ORCID Profile
0000-0001-6649-9148
Current Organisation
University of Tasmania
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Publisher: Royal Society of Chemistry (RSC)
Date: 2018
DOI: 10.1039/C8OB02590H
Abstract: The rate determining step for such a Nazarov cyclization is direct hydride transfer from pentadienyl ether to the oxygen of DDQ.
Publisher: American Chemical Society (ACS)
Date: 23-05-2018
Publisher: CSIRO Publishing
Date: 2019
DOI: 10.1071/CH19247
Publisher: Wiley
Date: 16-05-2018
Abstract: Density functional theory (DFT) was utilized to explore the reduction of gold(III) complexes by the amino acid glycine (Gly). Interestingly, when the nitrogen atom of Gly coordinates to the gold(III) center, its C
Publisher: Wiley
Date: 26-05-2021
Abstract: Palladium(II) boronates are recognized as fundamental pre‐transmetalation intermediates in Suzuki–Miyaura cross‐couplings. While these typically transient species have been detected and studied spectroscopically, it is conspicuous that they have never been isolated since this important reaction was discovered over forty years ago. This study reports the synthesis of a family of unprecedented arylpalladium(II) boronates that are, by design, kinetically stable at ambient temperature, both in solution and in the solid state. These properties enabled unambiguous crystallographic confirmation of their structure for the first time and their chemical competence in a Suzuki–Miyaura reaction was demonstrated.
Publisher: Royal Society of Chemistry (RSC)
Date: 2020
DOI: 10.1039/D0DT02737E
Abstract: Heterobi- and tetrametallic phosphoniocarbyne bridged complexes arise from the reactions of the terminal phosphoniocarbyne [W(CPMe 2 Ph)(CO) 2 (Tp*)]PF 6 with unsaturated metal centres.
Publisher: American Chemical Society (ACS)
Date: 04-09-2019
DOI: 10.1021/JACS.9B08634
Abstract: Bench- and air-stable 1-methoxy-2,2,6,6-tetramethylpiperidine (TEMPO-Me) is relatively unreactive at ambient temperature in the absence of an electrochemical stimulus. In this report, we demonstrate that the one-electron electrochemical oxidation of TEMPO-Me produces a powerful electrophilic methylating agent in situ. Our computational and experimental studies are consistent with methylation proceeding via a S
Publisher: CSIRO Publishing
Date: 2018
DOI: 10.1071/CH18046
Publisher: American Chemical Society (ACS)
Date: 14-09-2018
Publisher: American Chemical Society (ACS)
Date: 14-04-2021
No related grants have been discovered for Angus Olding.