ORCID Profile
0000-0001-9236-5565
Current Organisations
IT University of Copenhagen
,
University of South Australia
,
CSIRO Adelaide
,
CSIRO
,
Griffith University
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Publisher: American Chemical Society (ACS)
Date: 26-01-2018
Abstract: Antimony (Sb) and arsenic (As) are priority environmental contaminants that often co-occur at mining-impacted sites. Despite their chemical similarities, Sb mobility in waterlogged sediments is poorly understood in comparison to As, particularly across the sediment-water interface (SWI) where changes can occur at the millimeter scale. Combined diffusive gradients in thin films (DGT) and diffusive equilibration in thin films (DET) techniques provided a high resolution, in situ comparison between Sb, As, and iron (Fe) speciation and mobility across the SWI in contaminated freshwater wetland sediment mesocosms under an oxic-anoxic-oxic transition. The shift to anoxic conditions released Fe(II), As(III), and As(V) from the sediment to the water column, consistent with As release being coupled to the reductive dissolution of iron(III) (hydr)oxides. Conversely, Sb(III) and Sb(V) effluxed to the water column under oxic conditions and fluxed into the sediment under anoxic conditions. Porewater DGT-DET depth profiles showed apparent decoupling between Fe(II) and Sb release, as Sb was primarily mobilized across the SWI under oxic conditions. Solid-phase X-ray absorption spectroscopy (XAS) revealed the presence of an Sb(III)-S phase in the sediment that increased in proportion with depth and the transition from oxic to anoxic conditions. The results of this study showed that Sb mobilization was decoupled from the Fe cycle and was, therefore, more likely linked to sulfur and/or organic carbon (e.g., most likely authigenic antimony sulfide formation or Sb(III) complexation by reduced organic sulfur functional groups).
Publisher: American Society of Civil Engineers (ASCE)
Date: 09-2017
Publisher: Eurowaste SRL
Date: 15-06-2023
DOI: 10.31025/2611-4135/2023.17278
Abstract: The race to meet net zero targets by 2050, while rapidly transitioning to a circular economy (CE) within the next decade, is shaping strategic Australian sustainability policy. While the success of integrating CE concepts relies on coordinating system-wide change, policies and strategies are still evolving under the traditional silos of waste and energy management. This presents multiple barriers to critical sectors, such as agriculture, which aims to become an $AUD100 billion industry by 2030. Agri-food systems face the challenge to meet growing global food demand, expected to increase by 70% by 2050, while decreasing emissions, resource use and waste production. Agriculture plays essential push and pull roles in meeting net zero targets and in developing a truly CE. Bioenergy, a critical part of the renewable circular bioeconomy, sits at the intersection of net zero and CE by producing renewable energy and recovering bioresources from waste biomass. By integrating agricultural end-users as key stakeholders, bioenergy can shift from a waste-to-energy process to a multi-resource generating process. These policy areas could be integrated via a similar approach to the Australian National Agricultural Innovation Policy Statement, with the goal of supporting agricultural production, while reducing emissions and maximising renewable resource use efficiency.
Publisher: Wiley
Date: 07-2022
DOI: 10.1111/PPL.13761
Abstract: Foliar fertilization delivers essential nutrients directly to plant tissues, reducing excessive soil fertilizer applications that can lead to eutrophication following nutrient leaching. Foliar nutrient absorption is a dynamic process affected by leaf surface structure and composition, plant nutrient status, and ion physicochemical properties. We applied multiple methods to study the foliar absorption behaviors of manganese (Mn) and phosphorus (P) in nutrient‐deficient spring barley ( Hordeum vulgare ) at two growth stages. Nutrient‐specific chlorophyll a fluorescence assays were used to visualize leaf nutrient status, while laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) was used to visualize foliar absorption pathways for P and Mn ions. Rapid Mn absorption was facilitated by a relatively thin cuticle with a low abundance of waxes and a higher stomatal density in Mn‐deficient plants. Following absorption, Mn accumulated in epidermal cells and in the photosynthetically active mesophyll, enabling a fast (6 h) restoration of Mn‐dependent photosynthetic processes. Conversely, P‐deficient plants developed thicker cuticles and epidermal cell walls, which reduced the penetration of P across the leaf surface. Foliar‐applied P accumulated in trichomes and fiber cells above leaf veins without reaching the mesophyll and, as a consequence, no restoration of P‐dependent photosynthetic processes was observed. This study reveals new links between leaf surface morphology, foliar‐applied ion absorption pathways, and the restoration of affected physiological processes in nutrient‐deficient leaves. Understanding that ions may have different absorption pathways across the leaf surface is critical for the future development of efficient fertilization strategies for crops in nutrient‐limited soils.
Publisher: Institute of Electrical and Electronics Engineers (IEEE)
Date: 11-2022
Publisher: American Society of Agricultural and Biological Engineers
Date: 2023
Publisher: Cambridge University Press
Date: 31-07-2016
Publisher: Oxford University Press (OUP)
Date: 15-06-2020
DOI: 10.1104/PP.20.00484
Publisher: Royal Society of Chemistry (RSC)
Date: 2016
DOI: 10.1039/C6EM00189K
Abstract: A new in situ s ling method enables the selective measurement of Sb( iii ) in surface waters and sediment porewaters.
Location: Australia
No related grants have been discovered for Maja Arsic.