites to complete multi-step reactions using carbon dioxide (CO2) hydrogenation to higher alcohols with enhanced selectivity for large-chain alcohols. CO2 is an abundant and renewable carbon source for use as a feedstock, and closing the carbon cycle in an energy efficient manner has the potential for significant environmental ....Tailoring multifunctional single site catalysts for carbon dioxide conversion. This project aims to develop multifunctional single site catalysts and collaborative surface sites to complete multi-step reactions using carbon dioxide (CO2) hydrogenation to higher alcohols with enhanced selectivity for large-chain alcohols. CO2 is an abundant and renewable carbon source for use as a feedstock, and closing the carbon cycle in an energy efficient manner has the potential for significant environmental benefits. The project is expected to advance the knowledge in rational design of new catalysts for CO2 conversion and understanding the catalyst structure-property induced reaction mechanism. This will result in an improved understanding of the reaction kinetics of utilising CO2 as a feedstock.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE130100011
Funder
Australian Research Council
Funding Amount
$470,000.00
Summary
A world class, high-resolution scanning electron microscopy facility for West Australian researchers. More than 100 West Australian researchers from a broad range of disciplines will benefit from new scanning electron microscopy facilities used to characterise surfaces of materials down to the nanoscale. This new microscope will continue the production of high-impact science outcomes that underpin Australia’s economic and social well being.
Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-si ....Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-site metal-organic framework catalyst with high reaction-activity and chemo-selectivity in converting CO2 into valuable chemicals. This advancement will provide significant benefits for Australia’s emerging chemical manufacturing industry, and ultimately leading to a carbon-neutral energy economy and environment.Read moreRead less
Assembling multi-functional nanocomposites for carbon dioxide reduction by hybrid catalytic and photochemical approach. The overall aim of this project is to assemble multi-functional nanocomposites for carbon dioxide reduction by an integrated catalytic and photocatalytic approach. The issues of impending depletion of fossil fuel resources and irreversible climate change due to carbon dioxide emissions have stimulated research for the sustainable utilisation of carbon dioxide. In situ spectros ....Assembling multi-functional nanocomposites for carbon dioxide reduction by hybrid catalytic and photochemical approach. The overall aim of this project is to assemble multi-functional nanocomposites for carbon dioxide reduction by an integrated catalytic and photocatalytic approach. The issues of impending depletion of fossil fuel resources and irreversible climate change due to carbon dioxide emissions have stimulated research for the sustainable utilisation of carbon dioxide. In situ spectroscopic studies combined with theoretical calculations will be used to elucidate the underlying reaction mechanisms of the synergistic effects of photon and thermal reduction of carbon dioxide . The success of the proposed project will allow the reduction of carbon dioxide, generate a cheap energy source in the form of environmentally benign hydrocarbons and close the carbon loop. Read moreRead less
Covalently immobilised molecular catalysts for carbon dioxide reduction. This project aims to develop innovative catalytic systems on semiconductor surfaces, to use sunlight for conversion of carbon dioxide (CO2) into high energy-content products. Sustainable chemical transformation of CO2 into valuable products, especially fuels, is one of the most important chemical processing challenges. This project will use innovative molecular engineering to covalently fix light-harvester to semiconductors ....Covalently immobilised molecular catalysts for carbon dioxide reduction. This project aims to develop innovative catalytic systems on semiconductor surfaces, to use sunlight for conversion of carbon dioxide (CO2) into high energy-content products. Sustainable chemical transformation of CO2 into valuable products, especially fuels, is one of the most important chemical processing challenges. This project will use innovative molecular engineering to covalently fix light-harvester to semiconductors. The expected outcome will be an efficient system to enhance CO2 conversion, which will not only reduce the environmental impact but also generate a cheap source of energy by closing the carbon loop. Using this approach, existing high carbon-emitting processes will be able to be replaced by new carbon-neutral or even carbon-negative ones for much-reduced environmental impact on our society.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE220100583
Funder
Australian Research Council
Funding Amount
$445,000.00
Summary
Engineering of biocatalysis in metal-organic frameworks for CO2 conversion. Transforming the greenhouse gas carbon dioxide (CO2) into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to architect a biocascade system in metal-organic frameworks (MOFs) for artificial CO2 conversion. Learned from the living organisms, a whole biocatalysis unit including enzymes and cofactors will be encased and protected in an artificial porous ....Engineering of biocatalysis in metal-organic frameworks for CO2 conversion. Transforming the greenhouse gas carbon dioxide (CO2) into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to architect a biocascade system in metal-organic frameworks (MOFs) for artificial CO2 conversion. Learned from the living organisms, a whole biocatalysis unit including enzymes and cofactors will be encased and protected in an artificial porous polymeric MOF coating. This approach is expected to deliver robust biocatalysts with high reaction-activity and chemo-selectivity in converting CO2 into methanol under the industrial operating condition, involving thermal, pH, and chemical stressors. This advancement will contribute to a carbon-neutral industry and society.Read moreRead less
Heterogeneous hydrophilic catalysts for green oxidation in bio-refining. The project aims to address one significant global challenge of developing green processes for producing high value chemicals from biomass, to enhance the environmental performance and cost-efficiency of bio-refining. This project aims to develop a new class of heterogeneous nanocatalysts with hydrophilic Co (salen) complexes for biomass oxidation in water rather than toxic solvent. This project will use this to devise prac ....Heterogeneous hydrophilic catalysts for green oxidation in bio-refining. The project aims to address one significant global challenge of developing green processes for producing high value chemicals from biomass, to enhance the environmental performance and cost-efficiency of bio-refining. This project aims to develop a new class of heterogeneous nanocatalysts with hydrophilic Co (salen) complexes for biomass oxidation in water rather than toxic solvent. This project will use this to devise practical routes for the production of targeted industrial components for flavours, fragrances, fine chemicals, and petrochemicals. The development of heterogeneous hydrophilic catalysts by which they will oxidise hydrophilic biomasses in a continuous flow system will dramatically improve the sustainability of the chemical industry.Read moreRead less