CCC method: new applications to electron scattering from atoms and molecules. Achievement of the stated aims will be of enormous benefit to industry
and laboratory research because at the present time no reliably accurate
models exist for the range of the required scattering parameters. The
modelling work will result in development of new software packages for
supercomputers and will provide training for research associates, PhD
and Honours students in an area where Australian theorists are ....CCC method: new applications to electron scattering from atoms and molecules. Achievement of the stated aims will be of enormous benefit to industry
and laboratory research because at the present time no reliably accurate
models exist for the range of the required scattering parameters. The
modelling work will result in development of new software packages for
supercomputers and will provide training for research associates, PhD
and Honours students in an area where Australian theorists are
preeminent.Read moreRead less
Atomic tests of unification theories. Although the standard model of particle physics has withstood decades of intensive experimental tests, it is widely believed to be merely a low-energy manifestation of a "true" theory that unifies the four forces of nature. While some searches for new physics beyond the standard model are performed at high-energy particle accelerators, a very sensitive probe can be done at low energies in atomic and molecular measurements of weak interaction effects. This pr ....Atomic tests of unification theories. Although the standard model of particle physics has withstood decades of intensive experimental tests, it is widely believed to be merely a low-energy manifestation of a "true" theory that unifies the four forces of nature. While some searches for new physics beyond the standard model are performed at high-energy particle accelerators, a very sensitive probe can be done at low energies in atomic and molecular measurements of weak interaction effects. This project is devoted to a theoretical investigation of weak interaction effects in atoms, molecules, and nuclei. It will provide improved tests of unified theories.Read moreRead less
Reaction transition states of halide-cluster complexes via velocity-map imaging of photoelectrons. This study will investigate the transition point between the reactants and products of a chemical reaction using a novel photoelectron imaging technique, velocity-map imaging. It is this region of chemical reactions that is the least understood. By combining the use of weakly bound negatively charged clusters and laser photodetachment of these clusters, information can be gleaned about these transi ....Reaction transition states of halide-cluster complexes via velocity-map imaging of photoelectrons. This study will investigate the transition point between the reactants and products of a chemical reaction using a novel photoelectron imaging technique, velocity-map imaging. It is this region of chemical reactions that is the least understood. By combining the use of weakly bound negatively charged clusters and laser photodetachment of these clusters, information can be gleaned about these transition states. The technique will be applied to an important class of halide-cluster complexes that form a set of prototypical reactions. These species also play important roles ranging from ozone depletion through to industrial chemistry.Read moreRead less
Uncovering highly excited states of quantum three body systems using new technological approaches. Experimental studies of the fundamental structure of quantum three body systems are proposed to uncover long-lived highly-excited states. Ultra-fast timing technology applied to a variant of electron time-of-flight studies will form the basis of the measurement system to be used at a world-class synchrotron light source.
Roaming around the Transition State: A New Mechanism of Chemical Reactions. Gas-phase reaction mechanisms are at the core of some of the most important problems facing Australia at present: atmospheric models for CO2 are central to climate change; models of isotope exchange are essential to learn about past climates from Antarctic ice cores; and models of combustion are used to optimise energy efficiency. The mechanisms used in these models rely on accurate chemistry. A newly discovered chemica ....Roaming around the Transition State: A New Mechanism of Chemical Reactions. Gas-phase reaction mechanisms are at the core of some of the most important problems facing Australia at present: atmospheric models for CO2 are central to climate change; models of isotope exchange are essential to learn about past climates from Antarctic ice cores; and models of combustion are used to optimise energy efficiency. The mechanisms used in these models rely on accurate chemistry. A newly discovered chemical mechanism has the potential to change many of the reactions that we currently use in these chemical models. This project will determine how important this new mechanism is, and what its impact is on gas-phase reaction models.Read moreRead less
The New Atom Laser: Theory of Quantum Atom Optical Sources. The atom laser is a new device which produces a coherent source of ultracold atoms. A practical atom laser will be a revolutionary source for atom optics. This project will develop a comprehensive and practical quantum theory of a new generation of atom lasers which can produce a continuous beam. This will require a different and more complicated theoretical approach to that which worked for optical lasers, but the result will be a d ....The New Atom Laser: Theory of Quantum Atom Optical Sources. The atom laser is a new device which produces a coherent source of ultracold atoms. A practical atom laser will be a revolutionary source for atom optics. This project will develop a comprehensive and practical quantum theory of a new generation of atom lasers which can produce a continuous beam. This will require a different and more complicated theoretical approach to that which worked for optical lasers, but the result will be a device with a spectral flux which is orders of magnitude better than the current state of the art.Read moreRead less
Electron correlation models using morph operators and hybrid intracules. A new solution to the central problem in quantum chemistry will allow researchers in the chemical, pharmaceutical and materials sciences to predict the chemical behaviour of moderately large molecular systems with an accuracy and efficiency that has not previously been possible. The software that will result will enable cost and time savings in the design of advanced materials in the medical and agricultural contexts.
Quantum magnetometry on the microscale. This proposal will create a microscope for magnetic fields by measuring the quantum spin of a Bose-Einstein condensate at temperatures near absolute zero. Classical measurements of spin have underpinned transforming technologies, from magnetic resonance imaging to terabyte-scale hard-disc storage. We will make a truly quantum measurement of spin which will create a magnetic field microscope one million times more sensitive than the current state-of-the-art ....Quantum magnetometry on the microscale. This proposal will create a microscope for magnetic fields by measuring the quantum spin of a Bose-Einstein condensate at temperatures near absolute zero. Classical measurements of spin have underpinned transforming technologies, from magnetic resonance imaging to terabyte-scale hard-disc storage. We will make a truly quantum measurement of spin which will create a magnetic field microscope one million times more sensitive than the current state-of-the-art. The magnetic field microscope will be sensitive enough to measure fields from single biological cells and from superconducting nanosurfaces, giving critical new perspectives in biomedical research and next-generation electronics.Read moreRead less
Superfluid helium nanodroplet spectroscopy. Molecules trapped in a helium nanodroplet find themselves in an ultracold liquid environment from which they cannot escape. As such, the molecules are forced to interact and this is studied at a resolution that is unrivaled in condensed phase spectroscopy. This technique will be used to create new materials and study the dynamics behind a large range of chemical processes. The results are expected to lead to a greater understanding of condensed phase c ....Superfluid helium nanodroplet spectroscopy. Molecules trapped in a helium nanodroplet find themselves in an ultracold liquid environment from which they cannot escape. As such, the molecules are forced to interact and this is studied at a resolution that is unrivaled in condensed phase spectroscopy. This technique will be used to create new materials and study the dynamics behind a large range of chemical processes. The results are expected to lead to a greater understanding of condensed phase chemistry and chemical reactions in general.Read moreRead less
The first critical tests of many-body and correlated Quantum Electro-Dynamics (QED) in medium-Z atomic systems. Major difficulties are being encountered in the computation of high-order and correlated terms of Quantum Electro-Dynamical effects in atoms. We will make the first measurements for medium-Z atoms critically sensitive to two-electron QED, and the first tests of QED in this region accurate to 1%. This accuracy will allow new insight into two-electron systems, theoretical approaches, and ....The first critical tests of many-body and correlated Quantum Electro-Dynamics (QED) in medium-Z atomic systems. Major difficulties are being encountered in the computation of high-order and correlated terms of Quantum Electro-Dynamical effects in atoms. We will make the first measurements for medium-Z atoms critically sensitive to two-electron QED, and the first tests of QED in this region accurate to 1%. This accuracy will allow new insight into two-electron systems, theoretical approaches, and recent observed discrepancies between QED theory and experiment. This proposal follows recent successful experimental work using new capabilities of Electron-Beam Ion Traps (EBITs). Our recent publications have proven that this novel approach can yield new insight into the interaction of light with matter.Read moreRead less