ORCID Profile
0000-0002-7560-121X
Current Organisations
Monash University
,
University of South Australia
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Publisher: Wiley
Date: 09-2009
DOI: 10.1002/PAT.1290
Publisher: Royal Society of Chemistry (RSC)
Date: 2018
DOI: 10.1039/C8PY00157J
Abstract: Recent progress in the photoinitiators and monomers/oligomers of photopolymers for 3D printing is presented in the review.
Publisher: Royal Society of Chemistry (RSC)
Date: 23-07-2014
DOI: 10.1039/C4PY00925H
Publisher: American Chemical Society (ACS)
Date: 16-09-2021
Publisher: Wiley
Date: 14-04-2018
Publisher: American Chemical Society (ACS)
Date: 14-05-2020
Publisher: Elsevier BV
Date: 11-2017
Publisher: Springer Science and Business Media LLC
Date: 28-08-2015
Publisher: Elsevier BV
Date: 2022
Publisher: American Chemical Society (ACS)
Date: 31-08-2020
Publisher: American Chemical Society (ACS)
Date: 02-05-2014
DOI: 10.1021/MA500612X
Publisher: Wiley
Date: 12-11-2015
DOI: 10.1002/POLA.27958
Publisher: Royal Society of Chemistry (RSC)
Date: 2021
DOI: 10.1039/D1PY00030F
Abstract: N -(1-Pyrenyl)glycine can act as a versatile initiator for various polymerizations.
Publisher: Elsevier BV
Date: 09-2016
Publisher: Wiley
Date: 23-10-2014
DOI: 10.1002/POLA.27435
Publisher: Wiley
Date: 10-12-2014
DOI: 10.1002/POLA.27477
Publisher: Wiley
Date: 05-04-2016
Publisher: Royal Society of Chemistry (RSC)
Date: 2018
DOI: 10.1039/C8PY00055G
Abstract: Four N -[2-(dimethylamino)ethyl]-1,8-naphthalimide derivatives (ANNs) with different substituents in the naphthalimide skeleton have been synthesized and can be used as versatile photoinitiators under various LEDs.
Publisher: Wiley
Date: 15-03-2016
DOI: 10.1002/POLA.28098
Publisher: Informa UK Limited
Date: 26-06-2013
Publisher: Wiley
Date: 18-06-2019
Abstract: The design and development of photoinitiating systems applicable to UV or even visible light delivered from light-emitting diodes (LEDs) has been attracting increasing attention due to their great potential applications in various fields. Compared to the strategy of synthesizing novel compounds, the exploration of existing chemicals with interesting photochemical hotophysical properties for their usage as photoinitiators is more appealing and easily commercialized. Nevertheless, a number of compounds such as monoamino-substituted anthraquinone derivatives, which are intensively investigated for their photophysical and photochemical properties, have seldom been studied for their roles as photoinitiators under LED irradiation. Herein, three monoamino-substituted anthraquinone derivatives, that is, 1-aminoanthraquinone, 1-(methylamino)anthraquinone and 1-(benzamido)anthraquinone, are studied for their potential as photoinitiators. The photoinitiation mechanism of these monoamino-substituted anthraquinone derivatives, when combined with iodonium salt, is first clarified using computational quantum chemistry, fluorescence, steady-state photolysis, and electron spin resonance spin-trapping techniques. Then, their photoinitiation ability for the cationic photopolymerization of epoxide and inyl ether monomers is also investigated.
Publisher: American Chemical Society (ACS)
Date: 06-06-2014
DOI: 10.1021/MA5006793
Publisher: American Chemical Society (ACS)
Date: 05-10-2018
Publisher: Royal Society of Chemistry (RSC)
Date: 27-06-2014
DOI: 10.1039/C4PY00770K
Publisher: Elsevier BV
Date: 03-2019
Publisher: Medknow
Date: 2015
Publisher: Wiley
Date: 13-04-2015
DOI: 10.1002/POLA.27640
Publisher: Wiley
Date: 14-08-2015
DOI: 10.1002/POLA.27762
Publisher: Wiley
Date: 04-08-2015
Publisher: Elsevier BV
Date: 12-2014
Publisher: Wiley
Date: 06-08-2015
DOI: 10.1002/POLA.27763
Publisher: The Royal Society of Chemistry
Date: 16-08-2018
DOI: 10.1039/9781788013307-00156
Abstract: Several novel photoinitiators applicable to various photopolymerisation reactions (e.g. free-radical photopolymerisation and cationic photopolymerisation) under visible light delivered from light-emitting diodes (LEDs) have been developed in the last 5 years. Based on the specific chemical structures of these photoinitiators, reactive species such as free radicals or cations can be generated through their exposure to blue, green, yellow, or red LEDs and induce photopolymerisation reactions. Specifically, naphthalimide derivatives or metal-based complexes (e.g. ruthenium-, iridium-, copper-, iron-, and zinc-based complexes) have emerged as efficient blue-light-sensitive photoinitiators, while some compounds with large π-conjugated structures demonstrate excellent photoinitiating ability of polymerisation under green to red LEDs. This chapter summarizes the recently emerging LED-sensitive photoinitiators, which demonstrate great potential for application in the fabrication of polymer-based materials under mild conditions.
Publisher: Wiley
Date: 16-12-2014
DOI: 10.1002/POLA.27490
Publisher: Royal Society of Chemistry (RSC)
Date: 2015
DOI: 10.1039/C5PY00258C
Abstract: The use of LEDs as novel and efficient light sources for the photopolymerization of various monomers (acylate, epoxy), interpenetrating polymer networks and thiols–ene, leads to the development of novel photoinitiating systems adapted for the LED emission.
Publisher: American Chemical Society (ACS)
Date: 03-04-2015
Publisher: Wiley
Date: 03-08-2016
Publisher: Frontiers Media SA
Date: 05-10-2020
Publisher: Wiley
Date: 02-06-2016
Publisher: Wiley
Date: 23-03-2021
Abstract: Photopolymerization allows fast production of materials with special properties however, a short wavelength of light is required for most commercial photoinitiating systems and the oxygen inhibition effect for the free radical polymerization has limited possible applications. Herein, we investigate thiol‐ene photopolymerization with various types of “ene” derivatives and thiols using our previously reported photoinitiator 2‐(4‐methoxystyryl)‐4,6‐bis(trichloromethyl)‐1,3,5‐triazine (triazine) alone or in combination with rubrene or 1,4‐bis(isopropylamino)anthraquinone (SB36) as the photoinitiating systems to trigger polymerization under irradiation with blue, green, and red LEDs. An analysis of photopolymerization kinetics and the effects of different light irradiation conditions, chemical structures, composites of “ene” and thiol monomers, and air on the thiol‐ene photopolymerization reaction are presented. Specifically, rates of photopolymerization of all thiol‐ene formulations decrease as the wavelength of irradiation increases and show no significant difference when polymerization occurs under air or in laminate. Mechanical properties and homogeneity of the photocured s les are analyzed and demonstrated that all thiol‐ene formulations appear to have a homogeneous network. Regarding mechanical properties, with a lower amount of thiol incorporated in the network, the storage modulus and the glass transition temperature (T g ) of the photocured product increased. Storage stability of thiol‐ene formulations is also studied and 5‐hydroxy‐1,4‐naphthoquinone (5HNQ), a naturally derived dye derivative, is found to be successful in inhibiting premature gelation in thiol‐ene systems without significantly affecting the photopolymerization performance.
Publisher: Wiley
Date: 17-11-2008
DOI: 10.1002/PAT.1235
Publisher: Royal Society of Chemistry (RSC)
Date: 2016
DOI: 10.1039/C6RA09422H
Abstract: Aminothiazonaphthalimide derivatives can act as photoinitiators (when combined with additives) to start the cationic polymerization or the radical polymerization upon exposure to visible LEDs or a polychromatic visible light.
Publisher: Wiley
Date: 25-03-2015
DOI: 10.1002/POLA.27615
Publisher: Elsevier BV
Date: 05-2014
Publisher: Wiley
Date: 07-11-2014
DOI: 10.1002/POLA.27451
Publisher: Wiley
Date: 29-10-2014
Publisher: American Chemical Society (ACS)
Date: 06-12-2018
Publisher: Elsevier BV
Date: 09-2015
Publisher: Wiley
Date: 12-09-2016
Publisher: Elsevier BV
Date: 02-2015
Publisher: American Chemical Society (ACS)
Date: 22-08-2022
DOI: 10.1021/ACS.ANALCHEM.2C01979
Abstract: The phase (solid, semisolid, or liquid) of atmospheric aerosols is central to their ability to take up water or undergo heterogeneous reactions. In recent years, the unexpected prevalence of viscous organic particles has been shown through field measurements and global atmospheric modeling. The aerosol phase has been predicted using glass transition temperatures (
Publisher: Wiley
Date: 10-09-2008
DOI: 10.1002/APP.28896
Publisher: Wiley
Date: 30-03-2009
DOI: 10.1002/APP.29982
Publisher: Wiley
Date: 20-04-2018
Abstract: Multihydroxy-anthraquinone derivatives [i.e., 1,2,4-trihydroxyanthraquinone (124-THAQ), 1,2,7-trihydroxyanthraquinone (127-THAQ), and 1,2,5,8-tetrahydroxyanthraquinone (1258-THAQ)] can interact with various additives [e.g., iodonium salt, tertiary amine, N-vinylcarbazole, and 2-(4-methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine] under household green LED irradiation to generate active species (cations and radicals). The relevant photochemical mechanism is investigated using quantum chemistry, fluorescence, cyclic voltammetry, laser flash photolysis, steady state photolysis, and electron spin resonance spin-trapping techniques. Furthermore, the multihydroxy-anthraquinone derivative-based photoinitiating systems are capable of initiating cationic photopolymerization of epoxides or inyl ethers under green LED, and the relevant photoinitiation ability is consistent with the photochemical reactivity (i.e., 124-THAQ-based photoinitiating system exhibits highest reactivity and photoinitiation ability). More interestingly, multihydroxy-anthraquinone derivative-based photoinitiating systems can initiate free radical crosslinking or controlled (i.e., reversible addition-fragmentation chain transfer) photopolymerization of methacrylates under green LED. It reveals that multihydroxy-anthraquinone derivatives can be used as versatile photoinitiators for various types of photopolymerization reactions.
Publisher: Royal Society of Chemistry (RSC)
Date: 2020
DOI: 10.1039/C9CS00731H
Abstract: This review summarises recent advances in light-regulated non-radical polymerisations as well as the applications in materials science.
Publisher: Royal Society of Chemistry (RSC)
Date: 2015
DOI: 10.1039/C4PY01409J
Abstract: The well-designed 2-amino-1 H -benzo[ de ]isoquinoline-1,3-(2 H )-dione derivatives exhibit an excellent photopolymerization ability upon LEDs.
Publisher: Royal Society of Chemistry (RSC)
Date: 2016
DOI: 10.1039/C5PY01617G
Abstract: A series of naphthalimide derivatives containing tertiary amine groups (DNNDs) have been prepared.
Publisher: Royal Society of Chemistry (RSC)
Date: 2016
DOI: 10.1039/C6PY01550F
Abstract: Dihydroxyanthraquinone derivatives can be used as versatile blue-light-sensitive photoinitiators for cross-linked free radical photopolymerization, RAFT photopolymerization, and cationic photopolymerization.
Publisher: Wiley
Date: 10-08-2017
Publisher: Wiley
Date: 10-01-2020
DOI: 10.1002/POL.20190157
Publisher: Wiley
Date: 08-05-2020
Publisher: The Royal Society of Chemistry
Date: 16-08-2018
DOI: 10.1039/9781788013307-00179
Abstract: This paper shows some ex les of the construction of new photoinitiators for blue light based on different chromophores: naphthalimides, naphthalic anhydrides, benzo-isoquinolinones, benzophenones, indanediones, chalcones, chromones, and perylenes. Theoretical calculations allow the molecular orbitals to be efficiently combined to shift the absorption properties of classical photoinitiators to longer wavelength. Moreover, suitable combinations of these original photoinitiators with various additives ensure excellent initiation of the free-radical polymerization of methacrylate monomers both in laminate and under air. Many additives were also studied in these multi-component photoinitating systems to drastically improve their initiating ability. The stability of photoinitiators in formulations as well as their bleaching properties are also important parameters to characterize for the end user.
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