Ab initio Theory in Complex Materials and Surfaces: Prediction and Design of Functional Structures. Using state-of-the-art first-principles theory, this project involves the study of complex materials and surfaces which are central to areas of high technological interest, namely, high temperature ferromagnetic semiconductor materials for spintronics, nitride-based structures for optoelectronic devices, nanocomposites for protective coatings, as well as heterogeneous oxidation catalysis. It wil ....Ab initio Theory in Complex Materials and Surfaces: Prediction and Design of Functional Structures. Using state-of-the-art first-principles theory, this project involves the study of complex materials and surfaces which are central to areas of high technological interest, namely, high temperature ferromagnetic semiconductor materials for spintronics, nitride-based structures for optoelectronic devices, nanocomposites for protective coatings, as well as heterogeneous oxidation catalysis. It will provide fundamental knowledge and understanding on the atomic level, and will facilitate the design and development of functional materials and surfaces of relevance to industry.Read moreRead less
Photodegradation of Oestrogenic Pollutants in the aquatic environment. Recent media attention has highlighted the problem of oestrogenic pollutants in the aquatic environment. This research proposes to investigate Photocatalysis of oestrogens in water using the magnetic titanium dioxide particles developed at the Centre for Particle and Catalyst Technologies in the University of New South Wales, Sydney. The natural oestrogens 17b-oestradiol, oestrone and oestriol and the synthetic oestrogen 17a- ....Photodegradation of Oestrogenic Pollutants in the aquatic environment. Recent media attention has highlighted the problem of oestrogenic pollutants in the aquatic environment. This research proposes to investigate Photocatalysis of oestrogens in water using the magnetic titanium dioxide particles developed at the Centre for Particle and Catalyst Technologies in the University of New South Wales, Sydney. The natural oestrogens 17b-oestradiol, oestrone and oestriol and the synthetic oestrogen 17a-ethynyl oestradiol (the main constituent of the contraceptive pill) will be investigated in the photocatalytic system. Degradation will be monitored using various analytical techniques. Other commercial catalysts will also be investigated and compared with the magnetic catalyst and previous catalysts tested.Read moreRead less
From Nanostructured Catalysts to Process Innovation. The results of this research will help to advance the fundamental scientific understanding of industrially important chemical reactions and give clear leads as to how to improve them. In particular, new catalysts (i.e. agents that increase the speed and selectivity of chemical reactions) will be generated and the first steps towards process innovation will be taken, using high-throughput equipment unique in the Southern Hemisphere. These new c ....From Nanostructured Catalysts to Process Innovation. The results of this research will help to advance the fundamental scientific understanding of industrially important chemical reactions and give clear leads as to how to improve them. In particular, new catalysts (i.e. agents that increase the speed and selectivity of chemical reactions) will be generated and the first steps towards process innovation will be taken, using high-throughput equipment unique in the Southern Hemisphere. These new catalysts will be the basis for the design of new and/or improved industrial processes that will be ?greener?, safer, use fewer resources, produce less waste and are generally more efficient and effective. As a result the Australian chemicals industry will be more competitive.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0775548
Funder
Australian Research Council
Funding Amount
$180,000.00
Summary
Advanced characterisation facilities for functional nanostructured materials. A critical factor that enhances frontier research is a set of advanced core research experimental facilities for material characterisation purposes. The proposed equipment aims to: (1) provide research facilities for advanced nanomaterial research; (2) improve national competitiveness and growth in a knowledge-based economy; and (3) foster local talented researchers in order to meet the strategic needs of the nation fo ....Advanced characterisation facilities for functional nanostructured materials. A critical factor that enhances frontier research is a set of advanced core research experimental facilities for material characterisation purposes. The proposed equipment aims to: (1) provide research facilities for advanced nanomaterial research; (2) improve national competitiveness and growth in a knowledge-based economy; and (3) foster local talented researchers in order to meet the strategic needs of the nation for a sustainable environment. These activities will revitalise Australia's leading role in creating new technologies with particular relevance to using advanced nanostructures for the production of clean air and water, and sustainable energy alternatives.Read moreRead less
Degradation of Oestrogenic and Carcinogenic Substances in Water using alternative water treatment technologies- Membrane Technology and Photocatalysis. There is currently much concern about the release into the aquatic environment of oestrogenic and carcinogenic pollutants. Current conventional water treatment technologies are ineffective in removing them from our water supplies. This research proposes to investigate alternative water treatment technologies for the removal of these compounds of ....Degradation of Oestrogenic and Carcinogenic Substances in Water using alternative water treatment technologies- Membrane Technology and Photocatalysis. There is currently much concern about the release into the aquatic environment of oestrogenic and carcinogenic pollutants. Current conventional water treatment technologies are ineffective in removing them from our water supplies. This research proposes to investigate alternative water treatment technologies for the removal of these compounds of concern. The technologies to be investigated involve integrating membrane technology and titanium dioxide photocatalysis to produce a highly effective and efficient water treatment process. The effects of various parameters on degradation of the pollutants will be investigated and monitored using different analytical techniques.Read moreRead less
Novel Nanostructures of Metal Oxides and Sulfides Intercalated Laponite for Catalytic Applications. The project aims to develop a novel synthesis approach for making nanocomposites of transition metal oxides and sulfides intercalated laponite clay. Such nanomaterials made by integrating template synthesis and intercalation have superior pore and surface properties promising for advanced catalytic applications. The project will provide insights into mechanisms of nanostructure formation and inter ....Novel Nanostructures of Metal Oxides and Sulfides Intercalated Laponite for Catalytic Applications. The project aims to develop a novel synthesis approach for making nanocomposites of transition metal oxides and sulfides intercalated laponite clay. Such nanomaterials made by integrating template synthesis and intercalation have superior pore and surface properties promising for advanced catalytic applications. The project will provide insights into mechanisms of nanostructure formation and interactions of molecular species during synthesis. The best catalysts screened will be tested for two important reactions to establish the relationships between processing parameters, nanostructural properties and catalytic performance. Optimised synthesis parameters for high catalytic performance will be obtained. The project contributes to significant knowledge creation in nanomaterials science and catalysis.Read moreRead less
Molecular Recognition in Chiral Ionic Liquids as Basis for the Design and Synthesis of New Enantioselective Heterogeneous Catalysts and Membranes. Molecules that can exist as mirror images, each with different, e.g., beneficial vs. toxic properties, underpin the pharmaceutical industry and increasingly new highly selective pesticides, and flavours/fragrances.
Current commercial pathways often make mixtures of the mirror images that then need to be separated laboriously. These routes are ineffic ....Molecular Recognition in Chiral Ionic Liquids as Basis for the Design and Synthesis of New Enantioselective Heterogeneous Catalysts and Membranes. Molecules that can exist as mirror images, each with different, e.g., beneficial vs. toxic properties, underpin the pharmaceutical industry and increasingly new highly selective pesticides, and flavours/fragrances.
Current commercial pathways often make mixtures of the mirror images that then need to be separated laboriously. These routes are inefficient, creating waste and use resources poorly.
We aim to create solutions for these problems, using supported thin films of special, new types of salts that are liquid at room temperature, and which have other unusual chemical properties that make them ideally suited to enable efficient conversions.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0668449
Funder
Australian Research Council
Funding Amount
$158,000.00
Summary
Advanced Surface and Porosity Characterization Facility. Material properties and processing play a significant role in many Australian industries. The benefits of research with this infrastructure to the greater community lies in the technological development of superior materials and processes to support the continued development of these industries. In addition to technological advances, this will have economic benefits due to improved business market share and profitability in these industrie ....Advanced Surface and Porosity Characterization Facility. Material properties and processing play a significant role in many Australian industries. The benefits of research with this infrastructure to the greater community lies in the technological development of superior materials and processes to support the continued development of these industries. In addition to technological advances, this will have economic benefits due to improved business market share and profitability in these industries, as well as educational development through completion of high quality research higher degree students.Read moreRead less
An Innovative Solid-State Approach to Enhanced Solar-Hydrogen Production. The project will make a major step towards the development of solar-hydrogen technology, which promises to deliver a clean and renewable fuel - hydrogen - from water (seawater or other) using sunlight and a suitable photo-catalytic material. Not only will solar-hydrogen assist Australia to reduce its dependence on imported energy, but will also reduce Australia's carbon emissions and overall contribution to climate change. ....An Innovative Solid-State Approach to Enhanced Solar-Hydrogen Production. The project will make a major step towards the development of solar-hydrogen technology, which promises to deliver a clean and renewable fuel - hydrogen - from water (seawater or other) using sunlight and a suitable photo-catalytic material. Not only will solar-hydrogen assist Australia to reduce its dependence on imported energy, but will also reduce Australia's carbon emissions and overall contribution to climate change. When commercialized, solar-hydrogen technology may also enable Australia to become a global leader in the export of clean fuel, which will have very positive, far-reaching consequences for the economy.Read moreRead less
Supercritical Highly-Integrated and Modular, Continuous Solid-Catalysed Biodiesel Production from Plant and Animal Feedstocks. We propose to revolutionise biodiesel production by creating a new reactor type and associated process that allows the production of 160,000 tonnes of biodiesel a year in a supercritical reactor volume of one cubic metre after scale-up. In this project, we propose to design the appropriate catalysts and pilot plant to study our ideas which should lead to a highly effici ....Supercritical Highly-Integrated and Modular, Continuous Solid-Catalysed Biodiesel Production from Plant and Animal Feedstocks. We propose to revolutionise biodiesel production by creating a new reactor type and associated process that allows the production of 160,000 tonnes of biodiesel a year in a supercritical reactor volume of one cubic metre after scale-up. In this project, we propose to design the appropriate catalysts and pilot plant to study our ideas which should lead to a highly efficient and sustainable system that offers a real alternative to current mineral oil-based technologies.Read moreRead less