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Linkage Infrastructure, Equipment And Facilities - Grant ID: LE130100061
Funder
Australian Research Council
Funding Amount
$710,000.00
Summary
Extending frontiers of structural chemistry and biology through high resolution pulsed Electron Paramagnetic Resonance. Multifrequency high resolution pulsed Electron Paramagnetic Resonance (EPR) instrumentation will provide forefront technologies in identifying, characterising, quantifying and visualising free radicals and metal ions that are involved in fundamental chemical and biological processes in science and nature.
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE170100144
Funder
Australian Research Council
Funding Amount
$480,000.00
Summary
Advanced X-ray facility for structural elucidation and photocrystallography. This project aims to establish an advanced photocrystallography X-ray facility. Accurately determining molecular structure and understanding how molecules interact with light is important to design and optimise new materials. Normally, measurements to elucidate these properties have to be done separately, making structure-property correlations difficult. The facility will allow the creation of new materials with applica ....Advanced X-ray facility for structural elucidation and photocrystallography. This project aims to establish an advanced photocrystallography X-ray facility. Accurately determining molecular structure and understanding how molecules interact with light is important to design and optimise new materials. Normally, measurements to elucidate these properties have to be done separately, making structure-property correlations difficult. The facility will allow the creation of new materials with application in pharmaceuticals, separation science, organic optoelectronics and magnetic materials. The facility will build capacity in X-ray techniques, create collaborations and provide a unique training ground for students and Early Career Researchers. The advances in materials innovation will strengthen the future viability of Australian industries and manufacturing innovation.Read moreRead less
Novel Nanomaterials for Photocatalytic Water Purification - Science and Application. Water is rapidly becoming Australia's most critical natural resource, and there is an urgent need to re-use and recycle water from domestic use (graywater) and industry, as well as utilisation of larger scale harvesting of rainwater. The outcome of this project will be a technology which can remove organic material (biological and non-biological) from water, enabling a greater range of uses of wastewater. This ....Novel Nanomaterials for Photocatalytic Water Purification - Science and Application. Water is rapidly becoming Australia's most critical natural resource, and there is an urgent need to re-use and recycle water from domestic use (graywater) and industry, as well as utilisation of larger scale harvesting of rainwater. The outcome of this project will be a technology which can remove organic material (biological and non-biological) from water, enabling a greater range of uses of wastewater. This technology will play a significant role in delivering future water security, and developing new industries involved in manufacture and export of water treatment technologies. This project directly addresses the National Priority Research area of water, and international priorities involving greater re-use and recycling of water.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE190101450
Funder
Australian Research Council
Funding Amount
$392,556.00
Summary
Tuning non-plasmonic metals to high performance photocatalysts. This project aims to develop non-plasmonic, transition metal-based, photocatalysts with enhanced light absorption, to achieve irradiation controllable product selectivity in organic synthesis. The project demonstrates how hollow-particle morphology alloy nano-structures can enhance photocatalytic activity. Alloy structures such as iridium-nickel (IrNi), iridium-cobalt (IrCo) and iridium-tin (IrSn) nanoparticles with a hollow morphol ....Tuning non-plasmonic metals to high performance photocatalysts. This project aims to develop non-plasmonic, transition metal-based, photocatalysts with enhanced light absorption, to achieve irradiation controllable product selectivity in organic synthesis. The project demonstrates how hollow-particle morphology alloy nano-structures can enhance photocatalytic activity. Alloy structures such as iridium-nickel (IrNi), iridium-cobalt (IrCo) and iridium-tin (IrSn) nanoparticles with a hollow morphology, exhibit dramatically increased photocatalytic activity over their individual components, Ir, Ni, Co and Sn respectively. The project is expected to expand the application of photocatalysis and generate knowledge that can be used to design efficient photocatalysts from non-plasmonic metals. Intended benefits are the generation of new knowledge and capabilities in synthetic catalysis and applications in fields such as the conversion of solar energy to chemical energy.Read moreRead less
Mobility of water in cartilage as a probe of molecular structure and function. Clinical diagnosis of early-stage osteoarthritis is difficult, and most patients are not diagnosed until a substantial degradation of cartilage has occurred as a result of the disease. This research will study the interaction between different components of articular cartilage and investigate, how this interaction can be exploited for the development of reliable and non-invasive techniques of cartilage imaging. Mobili ....Mobility of water in cartilage as a probe of molecular structure and function. Clinical diagnosis of early-stage osteoarthritis is difficult, and most patients are not diagnosed until a substantial degradation of cartilage has occurred as a result of the disease. This research will study the interaction between different components of articular cartilage and investigate, how this interaction can be exploited for the development of reliable and non-invasive techniques of cartilage imaging. Mobility of water molecules is a potent indicator of the microscopic structure of the cartilage scaffold. We will use this fundamental biophysical relationship to measure the internal architecture of collagen fibres; observe the changes effected by mechanical load; and distinguish between healthy and osteoarthritic cartilage.
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Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0775590
Funder
Australian Research Council
Funding Amount
$200,000.00
Summary
A single crystal X-ray diffractometer with CCD detector for structural analysis of small molecules. In recent years their have been major advances in the capacity of instrumentation to determine the crystal and molecular structure of chemical compounds and materials which in turn has resulted in a rapidly growing understanding of the relationship between the structure of molecules and their function in the design of new materials and as drugs for the treatment of disease and pain. This infrastr ....A single crystal X-ray diffractometer with CCD detector for structural analysis of small molecules. In recent years their have been major advances in the capacity of instrumentation to determine the crystal and molecular structure of chemical compounds and materials which in turn has resulted in a rapidly growing understanding of the relationship between the structure of molecules and their function in the design of new materials and as drugs for the treatment of disease and pain. This infrastructure also provides training of an international standard for undergraduate and post graduate students, thus building the skills capabilities of Australian scientists in the workforce.Read moreRead less
Carbon-based electrode materials for electrochemical energy storage and water desalination. Clean energy and water resource are two critical issues for an environmentally sustainable Australia. The research project will lead to the discovery of innovative carbon-based electrode materials with well-designed physical and chemical properties for clean energy storage and alternative water desalination technology.
Surface modification of semiconducting organic charge transfer complexes with metal nanoparticles to create a new class of multifunctional materials. This project aims to deliver a facile and cheap method to produce a class of nanostructured composite materials to be used in applications which will have environmental and social benefits such as photocatalyst development for water purification, biosensing and the creation of antibacterial fabrics to prevent the spread of infection.
Modifying Structure and Properties of Carbon Nanotubes for Device Applications (MWN). The focus of this project is to develop new heteroatom-doped carbon nanotube materials for use in conjugated-polymer composite photovoltaic cells. Synthesis of boron and of nitrogen doped carbon nanotubes (CNTs) by the US researchers will be complemented by ion-implantation post-synthesis of CNTs by the Australian team, to gain a thorough and detailed understanding of how the CNTs can act effectively as both an ....Modifying Structure and Properties of Carbon Nanotubes for Device Applications (MWN). The focus of this project is to develop new heteroatom-doped carbon nanotube materials for use in conjugated-polymer composite photovoltaic cells. Synthesis of boron and of nitrogen doped carbon nanotubes (CNTs) by the US researchers will be complemented by ion-implantation post-synthesis of CNTs by the Australian team, to gain a thorough and detailed understanding of how the CNTs can act effectively as both an electron acceptor and charge transport medium in a conjugated polymer. Outcomes will include fundamental advances in our understanding of charge transport in the composite devices and prototype organic photovoltaic devices of improved efficiency.Read moreRead less
The photons take charge: Elucidating the structure and stability of distonic radical anions by mass spectrometry and photoelectron spectroscopy. Recent work has discovered that certain radical anions have electronic configurations that defy chemical convention and exhibit exceptional radical stability. Exploitation of this breakthrough first requires experimental elucidation of the intrinsic electronic structure of these compounds and how it relates to their remarkable properties. This project w ....The photons take charge: Elucidating the structure and stability of distonic radical anions by mass spectrometry and photoelectron spectroscopy. Recent work has discovered that certain radical anions have electronic configurations that defy chemical convention and exhibit exceptional radical stability. Exploitation of this breakthrough first requires experimental elucidation of the intrinsic electronic structure of these compounds and how it relates to their remarkable properties. This project will probe the fundamental structure and energetics of radical anions by modifying instrumentation to enable multi-step gas-phase ion synthesis to be efficiently coupled with anion photoelectron spectroscopy. These investigations are essential to revealing the scope of this phenomenon in free radical chemistry and biology and could inform future development of new catalysts for polymerisation.Read moreRead less