ORCID Profile
0000-0002-2676-6018
Current Organisation
NSW Department of Industry Skills and Regional Development
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In Research Link Australia (RLA), "Research Topics" refer to ANZSRC FOR and SEO codes. These topics are either sourced from ANZSRC FOR and SEO codes listed in researchers' related grants or generated by a large language model (LLM) based on their publications.
Nanomaterials | Crop and Pasture Nutrition | Crop and Pasture Production | Mineral Processing/Beneficiation | Fertilisers and Agrochemicals (Application etc.)
Chemical Fertilisers | Farmland, Arable Cropland and Permanent Cropland Soils | Mining and Extraction of Stone and Clay | Grain Legumes | Wheat |
Publisher: Wiley
Date: 28-09-2015
DOI: 10.1111/EJSS.12294
Publisher: Elsevier BV
Date: 12-2021
Publisher: Wiley
Date: 21-03-2011
Publisher: Frontiers Media SA
Date: 04-08-2020
Publisher: Elsevier BV
Date: 2019
DOI: 10.1016/J.SCITOTENV.2018.07.221
Abstract: Glyphosate represents one quarter of global herbicide sales, with growing interest in both its fate in soils and potential to cause non-target phytotoxicity to plants. However, assessing glyphosate bioavailability to plants from soil residues remains challenging. Here we demonstrate that the diffusive gradient in thin-films technique (DGT) can effectively measure available glyphosate across boundary conditions typical of the soil environment: pH 4-9, P concentrations of 20-300 μg P L
Publisher: Springer Science and Business Media LLC
Date: 02-09-2022
DOI: 10.1038/S41467-022-32819-7
Abstract: The soil carbon (C) saturation concept suggests an upper limit to the storage of soil organic carbon (SOC). It is set by the mechanisms that protect soil organic matter from mineralization. Biochar has the capacity to protect new C, including rhizodeposits and microbial necromass. However, the decadal-scale mechanisms by which biochar influences the molecular ersity, spatial heterogeneity, and temporal changes in SOC persistence, remain unresolved. Here we show that the soil C storage ceiling of a Ferralsol under subtropical pasture was raised by a second application of Eucalyptus saligna biochar 8.2 years after the first application—the first application raised the soil C storage ceiling by 9.3 Mg new C ha −1 and the second application raised this by another 2.3 Mg new C ha −1 . Linking direct visual evidence from one-, two-, and three-dimensional analyses with SOC quantification, we found high spatial heterogeneity of C functional groups that resulted in the retention of rhizodeposits and microbial necromass in microaggregates (53–250 µm) and the mineral fraction ( µm). Microbial C-use efficiency was concomitantly increased by lowering specific enzyme activities, contributing to the decreased mineralization of native SOC by 18%. We suggest that the SOC ceiling can be lifted using biochar in (sub)tropical grasslands globally.
Publisher: Springer Science and Business Media LLC
Date: 11-07-2022
DOI: 10.1007/S11104-022-05569-0
Abstract: Alkaline dispersive subsoils are characterised by multiple physicochemical constraints that limit plant water and nutrient acquisition. Subsoil amelioration through organic amendments (OAs) requires significant financial investment. Whereas large yield responses can result following amelioration, sometimes small or even negative yield responses can occur, resulting in a significant net financial loss for the farmer. For farmers to feel confident in investing in subsoil amelioration better prediction of the likely yield improvement is required and to achieve this an understanding of the underlying mechanisms such as nutritional and non-nutritional drivers, and the longevity of benefits are required. Our study aimed to ascertain the drivers of yield improvements from subsoil amelioration with OAs. In a controlled environment, wheat ( Triticum aestivum L. cv. Scepter) plants were grown until maturity in a Solonetz amended with (i) poultry litter (PL 20 t ha −1 ), and (ii) NPKS nutrients and (iii) model organic carbon (MOC) with equivalent amounts of nutrients and total carbon contained in the PL, and (iv) NPKS + MOC. Control (no amendments) and gypsum (5 t ha −1 ) were included as district practices. Before planting, amendments were applied as a vertical band at 20 – 40 cm depth and pre-incubated. Plant biomass, grain yield, root biomass, and physicochemical properties of the soil associated with the amendment band were quantified at harvest. Compared to the control, wheat grain yield was increased by 30% for PL, 43% for NPKS + MOC, and 61% for NPKS, but no differences in yield were detected for MOC or gypsum. The lower yield increase by PL than NPKS with or without MOC was likely due to the readily available form of plant nutrients in the inorganic fertilisers vs slower mineralisation of nutrients from the OAs. Improvement in soil physicochemical properties following amelioration of alkaline dispersive subsoil resulted in better root proliferation and subsoil water use. Grain yield showed a positive correlation with root biomass in the subsoil layers. In the short-term (one crop cycle), organic amendments improved soil’s non-nutritional physical and chemical properties but had no additional nutritional effect on wheat grain yield compared to inorganic fertiliser application. Longer-term studies are needed to determine the legacy effect of the nutritional contribution in conjunction with the improvement of soil structure from the OAs in alkaline dispersive subsoils.
Publisher: Elsevier BV
Date: 2008
Publisher: American Chemical Society (ACS)
Date: 30-07-2012
DOI: 10.1021/ES301487S
Abstract: The rapid development and commercialization of nanomaterials will inevitably result in the release of nanoparticles (NPs) to the environment. As NPs often exhibit physical and chemical properties significantly different from those of their molecular or macrosize analogs, concern has been growing regarding their fate and toxicity in environmental compartments. The wastewater-sewage sludge pathway has been identified as a key release pathway leading to environmental exposure to NPs. In this study, we investigated the chemical transformation of two ZnO-NPs and one hydrophobic ZnO-NP commercial formulation (used in personal care products), during anaerobic digestion of wastewater. Changes in Zn speciation as a result of postprocessing of the sewage sludge, mimicking composting/stockpiling, were also assessed. The results indicated that "native" Zn and Zn added either as a soluble salt or as NPs was rapidly converted to sulfides in all treatments. The hydrophobicity of the commercial formulation retarded the conversion of ZnO-NP. However, at the end of the anaerobic digestion process and after postprocessing of the sewage sludge (which caused a significant change in Zn speciation), the speciation of Zn was similar across all treatments. This indicates that, at least for the material tested, the risk assessment of ZnO-NP through this exposure pathway can rely on the significant knowledge already available in regard to other "conventional" forms of Zn present in sewage sludge.
Publisher: Elsevier BV
Date: 03-2022
Publisher: American Chemical Society (ACS)
Date: 17-09-2013
DOI: 10.1021/ES400805J
Abstract: The interaction of inorganic contaminants present in biosolids with iron, aluminum, and manganese oxy/hydroxides has been advocated as a key mechanism limiting their bioavailability. In this study, we investigated whether this is indeed the case, and further, whether it can be exploited to produce optimized biosolids products through the addition of chemical additives during sewage sludge processing. Experiments were conducted to investigate whether the addition of iron- and aluminum-based amendments (at 5 different rates) during the anaerobic digestion phase of wastewater treatment can effectively change the speciation or lability of contaminant metals (copper, zinc and cadmium) in biosolids destined for use in agriculture. The performance of the bioreactors was monitored throughout and the speciation and lability were determined in both fresh and 3-month aged biosolids using X-ray absorption spectroscopy (Cu, Zn) and isotopic dilution ((65)Cu, (65)Zn, (109)Cd). The tested amendments (FeCl3, Al2(SO4)3, and Al-rich water treatment residual) did not cause significant changes in metal speciation and were of limited use for reducing the lability of contaminant metals in good quality biosolids (suitable for use in agriculture), suggesting that high affinity binding sites were already in excess in these materials. However, the use of chemical amendments may offer advantages in terms of treatment process optimization and may also be beneficial when biosolids are used for contaminated site remediation.
Publisher: Springer Science and Business Media LLC
Date: 27-06-2018
Publisher: Oxford University Press (OUP)
Date: 16-08-2010
DOI: 10.1093/JXB/ERQ251
Publisher: Elsevier BV
Date: 11-2018
Publisher: Wiley
Date: 05-05-2021
DOI: 10.1002/LDR.3971
Abstract: Identification of key soil properties is an essential prerequisite to delineating the management zone (MZ), which is traditionally done by selecting soil parameters before crop planting. However, soil properties during sensitive stages of crop growth may have a greater effect on the MZ delineation than those before planting. This study is aimed to determine whether inclusion of soil properties measured in surface layers during the reproductive stage of rice could enhance the appropriateness of MZ delineation based on sodic/saline‐sodic paddy fields. When including soil variables during the reproductive stage, with/without soil variables before planting, a similar MZ pattern (MZ pattern 3) was generated. Furthermore, when including soil variables during the reproductive stage and rice yield components, with/without soil variables before planting, another similar MZ pattern (MZ Pattern 4) was generated. Compared with other patterns, the MZ pattern 4 showed higher relative variances for rice yield and the mean of its most important yield‐influencing factors, with lower coefficient of variation (CV) in all MZs compared with the whole‐paddock CV. Likewise, this pattern showed improvement in discriminating soil and rice variables among MZs. These findings confirm that inclusion of soil properties during the reproductive stage of rice has potential for enhancing the appropriateness of MZ delineation. This study also necessitates inclusion of carbonate‐derived variables when delineating MZs in sodic/saline‐sodic paddy fields. Our results encourage further investigation of the role of soil properties in surface soil layers at critical crop growth stages in MZ delineation under multiple soil and climatic conditions.
Publisher: Elsevier BV
Date: 02-2012
Publisher: Elsevier BV
Date: 06-2018
Publisher: Springer Science and Business Media LLC
Date: 28-11-2020
Publisher: Elsevier BV
Date: 07-2020
Publisher: Elsevier BV
Date: 11-1919
Publisher: Wiley
Date: 25-08-2022
DOI: 10.1111/SUM.12756
Abstract: Highly alkaline soils are widespread throughout south‐eastern Australia. High pH limits the accumulation and retention of organic carbon (C), and thus the availability of nutrients to crops and is also associated with various elemental deficiencies and toxicities that restrict crop productivity. Applying gypsum and increasing legume production reduce pH and improve soil chemical and physical properties in alkaline, sodic soils, but this strategy has not been explored in alkaline soils in the region where many of the topsoils are non‐sodic. Five short‐term rotation experiments were conducted to examine the potential to reduce pH, improve soil organic C and increase crop production. In the first year, three legumes—field peas ( Pisum sativum ), vetch ( Vicia sativa ) and a medic pasture ( Medicago spp.)—were grown at low or high inputs of seed and fertilizer and with three rates of gypsum (0, 2.5 t/ha and 5.0 t/ha). In the following seasons, wheat ( Triticum aestivum) and barley ( Hordeum vulgare ) were grown. Using high sowing and fertilizer rates to increase legume biomass had little effect on soil properties however, applying gypsum consistently resulted in a lower soil pH and dissolved organic C and higher organic C compared with the unamended control to a depth of 0.20–0.30 m. The largest difference occurred with 2.5 t gypsum/ha with little further change at 5 t/ha. Gypsum significantly increased biomass and grain yield at sites with low concentrations of calcium carbonate. Low rates of gypsum may be effective in reducing pH, maintaining soil organic C and improving crop production in regions with alkaline soils low in calcium carbonate.
Publisher: Elsevier BV
Date: 04-2015
DOI: 10.1016/J.ENVPOL.2015.01.031
Abstract: The association of polycyclic aromatic hydrocarbons (PAHs) with inorganic and organic colloids is an important factor influencing their bioavailability, mobility and degradation in the environment. Despite this, our understanding of the exchangeability and potential bioavailability of PAHs associated with colloids is limited. The objective of this study was to use phenanthrene as a model PAH compound and develop a technique using (14)C phenanthrene to quantify the isotopically exchangeable and non-exchangeable forms of phenanthrene in filtered soil water or sodium tetraborate extracts. The study was also designed to investigate the exchangeability of colloidal phenanthrene as a function of particle size. Our findings suggest that the exchangeability of phenanthrene in sodium tetraborate is controlled by both inorganic and organic colloids, while in aqueous solutions inorganic colloids play the dominant role (even though coating of these by organic matter cannot be excluded). Filter pore size did not have a significant effect on phenanthrene exchangeability.
Publisher: Elsevier BV
Date: 03-2018
Publisher: Oxford University Press (OUP)
Date: 27-01-2011
DOI: 10.1093/JXB/ERQ422
Publisher: CSIRO Publishing
Date: 2010
DOI: 10.1071/FP09202
Abstract: Many studies on salinity stress assume that responses in hydroponics mimic those in soil. However, interactions between the soil solution and the soil matrix can affect responses to salinity stress. This study compared responses to salinity in hydroponics and soil, using two varieties of barley (Hordeum vulgare L.). The responses to salinity caused by high concentrations of Na+ and Cl– were compared to assess any consistent differences between hydroponics and soil associated with a cation and an anion that contribute to salinity stress. Concentrated nutrient solutions were also used to assess the effects of osmotic stress. The effects of salinity differed between the hydroponic and soil systems. Differences between barley cultivars in growth, tissue moisture content and ionic composition were not apparent in hydroponics, whereas significant differences occurred in soil. Growth reductions were greater under hydroponics than in soil at similar electrical conductivity values, and the uptake of Na+ and Cl– was also greater. The relative importance of ion exclusion and osmotic stress varied. In soil, ion exclusion tended to be more important at low to moderate levels of stress (EC at field capacity up to 10 dS m–1) but osmotic stress became more important at higher stress levels. High external concentrations of Cl– had similar adverse effects as high concentrations of Na+, suggesting that Cl– toxicity may reduce growth. Fundamental differences in salinity responses appeared between soil and solution culture, and the importance of the different mechanisms of damage varies according to the severity and duration of the salt stress.
Publisher: Elsevier BV
Date: 10-2021
Publisher: American Chemical Society (ACS)
Date: 11-03-2020
Publisher: Springer Science and Business Media LLC
Date: 24-04-2017
DOI: 10.1038/NCLIMATE3276
Publisher: CSIRO Publishing
Date: 2020
DOI: 10.1071/CP20280
Abstract: Soil testing guidelines for sulfur (S) under dryland cropping in south-eastern Australia are not well developed. Our objective was to assess the value of soil and tissue tests for S and nitrogen (N), because the two minerals frequently interact), in predicting S-deficient sites and hence increasing the probability of response to application of S (and N). Here, we report three proximal experiments in 2014–16 for barley (Hordeum vulgare L.) and wheat (Triticum aestivum L.) on a sandy soil in a semi-arid environment near Merriwagga in western New South Wales. The trials contained a factorial combination of four rates of each of applied N as urea and S as high-grade gypsum. Responses to S were obtained for dry matter (DM) quantity and nutrient content at flowering in 2014, but no grain-yield response was obtained in any year. DM response to applied S was obtained when the concentration of S in the DM was increased from 0.08% in barley and 0.09% in wheat without S application to 0.10–0.11% in both crops with S applied as gypsum. Because we obtained no grain-yield responses to applied S, the 0.10% S in grain was likely to have been adequate for both crops in these experiments. A pool of subsoil S was accessed during each season and this compensated for any DM deficiencies of S by the time of grainfill. Shallow soil tests (0–10 cm) for S can therefore indicate sufficiency but not necessarily deficiency therefore, in grain-cropping areas, we recommend soil S tests on the same s les as used for deep N testing (to 60 cm) and that an S-budgeting approach be used following the soil tests. Furthermore, for marginal nutritional circumstances such as occurred in this study, the supporting use of N:S ratio is recommended, with values & in DM or grain likely to indicate S deficiency for both barley and wheat.
Publisher: Wiley
Date: 28-07-2016
DOI: 10.1111/EJSS.12369
Publisher: Oxford University Press (OUP)
Date: 21-03-2012
DOI: 10.1093/JXB/ERS085
Publisher: CSIRO Publishing
Date: 2013
DOI: 10.1071/EN13020
Abstract: Environmental context The fate and behaviour of inorganic contaminants are dominated by soluble complex formation and interactions with naturally occurring colloids. Although the importance of these interactions has long been debated, our understanding of the mobility and bioavailability of contaminant–colloid associations has been h ered by the limitations of common operationally defined analytical techniques. The method developed in this study facilitates a step forward from operationally defined characterisation of the association between contaminants and colloids to a functional characterisation in terms of their exchangeability and potential bioavailability. Abstract Despite evidence that the fate and behaviour of inorganic contaminants are influenced by their interactions with water-dispersible naturally occurring soil colloids, our understanding of the mobility and bioavailability of contaminant–colloid associations has been h ered by the limitations of common operationally defined analytical techniques. In this paper, an isotopic dilution method was developed to quantify the isotopically exchangeable and non-exchangeable forms of zinc and phosphorus in filtered soil-water extracts. In addition, the effect of filter size on the determination of Zn and P exchangeability was investigated. The results showed that the isotopically non-exchangeable Zn and P in filtered soil-water extracts respectively ranged between 5 and 60% and 10 and 50% and was associated with water-dispersible colloids. Filter pore size had a significant effect on Zn and P exchangeability. Whereas the .1-µm filtrates contained isotopically exchangeable Zn and P fractions equal to the total Zn and P concentrations (i.e. 100% isotopically exchangeable Zn and P), the filtrates obtained from larger filter sizes (0.22, 0.45 and 0.7µm) contained increasing proportions of non-exchangeable Zn and P.
Publisher: Elsevier BV
Date: 10-2021
Publisher: CSIRO Publishing
Date: 2017
DOI: 10.1071/SR16237
Abstract: Dissolved organic carbon (DOC) is important to microbial activity and nutrient cycling, and its concentration is sensitive to pH. Despite the importance of alkaline soils to agricultural production in southern Australia, few studies have documented the concentrations of soil organic carbon (C) and DOC or described the effects of soil properties and management practices on DOC in these soils. A survey of 33 paddocks from the Eyre Peninsula and mid-North regions of South Australia and north-western Victoria demonstrated significant variation in pH, soil organic C and DOC. Carbon stocks in the surface 30cm were 40–55tC/ha and were lowest in paddocks from Victoria. Soils from South Australia had higher DOC concentrations in the top 20cm than soils from Victoria. Principal component analysis suggested variation in DOC was increased by high pH, electric conductivity and the concentration of exchangeable Na, and was reduced by the concentration of exchangeable Ca and clay content. Mid-infrared Fourier transform infrared spectroscopy identified regional differences in the composition of soil organic C, with high amounts of charcoal in Eyre Peninsula soils. Farm management practices had little effect on soil organic C but influenced DOC. Grain yield and DOC concentration were inversely related across and within regions which appeared to be related to the intensity of cropping having opposite influences on yield and DOC. Compared with international data, DOC concentrations were high relative to the amount of soil organic C and, in contrast to many previous studies, DOC in all regions increased with depth.
Publisher: Wiley
Date: 05-2020
Publisher: Wiley
Date: 29-04-2019
DOI: 10.1111/EJSS.12808
Publisher: Elsevier BV
Date: 06-2020
Publisher: Informa UK Limited
Date: 28-02-2011
Publisher: Royal Society of Chemistry (RSC)
Date: 2019
DOI: 10.1039/C9NJ01641D
Abstract: Engineering of a graphene-oxide based slow release P composite as an efficient, environmental friendly fertiliser.
Publisher: Elsevier BV
Date: 03-2021
Publisher: Elsevier BV
Date: 07-2022
Publisher: Elsevier
Date: 2021
Publisher: Wiley
Date: 14-10-2020
Abstract: Carbon nitride (CN), a 2D material composed of only carbon (C) and nitrogen (N), which are linked by strong covalent bonds, has been used as a metal-devoid and visible-light-active photocatalyst owing to its magnificent optoelectronic and physicochemical properties including suitable bandgap, adjustable energy-band positions, tailor-made surface functionalities, low cost, metal-free nature, and high thermal, chemical, and mechanical stabilities. CN-based materials possess a lot of advantages over conventional metal-based inorganic photocatalysts including ease of synthesis and processing, versatile functionalization or doping, flexibility for surface engineering, low cost, sustainability, and recyclability without any leaching of toxic metals from photocorrosion. Carbon nitrides and their hybrid materials have emerged as attractive candidates for CO
Publisher: Elsevier BV
Date: 05-2013
DOI: 10.1016/J.ENVPOL.2013.01.029
Abstract: The increasing use of silver (Ag) nanoparticles [containing either elemental Ag (Ag-NPs) or AgCl (AgCl-NPs)] in commercial products such as textiles will most likely result in these materials reaching wastewater treatment plants. Previous studies indicate that a conversion of Ag-NPs to Ag2S is to be expected during wastewater transport/treatment. However, the influence of surface functionality, the nature of the core structure and the effect of post-processing on Ag speciation in sewage sludge/biosolids has not been investigated. This study aims at closing these knowledge gaps using bench scale anaerobic digesters spiked with Ag nitrate, three different types of Ag-NPs, and AgCl-NPs at environmentally realistic concentrations. The results indicate that neither surface functionality nor the different compositions of the NP prevented the formation of Ag2S. Silver sulfides, unlike the sulfides of other metals present in sewage sludge, were stable over a six month period simulating composting/stockpiling.
Location: Australia
Location: Australia
Start Date: 2015
End Date: 2017
Funder: Australian Research Council
View Funded ActivityStart Date: 2014
End Date: 2017
Funder: Grains Research and Development Corporation
View Funded ActivityStart Date: 2013
End Date: 2013
Funder: Grains Research and Development Corporation
View Funded ActivityStart Date: 2021
End Date: 2024
Funder: Australian Research Council
View Funded ActivityStart Date: 2015
End Date: 2020
Funder: Grains Research and Development Corporation
View Funded ActivityStart Date: 2016
End Date: 2021
Funder: Grains Research and Development Corporation
View Funded ActivityStart Date: 2015
End Date: 06-2018
Amount: $431,200.00
Funder: Australian Research Council
View Funded ActivityStart Date: 11-2022
End Date: 11-2025
Amount: $389,009.00
Funder: Australian Research Council
View Funded Activity