Reactivity of Carbon-Carbon Composites. This project investigates the reactivity of pitch-coke carbon composites with the aim of minimising oxidative carbon loss from anodes during aluminium smelting. Such carbon loss accounts for about 15 percent of the total carbon consumption in smelting, and its reduction will provide considerable economic benefit besides contributing to mitigation of greenhouse gas emission. In the present project the effect of coke calcination and composite baking temper ....Reactivity of Carbon-Carbon Composites. This project investigates the reactivity of pitch-coke carbon composites with the aim of minimising oxidative carbon loss from anodes during aluminium smelting. Such carbon loss accounts for about 15 percent of the total carbon consumption in smelting, and its reduction will provide considerable economic benefit besides contributing to mitigation of greenhouse gas emission. In the present project the effect of coke calcination and composite baking temperatures on the relationship between anode microstructure and reactivity in oxygen as well as carbon dioxide will be investigated, and optimum process conditions determined for minimum reactive carbon loss during smelting.Read moreRead less
Homogeneous Combustion Catalysts for Efficiency Improvements and Emission Reduction in Diesel Engines. Australia currently consumes about 25 billion litres of diesel annually through the mining industry, road transportation and electricity generation for remote communities which presentins a significant cost and carbon footprint. A small reduction of say 2.5% in diesel consumption nationwide by improving engine performance and energy efficiency can result in more than $0.5 billion in savings and ....Homogeneous Combustion Catalysts for Efficiency Improvements and Emission Reduction in Diesel Engines. Australia currently consumes about 25 billion litres of diesel annually through the mining industry, road transportation and electricity generation for remote communities which presentins a significant cost and carbon footprint. A small reduction of say 2.5% in diesel consumption nationwide by improving engine performance and energy efficiency can result in more than $0.5 billion in savings and a reduction of 1.75 million tonnes in greenhouse gas emission annually. The homogeneous combustion catalysts, to be developed in this research for direct doping into diesel supply system, will help realise these objectives and contribute to the development of an environmentally sustainable Australia.Read moreRead less
Process Systems for Distributed Chemical Manufacturing. This Project investigates a new paradigm for chemicals production, moving away from large-scale centralised plant to distributed manufacture in relatively small localised facilities. The Project is built on the conjunction of a revolutionary process systems synthesis methodology with a new approach to highly compact equipment manufacture. The Project is of great significance to developing countries and to smaller, remote economies such as A ....Process Systems for Distributed Chemical Manufacturing. This Project investigates a new paradigm for chemicals production, moving away from large-scale centralised plant to distributed manufacture in relatively small localised facilities. The Project is built on the conjunction of a revolutionary process systems synthesis methodology with a new approach to highly compact equipment manufacture. The Project is of great significance to developing countries and to smaller, remote economies such as Australia's, which cannot justify or compete with world-scale production facilities. We will develop our ideas in a case study and identify routes to practical implementation of this example in particular and of the new approach in general.Read moreRead less
Understanding the reactivity of pulverised coal at extreme conditions when injected into blast furnaces during PCI. This study aims to improve the understanding and develop a mathematical model of coal combustion during injection into blast furnaces as PCI (pulverised coal injection). The principle economic and social benefits of this project to the community are: (i) Increased efficiency of Blast Furnace operations, resulting in cheaper production of iron in an increasingly globally competitive ....Understanding the reactivity of pulverised coal at extreme conditions when injected into blast furnaces during PCI. This study aims to improve the understanding and develop a mathematical model of coal combustion during injection into blast furnaces as PCI (pulverised coal injection). The principle economic and social benefits of this project to the community are: (i) Increased efficiency of Blast Furnace operations, resulting in cheaper production of iron in an increasingly globally competitive industry, supporting the Australian steel industry and domestic market. And (ii) the potential to impact on process fuel efficiency and reduce CO2 emissions from fossil fuel sources providing a cleaner source of iron for steel production.Read moreRead less
Mechanisms of Ammonium Nitrate Decomposition and Stability of Industrial Explosives in Reactive Mining Grounds. This project is designed to probe reaction mechanisms of ammonium nitrate based explosives with pyritic shales commonly found in overburdens of mineral deposits, and to study the influence of various factors, such as mineralogical characteristics, carbonaceous materials, weathering, pH values and application of various inhibition agents, on the decomposition and stability of ammonium n ....Mechanisms of Ammonium Nitrate Decomposition and Stability of Industrial Explosives in Reactive Mining Grounds. This project is designed to probe reaction mechanisms of ammonium nitrate based explosives with pyritic shales commonly found in overburdens of mineral deposits, and to study the influence of various factors, such as mineralogical characteristics, carbonaceous materials, weathering, pH values and application of various inhibition agents, on the decomposition and stability of ammonium nitrate. Ammonium nitrate crystallisation, which significantly reduces the stability of emulsion explosives, will be examined using both chemical and microscopic tools. The outcomes of this research will provide a scientific basis that underpins the development of safe and cost-effective explosives for applications in dangerous reactive mining grounds.Read moreRead less
Selective generation of hydrogen from biomass and waste fuels. Biomass fuels account for 14% of global energy supply. This is likely to increase in future as the population increases, energy demand rises, cheap oil and coal reserves are depleted, and the effects of global warming become more readily visible. In Australia the development of a sustainable hydrogen economy is a national priority. The hydrogen economy could bring about improved energy security, substantially reduced greenhouse gas e ....Selective generation of hydrogen from biomass and waste fuels. Biomass fuels account for 14% of global energy supply. This is likely to increase in future as the population increases, energy demand rises, cheap oil and coal reserves are depleted, and the effects of global warming become more readily visible. In Australia the development of a sustainable hydrogen economy is a national priority. The hydrogen economy could bring about improved energy security, substantially reduced greenhouse gas emissions, improved energy efficiency and improved air quality. This proposal directly addresses this challenge by investigating the science underpinning a large-scale sustainable hydrogen synthesis process using biomass and waste fuels. Read moreRead less
Modelling of Nitric Oxides and Carbon Monoxide Emissions from Bagasse-Fires Boilers. The project aims to develop computational models to predict emissions of nitric oxides and carbon monoxide from sugar-mill boilers burning bagasse. Bagasse combustion does not contribute to greenhouse gas emissions and clean and efficient combustion of this fuel has become very important for the sugar industry and for Australia. The project combines the opportunity of direct boiler measurements by SRI with the m ....Modelling of Nitric Oxides and Carbon Monoxide Emissions from Bagasse-Fires Boilers. The project aims to develop computational models to predict emissions of nitric oxides and carbon monoxide from sugar-mill boilers burning bagasse. Bagasse combustion does not contribute to greenhouse gas emissions and clean and efficient combustion of this fuel has become very important for the sugar industry and for Australia. The project combines the opportunity of direct boiler measurements by SRI with the modelling expertise at the University to develop combustion-kinetics models for these species. The models will be incorporated into the previously developed computational fluid dynamics - combustion code of the furnace to give the capability of emission prediction as a function of burner operating conditions and fuel parameters.Read moreRead less
The Effects of Pyrolysis Conditions on Combustion and Gasification Reactivities of Biomass Chars and the Quality of Their Ash. Considerable efforts are being made to minimise the environmental impacts of fossil fuels by utilising renewable energy sources like biomass. Many of the challenges associated with the thermal conversion of biomass relate to its char characteristics. The aim of this project is to gain a fundamental understanding about the impact of reaction conditions during the pyrolyti ....The Effects of Pyrolysis Conditions on Combustion and Gasification Reactivities of Biomass Chars and the Quality of Their Ash. Considerable efforts are being made to minimise the environmental impacts of fossil fuels by utilising renewable energy sources like biomass. Many of the challenges associated with the thermal conversion of biomass relate to its char characteristics. The aim of this project is to gain a fundamental understanding about the impact of reaction conditions during the pyrolytic stage on the structural and compositional transformations of the resultant char, its combustion and gasification reactivities, and the release of inorganic matter and ash formation. This holistic and integrated approach should reveal the underlying science necessary to support existing and future biomass use.Read moreRead less
Study of hydrocarbon flames under heat and gas recirculation conditions. This project aims to study gaseous flames under heat and gas recirculation conditions. This technology has been proven to reduce fuel consumption, improve thermal efficiency and substantially reduce nitric oxides emission. The effect of mixing, turbulence and temperature on the structure and stability of these flames will be investigated. The project combines experimental and computational research applied to a laboratory s ....Study of hydrocarbon flames under heat and gas recirculation conditions. This project aims to study gaseous flames under heat and gas recirculation conditions. This technology has been proven to reduce fuel consumption, improve thermal efficiency and substantially reduce nitric oxides emission. The effect of mixing, turbulence and temperature on the structure and stability of these flames will be investigated. The project combines experimental and computational research applied to a laboratory scale burner and a small scale furnace. The main objectives are to better understand the chemical pathways in low temperature hydrocarbon flames under heat and gas recirculation conditions and to understand the effect of mixing and turbulence on the flame structure and pollutants emission.Read moreRead less
A Comprehensive Kinetic Model for Sulfur Reactions in Combustion, Gasification, and Chemical Processing. Sulfur chemistry in high temperature processes is poorly understood, leading to uncertainties in the design of these processes and in the control of their emissions. In particular, new approaches to lowering greenhouse emissions which depend on the combustion and gasification of coal, biomass, or refuse-derived fuel, such as integrated gasification combined cycle processes, are especially aff ....A Comprehensive Kinetic Model for Sulfur Reactions in Combustion, Gasification, and Chemical Processing. Sulfur chemistry in high temperature processes is poorly understood, leading to uncertainties in the design of these processes and in the control of their emissions. In particular, new approaches to lowering greenhouse emissions which depend on the combustion and gasification of coal, biomass, or refuse-derived fuel, such as integrated gasification combined cycle processes, are especially affected by these uncertainties. This project seeks to combine experimental measurements and quantum chemical modelling to produce a detailed mechanistic model for the reactions of sulfur in high-temperature systems. Such a model will provide designers with a tool to optimise these complex interacting systems.Read moreRead less