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Polymer nanodiscs. This project aims to produce disc-shaped polymer nanomaterials by utilising a new self-assembly concept based on oppositely charged polymers. This project expects to generate a modular technology that allows synthesis and control over the geometry and functionality of polymer nanoparticles. This level of control will permit a precise investigation of polymer nanodisc properties for nanomedicine applications. Expected outcomes of this project will be the fundamental understandi ....Polymer nanodiscs. This project aims to produce disc-shaped polymer nanomaterials by utilising a new self-assembly concept based on oppositely charged polymers. This project expects to generate a modular technology that allows synthesis and control over the geometry and functionality of polymer nanoparticles. This level of control will permit a precise investigation of polymer nanodisc properties for nanomedicine applications. Expected outcomes of this project will be the fundamental understanding of how nanoparticle geometry affects particle-cell interaction and how nanoscale polymer discs can be used to mimic biological nanoparticles in shape and function.Read moreRead less
Synthetic molecular transporters. This work involves the synthesis of artificial motors that transport cargo down linear tracks in a manner that is reminiscent of the function of biological motor proteins such as kinesin and myosin. Attachment of these molecular machines to solid surfaces will also be explored.
'Multi-Coloured' Tracers for Magnetic Particle Imaging . Magnetic Particle Imaging (MPI) is predicted to be the future of imaging and will outperform all current imaging techniques by having 'colours', improved resolution and 3D precision. This project aims to create 'multi-coloured' high-performance MPI tracers by synthesising a range of the most effective magnetic nanoparticle structures. The expected outcome is the fundamental understanding of the relationships between nanoparticle structures ....'Multi-Coloured' Tracers for Magnetic Particle Imaging . Magnetic Particle Imaging (MPI) is predicted to be the future of imaging and will outperform all current imaging techniques by having 'colours', improved resolution and 3D precision. This project aims to create 'multi-coloured' high-performance MPI tracers by synthesising a range of the most effective magnetic nanoparticle structures. The expected outcome is the fundamental understanding of the relationships between nanoparticle structures and their magnetic properties for the formation of MPI signals with distinct ‘colours’. The benefits will be a library of MPI tracers that are able to provide ‘coloured’, high intensity, precise signals beyond what can be achieved with other imaging technologies.Read moreRead less
A Radical Approach to Multifunctional Coordination Solids. The development of multifunctional coordination solids represents one of the foremost challenges in the field of advanced materials as their properties underpin the next generation of technologically useful devices. Using a highly targeted theoretical and experimental approach for crystal engineering, this project aims to generate coordination solids that integrate radicals as molecular components for charge transfer. At a fundamental le ....A Radical Approach to Multifunctional Coordination Solids. The development of multifunctional coordination solids represents one of the foremost challenges in the field of advanced materials as their properties underpin the next generation of technologically useful devices. Using a highly targeted theoretical and experimental approach for crystal engineering, this project aims to generate coordination solids that integrate radicals as molecular components for charge transfer. At a fundamental level these materials will offer unprecedented insights into charge delocalisation and radical-induced switching phenomena in three-dimensional coordination space. It is expected that the outcomes of the project will spur the development of devices for applications ranging from solid state sensing to energy conversion and storage.Read moreRead less
Sulphate sensor for reverse osmosis integrity and performance monitoring. Sulphate sensor for reverse osmosis integrity and performance monitoring. This project aims to investigate new chemical sensors for sulphate for online reverse osmosis integrity and performance monitoring at an advanced water recycling plant. Wastewater re-use is increasingly important in Australia and worldwide for providing potable water. Demonstrating the integrity and performance of treatment technologies is needed to ....Sulphate sensor for reverse osmosis integrity and performance monitoring. Sulphate sensor for reverse osmosis integrity and performance monitoring. This project aims to investigate new chemical sensors for sulphate for online reverse osmosis integrity and performance monitoring at an advanced water recycling plant. Wastewater re-use is increasingly important in Australia and worldwide for providing potable water. Demonstrating the integrity and performance of treatment technologies is needed to meet health regulations. Sulphate and other surrogates of biological entities enable a rapid, on-line approach to integrity and performance monitoring, but detection with available analytical chemical technology is not feasible. This research is expected to enable better management of water treatment processes and demonstrate compliance to health standards.Read moreRead less
Light driven supramolecular reactors. A major problem facing synthetic chemistry is how to control chemical reactivity using benign techniques. The aim of this project is to form supramolecular capsules that can bind guest molecules and use visible light to drive chemical reactions inside these cages. This project aims to develop the first examples of molecular cages that are able to catalyse photoredox processes. These enantiopure, self-assembled cages will be based on ruthenium(II) complexes w ....Light driven supramolecular reactors. A major problem facing synthetic chemistry is how to control chemical reactivity using benign techniques. The aim of this project is to form supramolecular capsules that can bind guest molecules and use visible light to drive chemical reactions inside these cages. This project aims to develop the first examples of molecular cages that are able to catalyse photoredox processes. These enantiopure, self-assembled cages will be based on ruthenium(II) complexes with established photophysical properties. The expected outcomes will include the first proof-of-principle examples of controlled photoredox reactions, opening the door for the development of enantioselective molecular photoreactors.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE220100558
Funder
Australian Research Council
Funding Amount
$420,000.00
Summary
Biomimetic catalysis for sustainable polymer syntheses. New classes of sustainable polymers are required to produce biodegradable materials for nanotechnology applications. This project aims to address this demand by developing versatile polymerisation catalysis protocols inspired by enzymatic systems. This new method of polymer synthesis expects to generate a diverse set of nanomaterials using chemical networks that modulate reaction conditions on-demand, providing facile control over polymer f ....Biomimetic catalysis for sustainable polymer syntheses. New classes of sustainable polymers are required to produce biodegradable materials for nanotechnology applications. This project aims to address this demand by developing versatile polymerisation catalysis protocols inspired by enzymatic systems. This new method of polymer synthesis expects to generate a diverse set of nanomaterials using chemical networks that modulate reaction conditions on-demand, providing facile control over polymer form and resulting function. The expected outcomes of this project will advance our understanding of polymer structure-property relationships and stimuli-responsive systems, and should provide significant benefits for the deployment of biorenewable polymers as next-generation soft materials.Read moreRead less
Controlling chemistry with light-powered molecular machines. This project aims to develop easily prepared synthetic molecules capable of performing complex tasks, such as controlled molecular motion or signal amplification, using visible light both as a fuel and a reporting mechanism. The challenge of using non-destructive visible light to control molecular motion is one of the most fundamental in science. The development of small molecular 'swimmers' would represent a landmark advance in the fi ....Controlling chemistry with light-powered molecular machines. This project aims to develop easily prepared synthetic molecules capable of performing complex tasks, such as controlled molecular motion or signal amplification, using visible light both as a fuel and a reporting mechanism. The challenge of using non-destructive visible light to control molecular motion is one of the most fundamental in science. The development of small molecular 'swimmers' would represent a landmark advance in the field. An expected outcome of the project is the control and monitoring of synthetic small molecule motion and function using visible light. These fundamental studies should benefit society by reducing energy consumption and waste during processes from production to disposal.Read moreRead less
All-Metal Nanoporous Materials as Highly Active Electrocatalysts. This project aims to create new avenues for well-controlled large-scale synthesis of hierarchical nanoporous platinum-based architectures, and develop applications for the resultant new electrocatalysts. Developing novel high-performance, low-cost, and long-life electrode catalysts can improve the efficiency, cost, and durability of energy conversion technology. The project plans to use the unique properties of well-defined nanoar ....All-Metal Nanoporous Materials as Highly Active Electrocatalysts. This project aims to create new avenues for well-controlled large-scale synthesis of hierarchical nanoporous platinum-based architectures, and develop applications for the resultant new electrocatalysts. Developing novel high-performance, low-cost, and long-life electrode catalysts can improve the efficiency, cost, and durability of energy conversion technology. The project plans to use the unique properties of well-defined nanoarchitectures to reduce platinum content and to improve electrocatalytic performance. Nanoporous systems in electrocatalysts can provide more active sites and effective surface permeability, which should enhance catalytic activity. Project outcomes may also contribute to our understanding of the relationships among morphologies, pore structures, surface atomic structures and catalytic activities to guide the development of other kinds of high performance nanoporous catalysts.Read moreRead less