Advancing the chemistry of rare earths - an Australian resource. This project aims to advance knowledge of the synthesis, structures and reactivity of highly reactive rare earth metal-organic compounds. The project expects to build the knowledge and skills to underpin many developments of Australia's still under utilized rare earth resources to diversify from Chinese domination. The anticipated outcomes will be new synthetic and reaction chemistry including a demonstration of how size and electr ....Advancing the chemistry of rare earths - an Australian resource. This project aims to advance knowledge of the synthesis, structures and reactivity of highly reactive rare earth metal-organic compounds. The project expects to build the knowledge and skills to underpin many developments of Australia's still under utilized rare earth resources to diversify from Chinese domination. The anticipated outcomes will be new synthetic and reaction chemistry including a demonstration of how size and electronic factors can be used to modify and advance rare earth chemistry. This project should provide significant benefit such as are a better knowledge base in rare earth chemistry to underpin future applications in chemical manufacturing, new materials, catalysis and recycling.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE240100054
Funder
Australian Research Council
Funding Amount
$1,341,398.00
Summary
Dedicated High-throughput 3D-Electron Diffractometer. This proposal aims to install the first dedicated high-throughput 3D-electron diffractometer in the Southern Hemisphere, and one of the first in the world. It will be able to rapidly solve the atomic-scale structures of molecules and materials for which this is now extremely difficult and time-consuming – or impossible – due to the inability to grow large enough crystals for traditional X-ray diffraction. It will thus provide a significant ad ....Dedicated High-throughput 3D-Electron Diffractometer. This proposal aims to install the first dedicated high-throughput 3D-electron diffractometer in the Southern Hemisphere, and one of the first in the world. It will be able to rapidly solve the atomic-scale structures of molecules and materials for which this is now extremely difficult and time-consuming – or impossible – due to the inability to grow large enough crystals for traditional X-ray diffraction. It will thus provide a significant advantage for chemists, physicists, biologists, geologists, and engineers who rely on detailed structural knowledge to rationally optimise the properties of their compounds, from pharmaceutical activity to carbon capture to superconductivity, to the substantial benefit of multiple national priority areas.Read moreRead less
Switching, sensing and multifunctionality in spin crossover materials. This project aims to increase the temperature range where molecular spin states can be switched optically or electronically, and to develop new multifunctional materials combining switchable hosts with functional guests. By combining novel theories, synthesis and experiments, this project expects to generate step-change advances in the understanding of spin-switching materials and discover materials with novel properties wort ....Switching, sensing and multifunctionality in spin crossover materials. This project aims to increase the temperature range where molecular spin states can be switched optically or electronically, and to develop new multifunctional materials combining switchable hosts with functional guests. By combining novel theories, synthesis and experiments, this project expects to generate step-change advances in the understanding of spin-switching materials and discover materials with novel properties worthy of commercial development. Significant anticipated outcomes and benefits include the identification and development of several new classes of materials function, each of major fundamental interest, and the generation of new advanced materials with applications in electronics, sensing and gas separations.Read moreRead less
Investigating Energy Transfer Pathways in Lanthanoid Elements. This project aims to investigate fundamental aspects concerning the luminescent properties of compounds containing lanthanoid elements. These elements have extensive use in many high-tech applications, yet essential knowledge related to their properties is still quite limited. This project will elucidate in detail the origin of lanthanoid luminescence through a multidisciplinary approach combining synthetic chemistry and spectroscopy ....Investigating Energy Transfer Pathways in Lanthanoid Elements. This project aims to investigate fundamental aspects concerning the luminescent properties of compounds containing lanthanoid elements. These elements have extensive use in many high-tech applications, yet essential knowledge related to their properties is still quite limited. This project will elucidate in detail the origin of lanthanoid luminescence through a multidisciplinary approach combining synthetic chemistry and spectroscopy. The outcomes of this proposal will expand our limited knowledge in this field, underpinning the future development of novel materials for advanced applications. This will lead to significant economic benefit in Australia as new commercial applications relying on lanthanoid luminescence will be developed.Read moreRead less
Converting Biomass into Value-Added Catalysts for Water Electrolysis. This project aims to employ agricultural waste to manufacture new highly active and stable non-precious metal catalysts for accelerating hydrogen production from water electrolysis. The project expects to generate new knowledge in the development of low-cost and sustainable catalysts for renewable hydrogen production and new technology for converting agricultural waste into value-added catalysts. The project outcomes are expec ....Converting Biomass into Value-Added Catalysts for Water Electrolysis. This project aims to employ agricultural waste to manufacture new highly active and stable non-precious metal catalysts for accelerating hydrogen production from water electrolysis. The project expects to generate new knowledge in the development of low-cost and sustainable catalysts for renewable hydrogen production and new technology for converting agricultural waste into value-added catalysts. The project outcomes are expected to benefit Australia by creating new commercial opportunities in ‘waste-to-catalyst’ conversion and generating a new pathway for managing and recycling agricultural waste, thus providing both environmental and economic benefits while contributing to a sustainable economy.Read moreRead less
Emergent organocopper complexes as robust catalysts for electrosynthesis. The capture and stabilisation of highly reactive chemical species is critical to making advances in the synthesis of novel materials, agrochemicals and pharmaceuticals. Metal-bound carbanions are essential components of carbon-carbon bond forming reactions. This project aims to develop an unprecedented family of copper catalysts and deliver an innovative and versatile chemical reactivity platform. Expected outcomes of this ....Emergent organocopper complexes as robust catalysts for electrosynthesis. The capture and stabilisation of highly reactive chemical species is critical to making advances in the synthesis of novel materials, agrochemicals and pharmaceuticals. Metal-bound carbanions are essential components of carbon-carbon bond forming reactions. This project aims to develop an unprecedented family of copper catalysts and deliver an innovative and versatile chemical reactivity platform. Expected outcomes of this project include methods of tempering and unleashing the high reactivity of these species by controlling the oxidation state of the copper ion. Benefits of these outcomes include fundamental understanding of the reactivity of a new class of copper complex that has potential commercial applications in catalysis.Read moreRead less
A top-down approach to synthesising high-value fluorocarbons. Fluorocarbons' ability to impart high stability, solubility, and unique reactivity to host molecules renders them invaluable in agrochemicals, pharmaceuticals, polymers and surfactants. Their robustness also renders them environmentally persistent. There are no industrially utilised methods for the re-purposing or recycling of fluorocarbons. This project aims to generate new methods for the selective activation of carbon-fluorine bond ....A top-down approach to synthesising high-value fluorocarbons. Fluorocarbons' ability to impart high stability, solubility, and unique reactivity to host molecules renders them invaluable in agrochemicals, pharmaceuticals, polymers and surfactants. Their robustness also renders them environmentally persistent. There are no industrially utilised methods for the re-purposing or recycling of fluorocarbons. This project aims to generate new methods for the selective activation of carbon-fluorine bonds in polyfluorocarbons, allowing their incorporation or repurposing into high value chemicals and/or easy derivitisation to access a plethora of new fluorocarbon products. Expected outcomes will allow new processing methods to value add to fluorocarbons while preventing their environmental release. Read moreRead less