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Synthetic and theoretical studies of metal complexes containing carbon-rich ligands. Previous studies in my group, in conjunction with synthetic and theoretical chemistry groups at the Université de Rennes 1, France, have delineated the properties of a series of complexes containing carbon chains linking two metal centres. Having achieved a partial understanding of the features which result in good electronic communication between the metal centres via the carbon chain, the present proposal see ....Synthetic and theoretical studies of metal complexes containing carbon-rich ligands. Previous studies in my group, in conjunction with synthetic and theoretical chemistry groups at the Université de Rennes 1, France, have delineated the properties of a series of complexes containing carbon chains linking two metal centres. Having achieved a partial understanding of the features which result in good electronic communication between the metal centres via the carbon chain, the present proposal seeks to extend this collaboration to further studies which will generate related compounds in which actual eletron exchange can occur, i.e. leading to oxidation/reduction, by using compounds in which two or more different metal centres are present. This may lead to development of nano devices, e.g. molecular-scale switches. If one of the centres is activated by light, a photo-active sensor may result.Read moreRead less
Synthesis of substrate analogues for probing catalytic mechanisms and specificity of enzymes involved in the metabolism of plant polysaccharides. The project is aimed at strengthening collaborations between research groups in Adelaide and France, with the specific objective of synthesizing substrate analogues as probes of enzymatic mechanisms and substrate specificity in polysaccharide hydrolases and synthases of barley. The chemical expertise resides in France, while the enzymatic work will be ....Synthesis of substrate analogues for probing catalytic mechanisms and specificity of enzymes involved in the metabolism of plant polysaccharides. The project is aimed at strengthening collaborations between research groups in Adelaide and France, with the specific objective of synthesizing substrate analogues as probes of enzymatic mechanisms and substrate specificity in polysaccharide hydrolases and synthases of barley. The chemical expertise resides in France, while the enzymatic work will be conducted largely in Australia. Exchange of research staff, particularly at the postgraduate student and research associate levels, is considered essential to capture the benefits of the complementary expertise and to extend an existing international collaboration. The target enzymes are of central importance in cell wall metabolism during development of higher plants.Read moreRead less
Laboratory and Field Testing of a Leak Detection Technique Using Fluid Transients. A major problem in fluid pipelines and pipe networks is undetected leakage. This research collaboration will develop new approaches that will enable systematic leak detection using advanced numerical modelling and inverse techniques with the ultimate goal of implementing these leak detection methods in practice. In addition to the numerical model development, an extensive series of laboratory experiments will be u ....Laboratory and Field Testing of a Leak Detection Technique Using Fluid Transients. A major problem in fluid pipelines and pipe networks is undetected leakage. This research collaboration will develop new approaches that will enable systematic leak detection using advanced numerical modelling and inverse techniques with the ultimate goal of implementing these leak detection methods in practice. In addition to the numerical model development, an extensive series of laboratory experiments will be undertaken by researchers from both universities using the laboratory facilities in Adelaide to verify and extend the new approaches. The researchers will conduct similar experiments under field conditions on much larger pipe systems in Toronto and generally in Canada.Read moreRead less
Simulation and verification of system-level specifications of requirements and constraints using Rosetta. Modern computer-based systems comprise a mixture of electronic hardware and embedded computer software that interacts with mechanical and other non-electrical subsystems. Future design capability will depend on being able to model the requirements and constraints of heterogeneous systems, so that they can be simulated and formally verified before being manufactured and deployed. This project ....Simulation and verification of system-level specifications of requirements and constraints using Rosetta. Modern computer-based systems comprise a mixture of electronic hardware and embedded computer software that interacts with mechanical and other non-electrical subsystems. Future design capability will depend on being able to model the requirements and constraints of heterogeneous systems, so that they can be simulated and formally verified before being manufactured and deployed. This project will develop techniques and software tools for simulation and verification based on the new Rosetta system-level design language. These tools will make the design of complex computer-based systems faster, more reliable and less costly by minimizing design errors early in the design flow.Read moreRead less
Displacement-based assessment of the seismic resistance of unreinforced masonry buildings. Earthquakes have caused over $1,000 billion of damage and more than 100,000 deaths in the last decade. This devastation occurred mainly in unreinforced brick masonry (URM) buildings which constitute the bulk of the domestic building stock in low seismicity regions, including Australia. These buildings were designed to resist forces, not the displacements, caused by earthquake ground shaking. This projec ....Displacement-based assessment of the seismic resistance of unreinforced masonry buildings. Earthquakes have caused over $1,000 billion of damage and more than 100,000 deaths in the last decade. This devastation occurred mainly in unreinforced brick masonry (URM) buildings which constitute the bulk of the domestic building stock in low seismicity regions, including Australia. These buildings were designed to resist forces, not the displacements, caused by earthquake ground shaking. This project will develop a new displacement-based method for assessing the earthquake resistance of URM buildings. Research outcomes will be in the form of improved analytical methods for the design of new buildings and the seismic assessment and retrofit of existing buildings.Read moreRead less
Influence of Spatial Variability on the Design and Performance of Pile Foundations. Currently, no model is available that incorporates the spatial variability of soil properties into the design and analysis of pile foundations. Furthermore, only basic rules-of-thumb are available to assist in determining the scope of appropriate site investigations for piles, and limited data are available for the LRFD of piles. The new and unique finite element model, site investigation guidelines and load re ....Influence of Spatial Variability on the Design and Performance of Pile Foundations. Currently, no model is available that incorporates the spatial variability of soil properties into the design and analysis of pile foundations. Furthermore, only basic rules-of-thumb are available to assist in determining the scope of appropriate site investigations for piles, and limited data are available for the LRFD of piles. The new and unique finite element model, site investigation guidelines and load resistance factors will reduce the over-design and uncertainty associated with pile design, which will lead to more reliable pile foundations and reduced construction cost overruns and delays. Conservatively, it is estimated that this research will result in savings in excess of $10 million per year, in Australia alone.Read moreRead less
Terahertz optoelectronics based on spintronics materials. Spintronic devices have many advantages which include non-volatility, permitting data retention in non-powered conditions, increased integration densities, high data processing speeds, low electrical energy demands, and a fabrication process compatible with those currently used in semiconductor microelectronics. The low energy consumption of spintronic devices also leads to economic and environmental benefits. Spintronic devices will help ....Terahertz optoelectronics based on spintronics materials. Spintronic devices have many advantages which include non-volatility, permitting data retention in non-powered conditions, increased integration densities, high data processing speeds, low electrical energy demands, and a fabrication process compatible with those currently used in semiconductor microelectronics. The low energy consumption of spintronic devices also leads to economic and environmental benefits. Spintronic devices will help to meet the sensing and storage demands of information technology in the decades to come. The project will enhance the international competitiveness and export power of Australian industry in the areas of information technology, quantum computing, magnetic recording and optoelectronics.Read moreRead less
Dehumidification and cooling driven by solar/waste heat using liquid desiccants. The provision of comfort cooling is responsible for a considerable and increasing portion of the world energy demand and electricity peak demand. To substitute electrically driven vapour compression machines with their high electrical energy consumption and especially high peak loads, the use of solar energy or waste heat for a cooling and dehumidification system driven by liquid desiccants is a promising opportunit ....Dehumidification and cooling driven by solar/waste heat using liquid desiccants. The provision of comfort cooling is responsible for a considerable and increasing portion of the world energy demand and electricity peak demand. To substitute electrically driven vapour compression machines with their high electrical energy consumption and especially high peak loads, the use of solar energy or waste heat for a cooling and dehumidification system driven by liquid desiccants is a promising opportunity. The project utilises the complementary strengths in the research groups to develop practical and economically feasible cooling/dehumidification systems for different types of buildings with different moisture removal and cooling requirements at different locations (Australia, Southern Europe).Read moreRead less
Studying Molecular Dynamics with Electron and Laser Interactions. We plan to use state-of-the-art experimental techniques and methodologies to probe the dynamics of molecular processes stimulated by either laser or electron interactions. These processes are fundamental to our understanding of both natural phenomena and many devices used in the technology of today and of the future. As a result of this study our insight into the mechanisms underpining these phenomena and devices will be enhanced.
The role of biological and chemical interactions in the rhizosphere in sustainable intercropping systems. Intercropping can result in large yield increases compared to mono-cropped systems. It is used extensively in China and could be an option for sustainable land-use in Australia. Belowground interactions between intercropped crop species may be important for the yield increase, but they are poorly understood, especially with regard to nutrient availability and soil biology. We will combine th ....The role of biological and chemical interactions in the rhizosphere in sustainable intercropping systems. Intercropping can result in large yield increases compared to mono-cropped systems. It is used extensively in China and could be an option for sustainable land-use in Australia. Belowground interactions between intercropped crop species may be important for the yield increase, but they are poorly understood, especially with regard to nutrient availability and soil biology. We will combine the field experience in intercropping systems of the Chinese scientists with the expertise of the Australian scientists in plant nutrition and rhizosphere ecology to characterise chemical and biological interactions in the rhizosphere governing nutrient availability and the competitive ability of intercropped species.Read moreRead less