Development of a Novel One Step Process for Gas Conversion to Liquid. Australia has a rich natural gas reserve, most of which is in remote locations. This project will lead to a new technology to use the remote gas that would be flared into the atmosphere, thus benefiting both Australian economy and green house gas reduction. It will also reduce the risk of relying on importing oil from Overseas thus contributing to Australia's energy security. In addition, while crude-based oil emits SOx, NOx a ....Development of a Novel One Step Process for Gas Conversion to Liquid. Australia has a rich natural gas reserve, most of which is in remote locations. This project will lead to a new technology to use the remote gas that would be flared into the atmosphere, thus benefiting both Australian economy and green house gas reduction. It will also reduce the risk of relying on importing oil from Overseas thus contributing to Australia's energy security. In addition, while crude-based oil emits SOx, NOx and particulates etc into air, the liquid fuels from gas are pure and burns cleanly thus also contributing to air pollution control. Read moreRead less
Supercritical Highly-Integrated and Modular, Continuous Solid-Catalysed Biodiesel Production from Plant and Animal Feedstocks. We propose to revolutionise biodiesel production by creating a new reactor type and associated process that allows the production of 160,000 tonnes of biodiesel a year in a supercritical reactor volume of one cubic metre after scale-up. In this project, we propose to design the appropriate catalysts and pilot plant to study our ideas which should lead to a highly effici ....Supercritical Highly-Integrated and Modular, Continuous Solid-Catalysed Biodiesel Production from Plant and Animal Feedstocks. We propose to revolutionise biodiesel production by creating a new reactor type and associated process that allows the production of 160,000 tonnes of biodiesel a year in a supercritical reactor volume of one cubic metre after scale-up. In this project, we propose to design the appropriate catalysts and pilot plant to study our ideas which should lead to a highly efficient and sustainable system that offers a real alternative to current mineral oil-based technologies.Read moreRead less
Novel Metal Carbide Catalysts For Gas-To-Liquid Conversion Processes. The development of efficient gas-to-liquid fuels processes is driven by the availability of abundant natural gas reserves and environmental advantages of synthetic liquid fuels. In this study, a new molybdenum-tungsten carbide catalyst that with excellent performance but 80 times cheaper than noble metal catalysts is proposed. It is especially attractive for industrial applications because it can be used for steam reforming of ....Novel Metal Carbide Catalysts For Gas-To-Liquid Conversion Processes. The development of efficient gas-to-liquid fuels processes is driven by the availability of abundant natural gas reserves and environmental advantages of synthetic liquid fuels. In this study, a new molybdenum-tungsten carbide catalyst that with excellent performance but 80 times cheaper than noble metal catalysts is proposed. It is especially attractive for industrial applications because it can be used for steam reforming of natural gas to synthesis gas, and subsequent conversion to gasoline. This represents huge cost savings in catalyst and energetically-efficient reactors in the global petrochemical industry where millions of dollars are spent annually on catalyst improvement and rehabilitation.Read moreRead less
Gas-phase and catalytic reaction of halons under reducing conditions. Halons are ozone-depleting substances, but their use continues in most countries. This project pursues techniques to convert, rather than destroy, halons into benign and useful products. The aims of this project are to gain a fundamental understanding of the reactions of the most commonly used halons, 1301, 1211 and 2402, and perform a detailed examination of catalytic processes for conversion of halons to HFCs. The primary ....Gas-phase and catalytic reaction of halons under reducing conditions. Halons are ozone-depleting substances, but their use continues in most countries. This project pursues techniques to convert, rather than destroy, halons into benign and useful products. The aims of this project are to gain a fundamental understanding of the reactions of the most commonly used halons, 1301, 1211 and 2402, and perform a detailed examination of catalytic processes for conversion of halons to HFCs. The primary outcome from the study will be the development of a process specifically designed to convert halons into useful products. This will assist with efforts to phase out continued halon use.Read moreRead less
Unsteady-State Operation of Slurry and Fixed-Bed Fischer-Tropsch Reactors for Improved Process Performance. The development of efficient gas-to-liquid processes via the Fischer-Tropsch reaction is the most economically viable route for the production of non-petroleum based chemicals and environmentally-friendly fuels from abundant natural gas. This investigation proposes the exploitation of both reactor and catalyst dynamics behaviour to obtain higher hydrocarbon synthesis rate and selectivity n ....Unsteady-State Operation of Slurry and Fixed-Bed Fischer-Tropsch Reactors for Improved Process Performance. The development of efficient gas-to-liquid processes via the Fischer-Tropsch reaction is the most economically viable route for the production of non-petroleum based chemicals and environmentally-friendly fuels from abundant natural gas. This investigation proposes the exploitation of both reactor and catalyst dynamics behaviour to obtain higher hydrocarbon synthesis rate and selectivity not attainable under conventional steady-state operation. With current market conditions of about US$30/bbl for crude oil, even modest process improvements of 30-60% will make the process competitive. Whilst individual national energy policy goals are promoted, the research will further strengthen closer economic and technology ties between France and Australia.Read moreRead less
Plasma-Catalytist Hybrid Process for Simultaneous Removal of NOx and SOx. Coal combustion provides over 80% of the electricity produced in Australia, with the power stations being major emitters of the pollutants NOx and SOx. This project will potentially lead to a new technology to simultaneously remove NOx and SOx in a single and economical process, eliminating the secondary waste streams that disadvantage current competing technologies. This will provide: significant environmental benefits f ....Plasma-Catalytist Hybrid Process for Simultaneous Removal of NOx and SOx. Coal combustion provides over 80% of the electricity produced in Australia, with the power stations being major emitters of the pollutants NOx and SOx. This project will potentially lead to a new technology to simultaneously remove NOx and SOx in a single and economical process, eliminating the secondary waste streams that disadvantage current competing technologies. This will provide: significant environmental benefits for Australia in reducing these dangerous atmospheric pollutants; economic advantage to our power stations by enabling cheaper, more efficient technologies and consolidate Australia's leading position in the world in air pollution control. Read moreRead less
Hydrogen Production by Non-thermal Plasma Assisted Catalytic Pyrolysis of Natural Gas. This project aims to develop a cost effective technology for hydrogen production using catalytic pyrolysis of natural gas assisted by non-thermal plasma. The mechanism and kinetics of catalytic hydrocarbon decomposition on carbons produced in situ will be systematically studied. Based on the fundamental understanding of carbon nanostructures and their catalytic activities and stabilities, the non-thermal plasm ....Hydrogen Production by Non-thermal Plasma Assisted Catalytic Pyrolysis of Natural Gas. This project aims to develop a cost effective technology for hydrogen production using catalytic pyrolysis of natural gas assisted by non-thermal plasma. The mechanism and kinetics of catalytic hydrocarbon decomposition on carbons produced in situ will be systematically studied. Based on the fundamental understanding of carbon nanostructures and their catalytic activities and stabilities, the non-thermal plasma and the catalytic reactions will be optimized to achieve high conversion and catalytic stability. The project will lead to a new process combining effective carbon catalyst and low temperature plasma to produce pure hydrogen with high energy efficiency and no CO2 emissions.Read moreRead less
Transformation of halons and CFC to valuable products through their reaction with methane. Halons and CFCs are well known as ozone depleting substances (ODS). This project pursues the development of a novel process to transform stockpiles of halons and CFCs into vinylidene difluoride (C2H2F2). Vinylidene difluoride is a highly valued commodity, used in the synthesis of heat resistant materials. The primary aim of this research is to gain understanding of the role of catalysts during conversion o ....Transformation of halons and CFC to valuable products through their reaction with methane. Halons and CFCs are well known as ozone depleting substances (ODS). This project pursues the development of a novel process to transform stockpiles of halons and CFCs into vinylidene difluoride (C2H2F2). Vinylidene difluoride is a highly valued commodity, used in the synthesis of heat resistant materials. The primary aim of this research is to gain understanding of the role of catalysts during conversion of CFC 12 and halon 1211 into the desired reaction product. The signifigance of the project is that it will facilitate development of a process for non-destructive treatment of ozone depleting substances. The major outcome of the proposed research is it will lay the technical foundation for the development of an energy efficient process to convert rather than destroy these ODS.Read moreRead less