The role of water uptake in novel all solid-state polymeric ion sensors. This research will enable the development of robust all solid-state polymeric ion sensors based on unplasticized copolymers. Significantly, the physical and chemical robustness of these copolymer ion sensors will allow their widespread use in new and exciting analytical applications, e.g., in-situ analysis of environmental samples in submersible instruments, clinical analysis of whole blood, in-vivo use of miniaturized ele ....The role of water uptake in novel all solid-state polymeric ion sensors. This research will enable the development of robust all solid-state polymeric ion sensors based on unplasticized copolymers. Significantly, the physical and chemical robustness of these copolymer ion sensors will allow their widespread use in new and exciting analytical applications, e.g., in-situ analysis of environmental samples in submersible instruments, clinical analysis of whole blood, in-vivo use of miniaturized electrodes in biological media, especially single cells and minute samples in biology and forensic science, etc. Extensive use of neutron characterization techniques aligns strongly this project with the new OPAL reactor to be commissioned in 2007.Read moreRead less
Nanostructured materials for development of advanced lithium energy storage systems. This project is expected to bring several national benefits. Novel nanostructured electro-active materials and high energy density rechargeable lithium batteries will be developed. The application of advanced lithium batteries as power sources for electric vehicles (EVs) and hybrid electric vehicles (HEVs) will realise nearly zero emission transportation. The widespread usage of EVs and HEVs could significantly ....Nanostructured materials for development of advanced lithium energy storage systems. This project is expected to bring several national benefits. Novel nanostructured electro-active materials and high energy density rechargeable lithium batteries will be developed. The application of advanced lithium batteries as power sources for electric vehicles (EVs) and hybrid electric vehicles (HEVs) will realise nearly zero emission transportation. The widespread usage of EVs and HEVs could significantly reduce air pollution, improve urban environment and increase national energy security and energy independence.Read moreRead less
Adsorption and recovery of gold thiosulfate using nanoporous carbon. The gold industry is a major export earner for both Australia and the United States. This collaborative project aims to develop an environmentally acceptable, cost effective process for the recovery of gold from thiosulfate leachate. Development of this process will remove one of the barriers to the acceptance of thiosulfate leaching over conventional cyanide extraction, leading to substantial benefits to the gold industry and ....Adsorption and recovery of gold thiosulfate using nanoporous carbon. The gold industry is a major export earner for both Australia and the United States. This collaborative project aims to develop an environmentally acceptable, cost effective process for the recovery of gold from thiosulfate leachate. Development of this process will remove one of the barriers to the acceptance of thiosulfate leaching over conventional cyanide extraction, leading to substantial benefits to the gold industry and the environment. A successful outcome in the research project would also lead to export earnings resulting from technology transfer and an enhanced reputation for high quality research.Read moreRead less
Blocking of the interfaces of polymeric ion sensors - implications for novel sensor applications. Control of the transmembrane fluxes of polymeric ion sensors represents a paradigm shift that has revolutionised the use of these analytically important devices. This project will develop and characterise innovative methods for controlling these fluxes by using blocked interfaces, and this has important ramifications for the development of robust and reliable sensors, as well as novel biosensors.
Polyaniline Nanofibre Systems. Advanced materials such as the conducting polymer and applications of these materials at the nanoscale and up is clearly a cutting edge area of international interest. Development of readily processable nano systems has been a challenge with a clear scientific and commercial benefit. This proposal will bring linkages to Australia with the world leader in the field, Professor Kaner -UCLA, on the synthesis of polyaniline nanofibres and associated photowelding process ....Polyaniline Nanofibre Systems. Advanced materials such as the conducting polymer and applications of these materials at the nanoscale and up is clearly a cutting edge area of international interest. Development of readily processable nano systems has been a challenge with a clear scientific and commercial benefit. This proposal will bring linkages to Australia with the world leader in the field, Professor Kaner -UCLA, on the synthesis of polyaniline nanofibres and associated photowelding processes. The opportunities to Australia and the USA will be to expand the potential utility of such systems, which without such interactions would permit others to take a stake hold in this emergent and potentially lucrative technology.Read moreRead less
An investigation of growth processes, structure and properties of biogenically synthesised gold nanoparticles. Nanoparticles can have unique and interesting properties such as optical activity and redox (electronic) behaviour that can be utilised in a number of applications such as drug delivery and cancer hyperthermia treatments, coatings, electronic devices and sensors. The main aims of this research program are to produce novel nanoparticles using an innovative method which uses biological sp ....An investigation of growth processes, structure and properties of biogenically synthesised gold nanoparticles. Nanoparticles can have unique and interesting properties such as optical activity and redox (electronic) behaviour that can be utilised in a number of applications such as drug delivery and cancer hyperthermia treatments, coatings, electronic devices and sensors. The main aims of this research program are to produce novel nanoparticles using an innovative method which uses biological species such as fungi and plant extracts, and to study the growth mechanisms, structure and properties of these nanoparticles. These studies could lead to the discovery of novel nanoparticles with applications in the fields mentioned above. This project also aims to train/educate young Australian graduates in the growing area of advanced materials.Read moreRead less
New Synthetic Routes to the Immobilisation of Mixed Valence Transition Metal Complexes on Conducting Metal Oxides. Highly coloured, electrochemically active transition metal dyes may find application electrochromic devices, where they may switch between contrasting coloured forms through a simple redox reaction. A prerequisite is that the dye be immobilised onto a solid conducting support whilst preserving the electrochemical and optical properties of the dye found in solution. This project tack ....New Synthetic Routes to the Immobilisation of Mixed Valence Transition Metal Complexes on Conducting Metal Oxides. Highly coloured, electrochemically active transition metal dyes may find application electrochromic devices, where they may switch between contrasting coloured forms through a simple redox reaction. A prerequisite is that the dye be immobilised onto a solid conducting support whilst preserving the electrochemical and optical properties of the dye found in solution. This project tackles this problem through a combination of organic and inorganic synthesis to develop new electrochromic dyes that may be attached to mesoporous titania.Read moreRead less
Design and Synthesis of Ionic Liquids for Use in Photoelectrochemical Cells Based on Inherently Conducting Polymers. We propose to evaluate the electrochemistry of photoactive polythiophenes recently synthesised by us in a range of ionic liquids. This knowledge will be used to design and synthesise customised ionic liquids with the properties required to enhance the photoelectrochemical efficiency of devices based on substituted polythiophenes. We expect our findings to lead to the development ....Design and Synthesis of Ionic Liquids for Use in Photoelectrochemical Cells Based on Inherently Conducting Polymers. We propose to evaluate the electrochemistry of photoactive polythiophenes recently synthesised by us in a range of ionic liquids. This knowledge will be used to design and synthesise customised ionic liquids with the properties required to enhance the photoelectrochemical efficiency of devices based on substituted polythiophenes. We expect our findings to lead to the development of low-cost, flexible, organic photoelectrochemical cells.Read moreRead less
Active polymer surfaces for control of fluid movement. The realisation of a diverse array of remote or portable chemical/biological monitoring systems depends on the development of low power fluid management protocols. The use of appropriate conducting polymer surfaces should enable this to occur. We envisage the integration of these fluid management platforms into portable, remote autonomous monitoring systems for environmental industrial and biomedical applications.
Overcoming the Barriers in the Development of Solid State Materials. A major impact of this proposal shall be in terms of researcher training. By synergistically combining materials chemistry, fundamental physical chemistry, inorganic chemistry, and electrochemistry, this basic program will provide high level training to a new generation of Australian and Irish scientists thus helping to safeguard the economic competitiveness of the countries. Beyond the impact of the fundamental insight into t ....Overcoming the Barriers in the Development of Solid State Materials. A major impact of this proposal shall be in terms of researcher training. By synergistically combining materials chemistry, fundamental physical chemistry, inorganic chemistry, and electrochemistry, this basic program will provide high level training to a new generation of Australian and Irish scientists thus helping to safeguard the economic competitiveness of the countries. Beyond the impact of the fundamental insight into the rational design, structure and behaviour of a new class of solid materials, success in this program will have widespread applications for a variety of strategically important industries and should place Australia and Ireland at the forefront of this technologyRead moreRead less