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Polymer nanoobjects functionalized by polymer brushes: preparation, organization and integration in devices. The proposed project targets the collaboration between two leading research teams. The University of Marburg is leading in the area of the preparation of nanoobjects, while the research team at CAMD (UNSW) focuses on the preparation of well-controlled polymer structures via RAFT polymerisation. The combined strength of both groups seeks to improve the properties of nanodevices by the atta ....Polymer nanoobjects functionalized by polymer brushes: preparation, organization and integration in devices. The proposed project targets the collaboration between two leading research teams. The University of Marburg is leading in the area of the preparation of nanoobjects, while the research team at CAMD (UNSW) focuses on the preparation of well-controlled polymer structures via RAFT polymerisation. The combined strength of both groups seeks to improve the properties of nanodevices by the attachment of well-defined polymer layers. We expect therefore an optimum scientific output with both groups focusing on their research potency next to being able to access new knowledge. The visit to the German research group enables the Australian researchers access to a leading team in nanotechnology.Read moreRead less
Living Free Radical Polymerization for Nano Technology Applications. The proposed linkage project centres on a series of core projects from both the Australian and German collaborators. These core projects range from the synthesis of multifunctional nano- and micro-sphere particles, block copolymer systems used as efficient vehicles for drug delivery purposes to polymer brushes for nano-wires. The collaborating teams will carry out joint research tasks in the above mentioned fields via the excha ....Living Free Radical Polymerization for Nano Technology Applications. The proposed linkage project centres on a series of core projects from both the Australian and German collaborators. These core projects range from the synthesis of multifunctional nano- and micro-sphere particles, block copolymer systems used as efficient vehicles for drug delivery purposes to polymer brushes for nano-wires. The collaborating teams will carry out joint research tasks in the above mentioned fields via the exchange of the CIs and PhD students. The project is planned for a duration of three years to ensure an in-depth approach to the proposed projects.Read moreRead less
Materials World Network Synthesis and Processing Optoelectronic Materials in Supercritical and Condensed Phase Carbon Dioxide. The Australian partner will have leveraged access to the skill base and facilities of the Cornell Center for Materials Research, and the NSF MRSEC that leads the world in frontier technologies in advanced materials. The partnership will deliver to Australia progress in national priority goals "Frontier Technologies" and new manufacturing technologies in environmentally ....Materials World Network Synthesis and Processing Optoelectronic Materials in Supercritical and Condensed Phase Carbon Dioxide. The Australian partner will have leveraged access to the skill base and facilities of the Cornell Center for Materials Research, and the NSF MRSEC that leads the world in frontier technologies in advanced materials. The partnership will deliver to Australia progress in national priority goals "Frontier Technologies" and new manufacturing technologies in environmentally friendly media that will enhance the national research priority "An Environmentally Sustainable Australia". New transferable skills will be acquired by the participants in the project. Technology transfer could result in the formation of spinoff companies to exploite the intellectual property arising in the project.Read moreRead less
Characterization of star nanogels by advanced transmission electron microscopy. This project will provide an excellent opportunity to combine research expertise from The Polymer Science Group at The University of Melbourne and The Polymer Morphology Group at North Carolina State University (NCSU) to develop and characterize novel star nanogels with unique macromolecular architectures. The success of the project will reveal the absolute structures of these molecules and the proposed studies are b ....Characterization of star nanogels by advanced transmission electron microscopy. This project will provide an excellent opportunity to combine research expertise from The Polymer Science Group at The University of Melbourne and The Polymer Morphology Group at North Carolina State University (NCSU) to develop and characterize novel star nanogels with unique macromolecular architectures. The success of the project will reveal the absolute structures of these molecules and the proposed studies are both intellectually challenging in the cutting-edge of leading research in the field and important to provide vital information for the design of new structures of these new materials for their application in many areas, such as drug delivery, new membrane formation, advance high density memory chips and possibly the next generation of automotive coating.Read moreRead less
Novel Nanofibre-Templated Nanotubes Prepared by Using ABA Block Copolymers. The aim of this project is to prepare new, highly functional nanomaterials using layer-by-layer assembly of polyelectrolytes on a three-dimensional template. Using this approach, a core-shell fibre is initially prepared by alternate deposition of oppositely charged materials onto an electrospun fibre template. The initial fibre can then be dissolved to give hollow nanotubes. New block copolymers, incorporating both charg ....Novel Nanofibre-Templated Nanotubes Prepared by Using ABA Block Copolymers. The aim of this project is to prepare new, highly functional nanomaterials using layer-by-layer assembly of polyelectrolytes on a three-dimensional template. Using this approach, a core-shell fibre is initially prepared by alternate deposition of oppositely charged materials onto an electrospun fibre template. The initial fibre can then be dissolved to give hollow nanotubes. New block copolymers, incorporating both charged and uncharged domains, will be used in the assembly, in order to design tubes with novel properties. The behaviour of these tubes under a variety of pH and solvent conditions will then be examined, and the tubes characterized using various microscopy techniques.Read moreRead less
Branching in acrylic polymers: analysis and mechanistic understanding. Some polymers can be branched. This branching has major effects on the end-product performance of a polymer, for example in adhesives and the flexibility of rubbery materials. Full quantification of this branching (the lengths of branches and the rates of the processes that create them) has been impossible hitherto. Two new complementary techniques, a new analytical method developed by the applicant Fellow in Paris, and a new ....Branching in acrylic polymers: analysis and mechanistic understanding. Some polymers can be branched. This branching has major effects on the end-product performance of a polymer, for example in adhesives and the flexibility of rubbery materials. Full quantification of this branching (the lengths of branches and the rates of the processes that create them) has been impossible hitherto. Two new complementary techniques, a new analytical method developed by the applicant Fellow in Paris, and a new synthesis technique developed in Sydney, will be used as the platforms to devise the first means of determining this information and thus understanding and quantifying branching.Read moreRead less
Conformationally constrained and immobilized beta-peptides. The research builds on world-class expertise in Australia (particularly Adelaide) in proteomics to provide a basis for fundamental advances in chemistry that will underpin the development of new pharmaceuticals and smart materials, and future technologies and industries. We create a mix of research at the interface of disciplines within academia and industry, with linkages to the very best international researchers and centres. A new cr ....Conformationally constrained and immobilized beta-peptides. The research builds on world-class expertise in Australia (particularly Adelaide) in proteomics to provide a basis for fundamental advances in chemistry that will underpin the development of new pharmaceuticals and smart materials, and future technologies and industries. We create a mix of research at the interface of disciplines within academia and industry, with linkages to the very best international researchers and centres. A new critical mass of expertise in a number of advancing areas of chemistry, biology, and materials science will be introduced to Australia. This will enhance existing strengths and opportunities in proteomics and biomedical research for the treatment of disease.Read moreRead less
Organotin based hybrid materials as selective catalysts. Hybrid organic-inorganic materials offer potential applications in a variety of fields ranging from photonics to selective catalysts. This pilot project brings together the expertise in four international research laboratories to focus on elaboration of new nanocomposites as highly selective Lewis acid catalysts for fine chemicals synthesis.
Synthesis and Characterization of Novel Hybrid star polymers grown from carbohydrate clusters. The aim of the project is to make complex polymer architectures based on stars grown from sugar clusters. The star molecules are expected to have unique properties for transporting guest molecules in drug delivery systems. The outcome will be the development of totally biodegradable, non-toxic cluster/star structures capable of complexing to drugs. This is the first attempt to utilise these clusters ....Synthesis and Characterization of Novel Hybrid star polymers grown from carbohydrate clusters. The aim of the project is to make complex polymer architectures based on stars grown from sugar clusters. The star molecules are expected to have unique properties for transporting guest molecules in drug delivery systems. The outcome will be the development of totally biodegradable, non-toxic cluster/star structures capable of complexing to drugs. This is the first attempt to utilise these clusters, with sugar-based vinyl monomers for star synthesis.Read moreRead less
Organotin Oxo-clusters Based Hybrid Materials. Hybrid materials are composites which contain both organic and inorganic components, intimately mixed at the microscopic (nanometer) scale. They have applications in areas ranging from recoverable chemical catalysts to micro-chip technology. We will provide new oganometallic components of suitable architecture for assessment as new materials.