Ab initio Theory in Complex Materials and Surfaces: Prediction and Design of Functional Structures. Using state-of-the-art first-principles theory, this project involves the study of complex materials and surfaces which are central to areas of high technological interest, namely, high temperature ferromagnetic semiconductor materials for spintronics, nitride-based structures for optoelectronic devices, nanocomposites for protective coatings, as well as heterogeneous oxidation catalysis. It wil ....Ab initio Theory in Complex Materials and Surfaces: Prediction and Design of Functional Structures. Using state-of-the-art first-principles theory, this project involves the study of complex materials and surfaces which are central to areas of high technological interest, namely, high temperature ferromagnetic semiconductor materials for spintronics, nitride-based structures for optoelectronic devices, nanocomposites for protective coatings, as well as heterogeneous oxidation catalysis. It will provide fundamental knowledge and understanding on the atomic level, and will facilitate the design and development of functional materials and surfaces of relevance to industry.Read moreRead less
From Nanostructured Catalysts to Process Innovation. The results of this research will help to advance the fundamental scientific understanding of industrially important chemical reactions and give clear leads as to how to improve them. In particular, new catalysts (i.e. agents that increase the speed and selectivity of chemical reactions) will be generated and the first steps towards process innovation will be taken, using high-throughput equipment unique in the Southern Hemisphere. These new c ....From Nanostructured Catalysts to Process Innovation. The results of this research will help to advance the fundamental scientific understanding of industrially important chemical reactions and give clear leads as to how to improve them. In particular, new catalysts (i.e. agents that increase the speed and selectivity of chemical reactions) will be generated and the first steps towards process innovation will be taken, using high-throughput equipment unique in the Southern Hemisphere. These new catalysts will be the basis for the design of new and/or improved industrial processes that will be ?greener?, safer, use fewer resources, produce less waste and are generally more efficient and effective. As a result the Australian chemicals industry will be more competitive.Read moreRead less
Electron transfer in proteins, a study of mechanism and function. Our research will probe the mechanisms by which nature's living systems build, maintain, and reproduce. We present an ability to understand these processes at a detailed molecular level using science and technology at the forefront of multidisciplinary research. The research will provide a foundation for new smart materials, technologies and future industries, and also ways forward for future basic scientific research and endeavo ....Electron transfer in proteins, a study of mechanism and function. Our research will probe the mechanisms by which nature's living systems build, maintain, and reproduce. We present an ability to understand these processes at a detailed molecular level using science and technology at the forefront of multidisciplinary research. The research will provide a foundation for new smart materials, technologies and future industries, and also ways forward for future basic scientific research and endeavor. All this is done with the best international researchers and capabilities within a local environment that will help to train the next generation of Australian scientists.Read moreRead less
Novel Nanostructures of Metal Oxides and Sulfides Intercalated Laponite for Catalytic Applications. The project aims to develop a novel synthesis approach for making nanocomposites of transition metal oxides and sulfides intercalated laponite clay. Such nanomaterials made by integrating template synthesis and intercalation have superior pore and surface properties promising for advanced catalytic applications. The project will provide insights into mechanisms of nanostructure formation and inter ....Novel Nanostructures of Metal Oxides and Sulfides Intercalated Laponite for Catalytic Applications. The project aims to develop a novel synthesis approach for making nanocomposites of transition metal oxides and sulfides intercalated laponite clay. Such nanomaterials made by integrating template synthesis and intercalation have superior pore and surface properties promising for advanced catalytic applications. The project will provide insights into mechanisms of nanostructure formation and interactions of molecular species during synthesis. The best catalysts screened will be tested for two important reactions to establish the relationships between processing parameters, nanostructural properties and catalytic performance. Optimised synthesis parameters for high catalytic performance will be obtained. The project contributes to significant knowledge creation in nanomaterials science and catalysis.Read moreRead less
Novel Graphitic Mesoporous Carbon Materials for Next Generation Carbon Catalyst Supports and Carbon Electrodes. This project will bring about direct application benefits in terms of disclosing novel graphitic mesoporous carbons with high accessible surface area and graphitic framework as catalyst supports and electrode materials. This would lead to advanced processes important to the Australian energy and environmental industries, such as electrical double layer capacitors, greenhouse reduction ....Novel Graphitic Mesoporous Carbon Materials for Next Generation Carbon Catalyst Supports and Carbon Electrodes. This project will bring about direct application benefits in terms of disclosing novel graphitic mesoporous carbons with high accessible surface area and graphitic framework as catalyst supports and electrode materials. This would lead to advanced processes important to the Australian energy and environmental industries, such as electrical double layer capacitors, greenhouse reduction by hydrogen fuel, and hydrodesulfurization of diesel fuels. The techniques and synthesis strategies developed in this project are also applicable to creating other graphitic mesoporsous carbons important to advanced sensors, fuel cells and optoelectronic applications. Read moreRead less
Molecular Recognition in Chiral Ionic Liquids as Basis for the Design and Synthesis of New Enantioselective Heterogeneous Catalysts and Membranes. Molecules that can exist as mirror images, each with different, e.g., beneficial vs. toxic properties, underpin the pharmaceutical industry and increasingly new highly selective pesticides, and flavours/fragrances.
Current commercial pathways often make mixtures of the mirror images that then need to be separated laboriously. These routes are ineffic ....Molecular Recognition in Chiral Ionic Liquids as Basis for the Design and Synthesis of New Enantioselective Heterogeneous Catalysts and Membranes. Molecules that can exist as mirror images, each with different, e.g., beneficial vs. toxic properties, underpin the pharmaceutical industry and increasingly new highly selective pesticides, and flavours/fragrances.
Current commercial pathways often make mixtures of the mirror images that then need to be separated laboriously. These routes are inefficient, creating waste and use resources poorly.
We aim to create solutions for these problems, using supported thin films of special, new types of salts that are liquid at room temperature, and which have other unusual chemical properties that make them ideally suited to enable efficient conversions.Read moreRead less
An Innovative Solid-State Approach to Enhanced Solar-Hydrogen Production. The project will make a major step towards the development of solar-hydrogen technology, which promises to deliver a clean and renewable fuel - hydrogen - from water (seawater or other) using sunlight and a suitable photo-catalytic material. Not only will solar-hydrogen assist Australia to reduce its dependence on imported energy, but will also reduce Australia's carbon emissions and overall contribution to climate change. ....An Innovative Solid-State Approach to Enhanced Solar-Hydrogen Production. The project will make a major step towards the development of solar-hydrogen technology, which promises to deliver a clean and renewable fuel - hydrogen - from water (seawater or other) using sunlight and a suitable photo-catalytic material. Not only will solar-hydrogen assist Australia to reduce its dependence on imported energy, but will also reduce Australia's carbon emissions and overall contribution to climate change. When commercialized, solar-hydrogen technology may also enable Australia to become a global leader in the export of clean fuel, which will have very positive, far-reaching consequences for the economy.Read moreRead less
Brønsted Acid Activated Chiral Brønsted Bases: Catalysts for Enantioselective Photochemical and Aminyl Radical Reactions. In coming years the Australian pharmaceutical industry will face unprecedented challenges regarding the generation of wealth in an environmentally sustainable fashion. This proposal aims to address these issues through the development of a range of organocatalytic methods, which will provide access to valuable materials in a sustainable manner. While the new technologies deri ....Brønsted Acid Activated Chiral Brønsted Bases: Catalysts for Enantioselective Photochemical and Aminyl Radical Reactions. In coming years the Australian pharmaceutical industry will face unprecedented challenges regarding the generation of wealth in an environmentally sustainable fashion. This proposal aims to address these issues through the development of a range of organocatalytic methods, which will provide access to valuable materials in a sustainable manner. While the new technologies derived from these studies will deliver general benefits in the area of chemical synthesis, more localised benefits will be achieved through the synthesis of the biologically significant Grandisine natural products, which have a possible role in the management of chronic pain.Read moreRead less
Novel Metal Carbide Catalysts For Gas-To-Liquid Conversion Processes. The development of efficient gas-to-liquid fuels processes is driven by the availability of abundant natural gas reserves and environmental advantages of synthetic liquid fuels. In this study, a new molybdenum-tungsten carbide catalyst that with excellent performance but 80 times cheaper than noble metal catalysts is proposed. It is especially attractive for industrial applications because it can be used for steam reforming of ....Novel Metal Carbide Catalysts For Gas-To-Liquid Conversion Processes. The development of efficient gas-to-liquid fuels processes is driven by the availability of abundant natural gas reserves and environmental advantages of synthetic liquid fuels. In this study, a new molybdenum-tungsten carbide catalyst that with excellent performance but 80 times cheaper than noble metal catalysts is proposed. It is especially attractive for industrial applications because it can be used for steam reforming of natural gas to synthesis gas, and subsequent conversion to gasoline. This represents huge cost savings in catalyst and energetically-efficient reactors in the global petrochemical industry where millions of dollars are spent annually on catalyst improvement and rehabilitation.Read moreRead less
Carbon dioxide conversion over nanostructured mixed metal catalysts. Nanocatalysts are particles of very small size that have the ability to accelerate chemical reactions. This project will develop nanocatalysts to convert carbon dioxide into other small molecules to provide new options for managing greenhouse gas emissions.