Minerals replacement reactions: understanding mineral formation under hydrothermal conditions. Many geological processes involve the transformation of one mineral into another. By understanding molecular-level reaction mechanisms, we can predict how fast reactions progress, and what the final product will look like. This project focuses on a reaction mechanism called 'coupled dissolution-reprecipitation', in which the parent mineral is dissolved into a thin layer of fluid at the reaction front, ....Minerals replacement reactions: understanding mineral formation under hydrothermal conditions. Many geological processes involve the transformation of one mineral into another. By understanding molecular-level reaction mechanisms, we can predict how fast reactions progress, and what the final product will look like. This project focuses on a reaction mechanism called 'coupled dissolution-reprecipitation', in which the parent mineral is dissolved into a thin layer of fluid at the reaction front, and the daughter mineral subsequently precipitates. This concept will be applied to sulfide minerals for the first time. The results have many applications for the Australian mining industry, in particular in improving the efficiency of the processing of Ni- and Au-ores.Read moreRead less
Contemporary sulfur biomineralisation in acid sulfate soil landscapes. This project aims to generate fundamental knowledge on the processes, kinetics and impacts to water quality of contemporary sulfur biomineralisation in acid sulfate soil landscapes. Extreme concentrations of highly reactive sulfides are forming in the surface sediments of floodplain drains, wetlands and agricultural soils. The newly forming sulfides are linked to severe oxygen depletion and acidification of coastal rivers a ....Contemporary sulfur biomineralisation in acid sulfate soil landscapes. This project aims to generate fundamental knowledge on the processes, kinetics and impacts to water quality of contemporary sulfur biomineralisation in acid sulfate soil landscapes. Extreme concentrations of highly reactive sulfides are forming in the surface sediments of floodplain drains, wetlands and agricultural soils. The newly forming sulfides are linked to severe oxygen depletion and acidification of coastal rivers and the complete failure of floodplain vegetation, leaving soils susceptible to erosion. The proposed study will greatly advance our understanding of how our precious coastal floodplain soil and water resources are being degraded, and will guide better land management.
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Learning to predict polymorphism through simulation of nucleation and nanoparticle evolution. Many substances are capable of exhibiting a myriad of different structures despite having the same composition. This behaviour can have a significant impact on the production of new pharmaceuticals, since the sudden appearance of a new form can lead to instant withdrawal of the drug. By understanding how different forms grow, rather than focusing on just the stability of the product, this research will ....Learning to predict polymorphism through simulation of nucleation and nanoparticle evolution. Many substances are capable of exhibiting a myriad of different structures despite having the same composition. This behaviour can have a significant impact on the production of new pharmaceuticals, since the sudden appearance of a new form can lead to instant withdrawal of the drug. By understanding how different forms grow, rather than focusing on just the stability of the product, this research will lead to more reliable prediction of how pharmaceutical molecules might assemble. The same technology will potentially have impacts in many areas of nanoscience through improvements in efficiency, including the production of minerals, desalination and undersea gas recovery.Read moreRead less
An experimental study of trace element equilibria during metamorphism. The analytical methods and experimental data to be developed will enable an Australian team to become world leaders in determining pressures and temperatures of mineral growth that correspond to a range of depths and temperature gradients in the Earth tha t is wider than accessible previously. Obtaining this information from small zones within single grains will allow determination of rates of change, and give us a detailed p ....An experimental study of trace element equilibria during metamorphism. The analytical methods and experimental data to be developed will enable an Australian team to become world leaders in determining pressures and temperatures of mineral growth that correspond to a range of depths and temperature gradients in the Earth tha t is wider than accessible previously. Obtaining this information from small zones within single grains will allow determination of rates of change, and give us a detailed picture of how the host rock has evolved, even from very small samples. One application would be checking the origin of relatively common minerals for whether they could be associated with diamonds.Read moreRead less
Order-disorder behaviour in Bi-tellurides: a tool to monitor gold scavenging by Bi-Te melts. This project addresses a group of minerals (bismuth tellurides) that are often part of the exotic assemblages present in gold deposits, yet their potential to model the gold-forming processes is only recently apparent. These minerals also have the capacity to record their genetic history due to crystal modularity. Materials scientists target the analogous synthetic compounds because of the same structura ....Order-disorder behaviour in Bi-tellurides: a tool to monitor gold scavenging by Bi-Te melts. This project addresses a group of minerals (bismuth tellurides) that are often part of the exotic assemblages present in gold deposits, yet their potential to model the gold-forming processes is only recently apparent. These minerals also have the capacity to record their genetic history due to crystal modularity. Materials scientists target the analogous synthetic compounds because of the same structural modularity for applications in nanotechnology. The dataset on the mineral compounds, using the geological environment as a natural laboratory, will serve materials science research, as much as delivering key information relevant to understanding the reasons for gold enrichment in economically important types of ores. Read moreRead less
Water storage in the earth's mantle - understanding the process of OH incorporation in olivine. The amount of water in the Earth's mantle is thought to be sufficient to replace the surface oceans more than ten times. Whether this water exists in a fluid, melt, or mineral is important for understanding a range of mantle properties. The entire upper mantle water budget may be accommodated at defect sites in the mineral olivine. However, defects found in natural olivine do not correspond to thos ....Water storage in the earth's mantle - understanding the process of OH incorporation in olivine. The amount of water in the Earth's mantle is thought to be sufficient to replace the surface oceans more than ten times. Whether this water exists in a fluid, melt, or mineral is important for understanding a range of mantle properties. The entire upper mantle water budget may be accommodated at defect sites in the mineral olivine. However, defects found in natural olivine do not correspond to those produced
experimentally. Therefore, previous conclusions on water storage in the mantle are questionable. To address this problem the mechanism of water incorporation in olivine will be investigated using experimental petrology and spectroscopy.Read moreRead less
Experimental studies on hydrothermal reaction processes at the molecular level: the role of mineral replacement reactions in ore formation. Most of the World's supply of metals such as copper (Cu), gold (Au), molybdenum (Mo), lead (Pb), zinc (Zn) or uranium (U) comes from hydrothermal ore deposits. The metals were deposited deep below the Earth's surface when hot fluids, carrying minute quantities of the metals, reacted with suitable rocks to form ore minerals. By understanding molecular-level ....Experimental studies on hydrothermal reaction processes at the molecular level: the role of mineral replacement reactions in ore formation. Most of the World's supply of metals such as copper (Cu), gold (Au), molybdenum (Mo), lead (Pb), zinc (Zn) or uranium (U) comes from hydrothermal ore deposits. The metals were deposited deep below the Earth's surface when hot fluids, carrying minute quantities of the metals, reacted with suitable rocks to form ore minerals. By understanding molecular-level reaction mechanisms at high pressure and temperature, we can predict the nature of the ore minerals formed for a given set of physical and chemical conditions. This multidisciplinary research project is devoted to understanding these chemical and physical processes and how this knowledge can be applied to improve mineral exploration, mining, and ore processing.Read moreRead less
Mineral Physics of the Earth's Core. Most information on the nature of Earth's core properties has come from teleseismic studies, which detect weak earthquake-wave signals that have traversed the Earth's deepest interior. These studies have revealed several unusual and enigmatic phenomena in the core, but interpretation of these observations must rely on mineral-physics data on the materials of the core (e.g. iron-based alloys). This project will create a unique world-class ultra-high pressure l ....Mineral Physics of the Earth's Core. Most information on the nature of Earth's core properties has come from teleseismic studies, which detect weak earthquake-wave signals that have traversed the Earth's deepest interior. These studies have revealed several unusual and enigmatic phenomena in the core, but interpretation of these observations must rely on mineral-physics data on the materials of the core (e.g. iron-based alloys). This project will create a unique world-class ultra-high pressure laboratory to obtain such data. By defining the composition and mineralogy of Earth's core, it will place Australia in the forefront of this exciting research field, and will also represent a major national resource for the study of novel materials at extreme conditions.Read moreRead less
Schwertmannite in acid sulfate soil landscapes: iron cycling induced acidification. Acid sulfate soils impact over 24 million ha of land throughout the world, 4 million ha of valuable coastal land in Australia alone. Their oxidation and acidification are the cause of catastrophic declines in water quality, aquatic habitat, agricultural productivity and urban infrastructure. The practical benefits of this project arise from an improved understanding of the processes controlling acidification a ....Schwertmannite in acid sulfate soil landscapes: iron cycling induced acidification. Acid sulfate soils impact over 24 million ha of land throughout the world, 4 million ha of valuable coastal land in Australia alone. Their oxidation and acidification are the cause of catastrophic declines in water quality, aquatic habitat, agricultural productivity and urban infrastructure. The practical benefits of this project arise from an improved understanding of the processes controlling acidification and water quality in these areas. Intellectual benefits include the development and application of novel geochemical concepts involving iron minerals relevant to acidity impacted coastal rivers, wetlands and estuaries; this project will enhance Australia's capacity for sustainable environmental management.Read moreRead less
Resistivity of typical rocks at crustal pressure and temperature conditions from combined laboratory and magnetotelluric measurements. Magnetotelluric surveys are playing an increasing role in Australian geoscience, including academic research, data collected by geological surveys (including a role in Geoscience Australia's $58.9 million Onshore Energy and Security Program), mineral exploration and geothermal exploration. This project will enable the results of these surveys to be interpreted mo ....Resistivity of typical rocks at crustal pressure and temperature conditions from combined laboratory and magnetotelluric measurements. Magnetotelluric surveys are playing an increasing role in Australian geoscience, including academic research, data collected by geological surveys (including a role in Geoscience Australia's $58.9 million Onshore Energy and Security Program), mineral exploration and geothermal exploration. This project will enable the results of these surveys to be interpreted more accurately and meaningfully by constraining the expected resistivities of crustal rocks at various pressures and temperatures. This research is vital if the investment currently being put into MT surveys is to be capitalized upon. Read moreRead less